公开(公告)号：DE19800934A1

公开(公告)日：1999-07-15

申请号：DE19800934

申请日：1998-01-13

Applicant: BASF AG

Inventor： SCHWAB PETER DR ,  SCHULZ MICHAEL DR ,  WOLF JUSTIN DR ,  STUEER WOLFRAM ,  WERNER HELMUT PROF DR

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08 ,  C07C6/02

Abstract: Ruthenium complexes are prepared by addition of alkyne compounds to ruthenium compounds in the presence of hydrogen, a reducing agent and optionally water. A process for the preparation of ruthenium complexes (I) of formula (1) comprises: (a) reaction of RuX3 with L and L in an inert solvent in the presence of a reducing agent and hydrogen and without isolation of intermediates followed by (b) addition of compounds of formula (2), optionally in the presence of water. RuX2(=CH-CH2R)L L (1) R - C ?= CH (2) where X = an anionic ligand R = H, 1-20C alkyl or 6-20C aryl, optionally substituted L , L = neutral electron donor ligands.