公开(公告)号：DE1522470A1

公开(公告)日：1969-07-31

申请号：DE1522470

申请日：1966-09-06

Applicant: BASF AG

Inventor： GEORG FLOSS DR JOSEF ,  RUDOLF BRODT DR ,  HERBERT HENKLER DR ,  HUGO STREHLER DR ,  HANS WILHELM DR

IPC: G03F7/037 ,  G03F7/10

Abstract: 1,191,177. Photopolymerizable compositions. BADISCHE ANILIN- & SODA-FABRIK A.G. 1 Sept., 1967 [2 Sept., 1966; 6 Sept., 1966], No. 40068/67. Heading C3P. [Also in Division G2] Photopolymerizable mixtures for use in producing printing plates comprise a polyamide, m- or p-xylylene-bis-acrylamide, triethylene glycol diacrylate and, optionally, butanediol monoacrylate, hexamethylene bisacrylamide and maleic anhydride, a photoinitiator, e.g. benzoin methyl ether, and a polymerization inhibitor, e.g. hydroquinone, p-methoxy-phenol or p-t-butyl-cresol.

公开(公告)号：DE1522463A1

公开(公告)日：1969-07-24

申请号：DEB0086310

申请日：1966-03-22

Applicant: BASF AG

Inventor： GERHARD FAULHABER DR ,  HERBERT HENKLER DR ,  HANS WILHELM DR ,  RUDOLF BRODT DR ,  JOSEF FLOSS DR

IPC: C08F283/04 ,  C08G69/02 ,  C08L77/00 ,  G03F7/027 ,  B41F

Abstract: 1,173,043. Photo-polymerizable processes for producing printing plates. BADISCHE ANILIN- & SODA FABRIK A.G. March 21, 1967 [March 22, 1966], No.13169/67. Heading G2C. Printing plates are produced by imagewise exposing a material which contains 30 to 75% of a synthetic polyamide and 70 to 25% of a photopolymerizable composition comprising a monomer containing at least two polymerizable carbon to carbon double bonds or a mixture of monomers at least one of which has two polymerizable double bonds, and the monomer or one of the monomers having at least one double bond and an alcoholetherified N-methylolamide group, a photoinitiator and/or a thermal polymerization inhibitor and developing by removing the unexposed areas with a solvent. The specified photo-polymerizable compounds are the N-methylolacrylamide bis-ether of ethylene glycol and the alkyl ether of N-methylolacrylamide. Preferred N-methylol ethers are N-methylol ethers of compounds of following formulae:- wherein R 1 is alkylene with up to six carbon atoms and R 2 is hydrogen or methyl.

公开(公告)号：DE1522469A1

公开(公告)日：1969-07-31

申请号：DE1522469

申请日：1966-09-02

Applicant: BASF AG

Inventor： GEORG FLOSS DR JOSEF ,  FRIEDRICH BAYERLEIN DR ,  RUDOLF BRODT DR ,  HERBERT HENKLER DR ,  HUGO STREHLER DR ,  HANS WILHELM DR ,  ROBERT GEHM DR

IPC: G03F7/037 ,  G03F7/10

Abstract: 1,191,177. Photopolymerizable compositions. BADISCHE ANILIN- & SODA-FABRIK A.G. 1 Sept., 1967 [2 Sept., 1966; 6 Sept., 1966], No. 40068/67. Heading C3P. [Also in Division G2] Photopolymerizable mixtures for use in producing printing plates comprise a polyamide, m- or p-xylylene-bis-acrylamide, triethylene glycol diacrylate and, optionally, butanediol monoacrylate, hexamethylene bisacrylamide and maleic anhydride, a photoinitiator, e.g. benzoin methyl ether, and a polymerization inhibitor, e.g. hydroquinone, p-methoxy-phenol or p-t-butyl-cresol.

公开(公告)号：DE1522441A1

公开(公告)日：1969-07-24

申请号：DE1522441

申请日：1966-09-16

Applicant: BASF AG

Inventor： STEINERT SIEGFRIED ,  HUGO STREHLER DR ,  RUDOLF BRODT DR

IPC: G03F7/037

公开(公告)号：DE1447931A1

公开(公告)日：1968-12-12

申请号：DE1447931

申请日：1965-09-08

Applicant: BASF AG

Inventor： HERBERT HENKLER DR ,  HANS WILHELM DR ,  GEORG FLOSS DR JOSEF ,  HUGO STREHLER DR ,  RUDOLF BRODT DR

IPC: G03F7/031 ,  G03F7/037

Abstract: 1,154,872. Photo-polymerizable materials. BADISHE ANILIN & SODA-FABRIK A. G. Sept. 7, 1966 [Sept. 8, 1965], No. 39967/66. Heading G2C. [Also in Division C3] Printing reliefs are prepared by exposing a plate, film or sheet of a photo-polymerizable composition to the action of actinic light, through a negative or positive image-bearing transparency, and removing in the desired depth the non-polymerized (non exposed) areas by means of a suitable solvent, said photo-polymerizable composition comprising a mixture of 50 - 90% by weight of a soluble linear synthetic polyamide containing as an integral part of the polymer chain recurring amido groups and 10 - 50% by weight of at least one addition polymerizable monomer containing at least two non-conjugated ethylenic double bonds or a mixture of such monomer with a monomer containing only one ethylenic double bond (said monomer or monomers being compatible to the extent of at least 30% by weight of the polyamidemonomer mixture with said polyamide), and 0À05 - 8% by weight of the polyamide/monomer mixture of at least one compatible carboxylic anhydride dispersed in the polyamide - monomer mixture. The compositions may also contain 0À01 - 10% by weight of the polyamide/monomer mixture of a photo-polymerisation initiator. The plate, film or sheet may be attached to a support, e.g. of metal, wood, paper or plastics material. The polyamide is preferably a copolymer of a lactam and/or nylon salt. Suitable poly-unsaturated monomers include alkylene - bis (meth) acrylamides, poly (meth) acrylyl derivatives of polyamines, (meth) acrylate esters of polyhydric alcohols, urethane and urea compounds obtained by reacting a diol mono (meth) acrylate or a mono - (meth) acrylamide with a diisocyanate, and heterocyclic compounds such as 1, 35 - triacryloyl - hexahydrotriazine- 1, 3, 5 and triallyl cyanurate. Suitable monoethylenic monomers include amides of (meth) acrylic, maleic and itaconic acid, styrene, mono- (meth) acrylate esters, N-vinyl-carbazole, N-vinyl pyrrolidone, N-vinyl-imides, vinyl acetate or propionate, dimethyl maleate and N - vinyl caprolactam. The anhydride component may be an aliphatic, cycloaliphatic or aromatic anhydride; polymeric anhydrides may also be used. Initiators which may be used include vicinal dicarbonyl compounds, α-carbonylalcohols, acyloin ethers, azonitriles, and polynuclear quinones. A thermal polymerization inhibitor, e.g. hydroquinone, p-methoxyphenol or di-t-butyl-p-cresol, may also be present. The photo-polymerization process is suitable for relief printing, indirect relief printing, dry offset printing and autotype intaglio printing.