公开(公告)号：JP2000327666A

公开(公告)日：2000-11-28

申请号：JP2000124501

申请日：2000-04-25

Applicant: BASF AG

Inventor： SLANY MICHAEL ,  SCHULZ MICHAEL DR ,  SCHAEFER MARTIN ,  ZELLER EDGAR DR ,  EBEL KLAUS DR

IPC: C07D263/08 ,  C07D233/76 ,  C07D263/44

Abstract: PROBLEM TO BE SOLVED: To easily produce a cyclic anhydride of hydantoin or amino acid useful as an intermediate for the production of an essential amino acid such as methionine by reacting an aldehyde with urea, etc., and CO in the presence of a transition metal catalyst. SOLUTION: The objective compound of formula II is produced by reacting an aldehyde of formula R-CHO [R is a (substituted)alkyl or a (substituted)aryl] with CO and a compound of formula I [R2 is NH2 or the like; R3 is H, a (substituted)alkyl, a (substituted)aryl or the like] in the presence of a transition metal catalyst (e.g. Fe or Pd). The catalyst is preferably a mixture of a palladium compound (e.g. PdBr2), an ionic compound (e.g. phosphonium bromide) and an acid (e.g. sulfuric acid). The reaction is carried out preferably by using a solvent such as N-methylpyrrolidone under a pressure of 0.1-200 bar. This synthetic process does not form a by-produced salt to be disposed.

公开(公告)号：JPH10114705A

公开(公告)日：1998-05-06

申请号：JP24899897

申请日：1997-09-12

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR ,  RIEBER NORBERT DR ,  SCHULZ MICHAEL DR ,  TELES JOAQUIM HENRIQUE DR

IPC: B01J27/128 ,  B01J27/138 ,  B01J31/02 ,  B01J31/12 ,  C07B61/00 ,  C07C27/02 ,  C07C35/06 ,  C07C67/03 ,  C07C67/04 ,  C07C69/06

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound in a short time without generating a coupling product and effectively utilizing the starting substances by reacting a specific cyclopentene with formic acid in the presence of an acidic catalyst. SOLUTION: The objective cyclopentyl formate of the formula II is produced by reacting (A) 1mol of a cyclopentene compound of the formula I (R1 to R3 are each H or a 1-8C alkyl, preferably a 1-4C alkyl) with (B) 0.1-25mol of formic acid in the presence of (C) 0.0001-25mol of an acidic catalyst (e.g. a Lewis acid) at -80 to +200 deg.C, preferably 35-80 deg.C. The component A is available as a 5C stream from a cracking apparatus or an oil refinery plant. Cyclopentyl formate is useful as a production raw material for cyclopentanol.

公开(公告)号：AT252944T

公开(公告)日：2003-11-15

申请号：AT99115168

申请日：1999-08-13

Applicant: BASF AG

Inventor： SCHWAB PETER DR ,  BREITSCHEIDEL BORIS DR ,  SCHULZ RALF DR ,  SCHULZ MICHAEL DR ,  MUELLER ULRICH DR

IPC: B01J23/36 ,  B01J35/10 ,  B01J37/02 ,  C07C6/04 ,  C08G61/08

Abstract: A catalyst containing Re2O7 on an inorganic support, wherein the Re2O7 component is on the support in the form of Re2O7 particles having a diameter of

公开(公告)号：DE19800934A1

公开(公告)日：1999-07-15

申请号：DE19800934

申请日：1998-01-13

Applicant: BASF AG

Inventor： SCHWAB PETER DR ,  SCHULZ MICHAEL DR ,  WOLF JUSTIN DR ,  STUEER WOLFRAM ,  WERNER HELMUT PROF DR

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08 ,  C07C6/02

Abstract: Ruthenium complexes are prepared by addition of alkyne compounds to ruthenium compounds in the presence of hydrogen, a reducing agent and optionally water. A process for the preparation of ruthenium complexes (I) of formula (1) comprises: (a) reaction of RuX3 with L and L in an inert solvent in the presence of a reducing agent and hydrogen and without isolation of intermediates followed by (b) addition of compounds of formula (2), optionally in the presence of water. RuX2(=CH-CH2R)L L (1) R - C ?= CH (2) where X = an anionic ligand R = H, 1-20C alkyl or 6-20C aryl, optionally substituted L , L = neutral electron donor ligands.

公开(公告)号：DE19746040A1

公开(公告)日：1999-04-22

申请号：DE19746040

申请日：1997-10-17

Applicant: BASF AG

Inventor： SCHWAB PETER DR ,  SCHULZ MICHAEL DR

IPC: B01J23/46 ,  C07B61/00 ,  C07C6/04 ,  C07C11/06 ,  B01J23/36 ,  C07C11/173

Abstract: Production of propene comprises (a) reacting but-1-ene, but-2-ene and isobutene in the presence of a metathesis catalyst (I) containing sub-group VIb, VIIb and/or VIII metal compound(s); and (b) separating propene.

公开(公告)号：DE19600708A1

公开(公告)日：1997-07-17

申请号：DE19600708

申请日：1996-01-11

Applicant: BASF AG

Inventor： MUELLER ULRICH DR ,  SCHULZ MICHAEL DR ,  GEHRER EUGEN DR ,  GROSCH GEORG HEINRICH DR ,  HARDER WOLFGANG DR ,  DEMBOWSKI JUERGEN DR

IPC: B01J29/04 ,  B01J29/89 ,  C01B15/029 ,  C07D301/04 ,  C07D301/06 ,  C07D303/04

Abstract: An oxidation catalyst based on titanium or vanadium silicalites with zeolith structure is characterised in that it contains 0.01-20 wt % of one or more lanthanide metals from the group lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium.

公开(公告)号：DE19546610A1

公开(公告)日：1997-06-19

申请号：DE19546610

申请日：1995-12-13

Applicant: BASF AG

Inventor： SCHULZ MICHAEL DR ,  TELES JOAQUIM HENRIQUE DR

IPC: B01J31/18 ,  C07B41/00 ,  C07B61/00 ,  C07C27/00 ,  C07C41/08 ,  C07C41/54 ,  C07C43/15 ,  C07C43/303 ,  C07C43/315 ,  C07C45/00 ,  C07C45/26 ,  C07C49/04 ,  C07C49/08 ,  C07C49/17 ,  C07C49/175 ,  C07C51/54 ,  C07C67/04 ,  C07C67/055 ,  C07C69/145 ,  C07D317/12 ,  C07D319/10 ,  C07D319/12 ,  C07B37/02 ,  C07C69/08

Abstract: A process is disclosed for the catalytic addition of nucleophilic agents to alkines or allenes to form alkenes that are substituted by the nucleophile and where required undergo further reaction and/or isomerisation with the nucleophile. The catalyst used is a monovalent gold complex which is present at least in part in ionised form.

公开(公告)号：MY137590A

公开(公告)日：2009-02-27

申请号：MYPI20014559

申请日：2001-09-28

Applicant: BASF AG

Inventor： SCHAFER MARTIN DR ,  SLANY MICHAEL DR ,  ZELLER EDGAR DR ,  ROPER MICHAEL PROF DR ,  SCHULZ MICHAEL DR ,  GRIMM GUNTHER DR

IPC: B01J31/24 ,  B01J31/16 ,  B01J31/28 ,  B01J35/00 ,  C07B61/00 ,  C07C51/14 ,  C07C53/122 ,  C07C67/38

Abstract: A CATALYST SYSTEM COMPRISING (A) PALLADIUM, (B) A PHOSPHINE, AND (C) A NITROGEN-CONTAINING POLYMER WHICH IS SOLUBILIZABLE IN THE REACTION MIXTURE, WITH THE EXCEPTIONOF POLYVINYL POLYMERS HAVING AROMATIC NITROGEN-CONTAINING RADICALS ON THE POLYMER CHAIN CAN BE USED IN A PROCESS FOR THE CARBONYLATION OF OLEFINICALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS BY MEANS OF CARBON MONOXIDE AND A NUCLEOPHILIC COMPOUND.

公开(公告)号：ES2210915T3

公开(公告)日：2004-07-01

申请号：ES99115168

申请日：1999-08-13

Applicant: BASF AG

Inventor： SCHWAB PETER DR ,  BREITSCHEIDEL BORIS DR ,  SCHULZ RALF DR ,  SCHULZ MICHAEL DR ,  MULLER ULRICH DR

IPC: B01J23/36 ,  B01J35/10 ,  B01J37/02 ,  C07C6/04 ,  C08G61/08

Abstract: A catalyst containing Re2O7 on an inorganic support, wherein the Re2O7 component is on the support in the form of Re2O7 particles having a diameter of

公开(公告)号：ES2210642T3

公开(公告)日：2004-07-01

申请号：ES98119484

申请日：1998-10-15

Applicant: BASF AG

Inventor： SCHWAB PETER DR ,  SCHULZ MICHAEL DR

IPC: B01J23/46 ,  C07B61/00 ,  B01J23/36 ,  C07C6/04 ,  C07C11/06

Abstract: A multistage process for preparing propene, in which the first stage is the reaction of 1-butene, 2-butene and isobutene to give propene, 2-pentene and 2-methyl-2-butene in the presence of a metathesis catalyst comprising at least one compound of a metal of transition group VIb, VIIb or VIII of the Periodic Table of the Elements; the second stage is separation of the propene and 2-pentene/2-methyl-2-butene formed; the third stage is reaction of the 2-pentene and 2-methyl-2-butene with ethehe to give propene, 1-butene and isobutene in the presence of a metathesis catalyst comprising at least one compound of a metal of transition group VIb, VIIb or VIII of the Periodic Table of the Elements; the fourth stage is separation of the propene and 1-butene/isobutene formed and returning the 1-butene and isobutene formed to the first stage.