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    PRODUCTION OF PHOSPHABENZENE COMPOUND
    1.
    发明专利
    PRODUCTION OF PHOSPHABENZENE COMPOUND 失效

    公开(公告)号：JP2000281692A

    公开(公告)日：2000-10-10

    申请号：JP2000077065

    申请日：2000-03-17

    Applicant: BASF AG

    Inventor： MACKEWITZ THOMAS ,  ROEPER MICHAEL PROF DR ,  BERNHARD BREIT

    IPC: C07F9/6568

    Abstract: PROBLEM TO BE SOLVED: To obtain, by an economically feasible method, a phosphabenzen compound useful as a ligand in a transition metal complex used in olefin hydroformyation, by reacting the corresponding pyrylium salt with PH3 in the presence (absence) of a solvent or the like, under specific conditions. SOLUTION: This compound of formula I or II (R1 to R6 are each H, a group COOM or the like; M is H, an alkali metal or the like; W is a covalent bond, oxo or the like) [e.g. 2,6-bis(2,4-dimethylphenyl)-4-phenylphosphabenzene] is obtained by reacting (A) the corresponding pyrylium salt such as 2,6-bis(2,4- dimethylphenyl))-4-phenylpyrylium tetrafluoroborate, and (B) PH3, in the presence (absence) of a solvent or diluent such as n-butanol, after joining the components A and B together at a temp. of >=0 deg.C, in the temp. range of 0 to 200 deg.C, and about >=1 bar pressure, with neither acid catalyst nor base added.

    HYDROFORMYLATION OF ETHYLENIC UNSATURATED POLYMER IN AQUEOUS DISPERSION
    2.
    发明专利
    HYDROFORMYLATION OF ETHYLENIC UNSATURATED POLYMER IN AQUEOUS DISPERSION 失效

    公开(公告)号：JPH1053613A

    公开(公告)日：1998-02-24

    申请号：JP13962197

    申请日：1997-05-29

    Applicant: BASF AG

    Inventor： ZELLER EDGAR DR ,  LEUBE HARTMANN F DR ,  SCHLARB BERNHARD DR ,  KNEUPER HEINZ-JOSEF DR ,  ROEPER MICHAEL PROF DR

    IPC: C08C19/00 ,  C08F8/00

    Abstract: PROBLEM TO BE SOLVED: To enable hydroformylating a polymer in the state of an aqueous dispersion by using a specific catalyst under specific conditions. SOLUTION: This method for hydroformylating an ethylenic unsaturated polymer comprises reacting (C) carbon monoxide and (D) hydrogen with (B) the aqueous dispersion of a polymer having ethylenic unsaturated double bonds in the presence of (A) a hydroformylation catalyst under a condition that the catalyst is at least partially impregnated into the phase of the polymer or at least into the boundary of the polymer/aqueous phase. The component A is preferably the salt or complex of cobalt, rhodium or ruthenium, especially rhodium. The reaction conditions are preferably selected from a temperature range of 50-150 deg.C and a pressure range of 20-300 bars. The polymer dispersion preferably contains a (co)polymer produced from 10-100wt.% of at least one conjugated diene and 0-90wt.% of at least one monoolefinic unsaturated monomer capable of copolymerizable with the diene.

    3.
    发明专利
    未知

    公开(公告)号：DE19622061A1

    公开(公告)日：1997-12-04

    申请号：DE19622061

    申请日：1996-05-31

    Applicant: BASF AG

    Inventor： ZELLER EDGAR DR ,  LEUBE HARTMANN F DR ,  SCHLARB BERNHARD DR ,  KNEUPER HEINZ-JOSEF DR ,  ROEPER MICHAEL PROF DR

    IPC: C08C19/00 ,  C08F8/00

    Abstract: A process for the hydroformylation of polymers containing ethylenic double bonds (I) by reacting (I) with carbon monoxide (CO) in presence of a hydroformylation catalyst, the reaction being carried out in an aqueous dispersion of (I) under conditions such that the catalyst is at least partly in the polymer phase or at least partly in the polymer/water interface. Also claimed are (i) polymer dispersions obtained by this process and (ii) polymers obtained from these dispersions by removing the aqueous solvent.

    5.
    发明专利
    未知

    公开(公告)号：DE19710994A1

    公开(公告)日：1998-09-24

    申请号：DE19710994

    申请日：1997-03-17

    Applicant: BASF AG

    Inventor： KANAND JUERGEN DR ,  PACIELLO ROCCO DR ,  ROEPER MICHAEL PROF DR

    IPC: C07C27/06 ,  C07B61/00 ,  C07C29/132 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C41/54 ,  C07C45/51 ,  C07C47/02 ,  C07C45/00 ,  C07C43/30

    Abstract: The invention relates to a method for producing n-butyraldehyde and/or n-butanol, whereby a) 1.3 butadiene or hydrocarbon mixtures containing butadiene are reacted with an alcohol of the formula (I) ROH wherein the radical R is an unsubstituted C2- to C20-alkyl- or alkenyl- or a C2- to C20-alkyl- or alkenyl- substituted with 1 to 2 C1- to C10-alkoxy- or hydroxy groups, a C6- to C10-aryl- or a C7- to C11- arylkyl group or methyl group at a high temperature and under high pressure in the presence of a bronsted acid or in the presence of a complex of an element from group IA, VIIA or VIIIA of the periodic table of elements with ligands containing phosphor or nitrogen to form a mixture of adducts of formulae (II) and (III); b) isomerizing adduct (III) to adduct (II); c) converting adduct (III) into acetal of formula (IV) in the presence of a sufficient quantity of an alcohol ROH I to form acetal (IV) and a homogeneous or heterogeneous transitional metal element catalyst which is different from dicobaltoctacarbonyl or hydridocobalttetracarbonyl in the liquid phase in essentially water-free conditions and d) then reacting this acetal (IV) with hydrogen and water or water in the presence of a homogenous or heterogeneous transitional metal element catalyst which is different from dicobaltoctacarbonyl or hydridocobalttetracarbonyl in liquid phase to produce n-butyraldehyde and/or n-butanol and releasing the alcohol ROH I and returning the released alcohol ROH I to the reaction in accordance with partial reaction a) and/or c).

    7.
    发明专利
    未知

    公开(公告)号：DE19631522A1

    公开(公告)日：1998-02-05

    申请号：DE19631522

    申请日：1996-08-03

    Applicant: BASF AG

    Inventor： FISCHER ROLF DR ,  PACIELLO ROCCO DR ,  ROEPER MICHAEL PROF DR ,  SCHNURR WERNER DR

    IPC: B01J23/44 ,  B01J23/46 ,  B01J23/75 ,  C07B61/00 ,  C07C209/48 ,  C07C209/60 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C209/24

    Abstract: The invention concerns a process for preparing 6-aminocapronitrile or 6-aminocapronitrile-hexamethylene diamine mixtures by: a) reacting 5-formylvaleronitrile with ammonia and hydrogen in the presence of hydrogenation catalysts selected from the group comprising metals or metal compounds of rhenium, copper and elements of the eight subgroups, a hydrogenation discharge product being obtained; and b) extracting from the hydrogenation discharge product 6-aminocapronitrile and optionally hexamethylene diamine, provided that the hydrogenation catalyst does not contain copper, nickel or copper and nickel as its only components.

    8.
    发明专利
    未知

    公开(公告)号：ES2102567T3

    公开(公告)日：1997-08-01

    申请号：ES93114394

    申请日：1993-09-08

    Applicant: BASF AG

    Inventor： KNEUPER HEINZ-JOSEF DR ,  ROEPER MICHAEL PROF DR ,  PACIELLO ROCCO DR

    IPC: C07B61/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02

    Abstract: Process for the preparation of aldehydes by the hydroformylation of olefins having more than 7 carbon atoms, comprising the stage of hydroformylation by means of a rhodium catalyst dissolved in homogeneous reaction medium, the separation of the rhodium catalyst from the material discharged from the hydroformylation reaction and the recycling of the rhodium separated from the material discharged from the hydroformylation to the hydroformylation stage, in which the rhodium catalyst is extracted into the aqueous phase from the material discharged from the hydroformylation by means of an aqueous solution of a nitrogen-containing complexing agent from the group consisting of the optionally substituted pyridines, quinolines, 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are sulphonated or carry sulphonated substituents, and/or from the group consisting of the carboxylated pyridines, the carboxylated quinolines, the optionally substituted 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are carboxylated or carry carboxylated substituents, and the aqueous, rhodium-containing extract is recycled to the hydroformylation stage.

    Process for the preparation of aldehydes
    10.
    发明专利
    Process for the preparation of aldehydes 未知

    公开(公告)号：DE4316180A1

    公开(公告)日：1994-11-17

    申请号：DE4316180

    申请日：1993-05-14

    Applicant: BASF AG

    Inventor： KNEUPER HEINZ-JOSEF DR ,  ROEPER MICHAEL PROF DR ,  PACIELLO ROCCO DR

    IPC: C07B61/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C45/45 ,  B01J31/40

    Abstract: Process for the preparation of aldehydes by the hydroformylation of olefins having more than seven carbon atoms, comprising the step of hydroformylation by means of a rhodium catalyst dissolved in homogeneous reaction medium, the separation of the rhodium catalyst from the material discharged from the hydroformylation reaction, and the recycling of the rhodium separated off from the material discharged from the hydroformylation in the hydroformylation step by extracting the rhodium catalyst from the material discharged from the hydroformylation by means of an aqueous solution of a nitrogen-containing complexing agent from the group consisting of pyridines, quinolines, 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are optionally substituted, sulphonated or carry sulphonated substituents and/or from the group consisting of carboxylated pyridines, carboxylated quinolines, and 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are optionally substituted, carboxylated or carry carboxylated substituents, in the aqueous phase and feeding back the aqueous, rhodium-containing extract to the hydroformylation step.

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