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    Fuel additive-containing lattice-engineered cerium dioxide nanoparticles
    1.
    发明专利
    Fuel additive-containing lattice-engineered cerium dioxide nanoparticles 有权
    含燃料添加剂的工程二氧化碳纳米颗粒

    公开(公告)号：JP2014058448A

    公开(公告)日：2014-04-03

    申请号：JP2013258488

    申请日：2013-12-13

    Applicant: Cerion Technology Inc ,  セリオン テクノロジー インコーポレイテッド

    Inventor： ALBERT GARY DIFRANCESCO ,  ALLSTON THOMAS D ,  RICHARD K HAILSTONE ,  ANDREAS LANGNER ,  REED KENNETH J

    IPC: C01F17/00 ,  C10L1/30

    Abstract: PROBLEM TO BE SOLVED: To provide cerium dioxide nanoparticles CeMOincluding at least one transition metal (M) and a method for preparing such particles.SOLUTION: In a process for forming cerium dioxide nanoparticles including at least one transition metal (M), a product flow including transition metal-containing cerium dioxide nanoparticles CeMO(x bears a value of approximately 0.3 to approximately 0.8) is generated by using a suspension of cerium hydroxide nanoparticles prepared by mechanically shearing an aqueous admixture including an oxidant at an amount effective for oxidizing trivalent cerium ions into tetravalent cerium ions. The nanoparticles thus obtained have a cubic fluorite-type structure, an average rheological diameter of approximately 1 to approximately 10 nm, and a geometric diameter of less than approximately 4 nm. A particle dispersion system within a non-polar medium can be prepared by using transition metal-containing crystalline cerium dioxide nanoparticles.

    Abstract translation: 要解决的问题：提供包含至少一种过渡金属（M）的二氧化铈纳米颗粒CeMO和制备这种颗粒的方法。解决方案：在形成二氧化铈纳米颗粒的方法中，包括至少一种过渡金属（M），产物流 包括含过渡金属的二氧化铈纳米颗粒通过使用通过机械剪切包含氧化剂的水性混合物以有效氧化三价铈离子的量制备的氢氧化铈纳米颗粒的悬浮液来产生CeMO（x值约为0.3至约0.8） 成四价铈离子。 由此获得的纳米颗粒具有立方萤石型结构，平均流变学直径为约1至约10nm，几何直径小于约4nm。 可以通过使用含过渡金属的结晶二氧化铈纳米颗粒来制备非极性介质中的颗粒分散体系。

    STRUCTURED CATALYTIC NANOPARTICLES AND METHOD OF PREPARATION
    2.
    发明专利
    STRUCTURED CATALYTIC NANOPARTICLES AND METHOD OF PREPARATION 未知

    公开(公告)号：CA2792409A1

    公开(公告)日：2011-09-15

    申请号：CA2792409

    申请日：2011-03-08

    Applicant: CERION TECHNOLOGY INC

    Inventor： REED KENNETH J ,  DIFRANCISCO ALBERT GARY ,  HAILSTONE RICHARD K ,  PROK GARY R ,  ALLSTON THOMAS D

    IPC: B22F9/16 ,  B22F1/00 ,  C10L1/12 ,  C10M125/10

    Abstract: A method for forming a structured doped cerium oxide nanoparticle including the steps of forming a first aqueous cerium(lll) reaction mixture, with optional metal/s other than cerium, a base, and a stabilizer; introducing an oxidant to singly oxidize cerium (III), followed by thermal formation of a doped cerium oxide nanoparticle core; then providing a second reaction mixture of one or more metal ions other than cerium, and optionally cerium (III) ions and sufficient cerium (III) oxidant, followed by thermally converting the mixture into a shell around the doped cerium oxide nanoparticle core, wherein the ratio of metal ions in the core differs from the ratio of metal ions in the shell. The disclosed structured doped cerium oxide nanoparticle may exhibit cubic fluorite crystal structure and possess a diameter in the range 1 nm-20 nm. A dispersion of the developed nanoparticle may be used as a fuel additive.

    ADITIVOS DE COMBUSTIBLE QUE CONTIENEN NANOPARTÍCULAS DE DIÓXIDO DE CERIO CON DISEÑO DE RED.
    4.
    发明专利
    ADITIVOS DE COMBUSTIBLE QUE CONTIENEN NANOPARTÍCULAS DE DIÓXIDO DE CERIO CON DISEÑO DE RED. 未知

    公开(公告)号：MX2011006461A

    公开(公告)日：2011-11-18

    申请号：MX2011006461

    申请日：2008-12-17

    Applicant: CERION TECHNOLOGY INC

    Inventor： DIFRANCESCO ALBERT GARY ,  ALLSTON THOMAS D ,  HAILSTONE RICHARD K ,  LANGNER ANDREAS ,  REED KENNETH J

    IPC: B01J23/10 ,  B01J23/00 ,  C09K23/00

    Abstract: Un proceso para hacer nanopartículas de dióxido de cerio que contienen al menos un material de transición (M) que comprende (a) proporcionar una mezcla de reacción acuosa que contiene una fuente de ión ceroso, una fuente de uno o más iones metálicos de transición (M), una fuente de ión de hidróxido, al menos un estabilizador de nanopartículas, y un oxidante a una temperatura inicial en un rango de alrededor de 200C alrededor de 950C; (b) cortar mecánicamente la mezcla y provocar que pase a través de una pantalla perforada, formando así una suspensión homogéneamente distribuída de nanopartículas de hidróxido de cerio; y (c) proporcionar condiciones de temperatura efectivas para lograr la oxidación de ión ceroso a ión cérico, formando así una corriente de producto que contiene nanopartículas de dióxido de cerio que contienen metal de transición, Ce1-xMxO2, en donde "x" tiene un valor de alrededor de 0.3 a alrededor de 0.8. Las nanopartículas así obtenidas, tienen una estructura de fluorita cúbica, una media de diámetro hidrodinámico en un rango de alrededor de 1 nm a alrededor de 10nm, y un diámetro geométrico menor a alrededor de 4 nm. Las nanopartículas cristalinas de dióxido de cerio que contienen metal de transición pueden usarse para preparar una dispersión de las partículas en un medio no polar.

    Structured catalytic nanoparticles and method of preparation
    5.
    发明专利
    Structured catalytic nanoparticles and method of preparation 未知

    公开(公告)号：AU2011224865A1

    公开(公告)日：2012-10-04

    申请号：AU2011224865

    申请日：2011-03-08

    Applicant: CERION TECHNOLOGY INC

    Inventor： REED KENNETH J ,  DIFRANCISCO ALBERT GARY ,  HAILSTONE RICHARD K ,  PROK GARY R ,  ALLSTON THOMAS D

    IPC: B01J23/00 ,  B01J23/10 ,  C10M125/10

    Abstract: A method for forming a structured doped cerium oxide nanoparticle including the steps of forming a first aqueous cerium(lll) reaction mixture, with optional metal/s other than cerium, a base, and a stabilizer; introducing an oxidant to singly oxidize cerium (III), followed by thermal formation of a doped cerium oxide nanoparticle core; then providing a second reaction mixture of one or more metal ions other than cerium, and optionally cerium (III) ions and sufficient cerium (III) oxidant, followed by thermally converting the mixture into a shell around the doped cerium oxide nanoparticle core, wherein the ratio of metal ions in the core differs from the ratio of metal ions in the shell. The disclosed structured doped cerium oxide nanoparticle may exhibit cubic fluorite crystal structure and possess a diameter in the range 1 nm-20 nm. A dispersion of the developed nanoparticle may be used as a fuel additive.

    Fuel additive containing lattice engineered cerium dioxide nanoparticles
    6.
    发明专利
    Fuel additive containing lattice engineered cerium dioxide nanoparticles 未知

    公开(公告)号：AU2008365234A1

    公开(公告)日：2011-07-07

    申请号：AU2008365234

    申请日：2008-12-17

    Applicant: CERION TECHNOLOGY INC

    Inventor： GARY DIFRANCESCO ALBERT ,  ALLSTON THOMAS D ,  HAILSTONE RICHARD K ,  ANDREAS LANGNER ,  REED KENNETH J

    IPC: B01J23/10 ,  B01J23/00 ,  C09K23/00

    Abstract: A process for making cerium dioxide nanoparticles containing at least one transition metal (M) utilizing a suspension of cerium hydroxide nanoparticles prepared by mechanical shearing of an aqueous mixture containing an oxidant in an amount effective to enable oxidation of cerous ion to eerie ion, thereby forming a product stream that contains transition metal-containing cerium dioxide nanoparticles, Cel-xMxO2, wherein "x" has a value from about 0.3 to about 0.8. The nanoparticles thus obtained have a cubic fluorite structure, a mean hydrodynamic diameter in the range of about 1 nm to about 10 nm, and a geometric diameter of less than about 4 run. The transition metal-containing crystalline cerium dioxide nanoparticles can be used to prepare a dispersion of the particles in a nonpolar medium.

    FUEL ADDITIVE CONTAINING LATTICE ENGINEERED CERIUM DIOXIDE NANOPARTICLES
    7.
    发明专利
    FUEL ADDITIVE CONTAINING LATTICE ENGINEERED CERIUM DIOXIDE NANOPARTICLES 未知

    公开(公告)号：CA2747547A1

    公开(公告)日：2010-06-24

    申请号：CA2747547

    申请日：2008-12-17

    Applicant: CERION TECHNOLOGY INC

    Inventor： DIFRANCESCO ALBERT GARY ,  ALLSTON THOMAS D ,  HAILSTONE RICHARD K ,  LANGNER ANDREAS ,  REED KENNETH J

    IPC: B01J23/10 ,  C09K23/00 ,  C10L10/02

    Abstract: A process for making cerium dioxide nanoparticles containing at least one transition metal (M) utilizing a suspension of cerium hydroxide nanoparticles prepared by mechanical shearing of an aqueous mixture containing an oxidant in an amount effective to enable oxidation of cerous ion to eerie ion, thereby forming a product stream that contains transition metal-containing cerium dioxide nanoparticles, Cel-xMxO2, wherein "x" has a value from about 0.3 to about 0.8. The nanoparticles thus obtained have a cubic fluorite structure, a mean hydrodynamic diameter in the range of about 1 nm to about 10 nm, and a geometric diameter of less than about 4 run. The transition metal-containing crystalline cerium dioxide nanoparticles can be used to prepare a dispersion of the particles in a nonpolar medium.

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