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公开(公告)号：JP2014139127A
公开(公告)日：2014-07-31
申请号：JP2014006333
申请日：2014-01-17
Inventor： ALBERT GARY DIFRANCESCO , HAILSTONE RICHARD K , ANDREAS LANGNER , REED KENNETH J
IPC: C01F17/00
CPC classification number: B01J23/10 , B01F3/0807 , B01F7/164 , B01J13/0047 , B01J13/0086 , B82Y30/00 , C10L1/10 , C10L1/103 , C10L1/1233 , C10L1/125 , C10L1/1258 , C10L1/1608 , C10L1/1616 , C10L1/1811 , C10L1/1824 , C10L1/1881 , C10L1/1883 , C10L1/19 , C10L1/1985 , C10L1/2222 , C10L1/2437 , C10L10/02 , C10L10/08 , C10L10/12 , C10M2201/062 , C10N2230/06 , C10N2240/10 , Y02T50/678 , C10N2210/03 , C10N2220/082
Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing cerium dioxide nanoparticles which can be used as a component of a fuel additive composition.SOLUTION: A method for manufacturing cerium dioxide nanoparticles includes: a) a process of providing a first cerium ion source, a hydroxide ion source, nanoparticles stabilizer and an aqueous reaction mixture having an oxidant at an initial temperature of 20°C or lower; b) a process of forming a suspension of cerium hydroxide nanoparticles by mechanically shearing the mixture and passing it through a boring screen; and c) a process of forming cerium nanoparticles having an average diameter in a range of about 1 mm to about 15 mm by increasing the initial temperature and causing oxidation of a primary cerium ion to a second cerium ion. Cerium dioxide nanoparticles can be formed by continuous processes.
Abstract translation: 要解决的问题：提供可用作燃料添加剂组合物的组分的二氧化铈纳米颗粒的制备方法。解决方案：二氧化铈纳米颗粒的制造方法包括：a）提供第一铈离子源的方法， 氢氧根离子源，纳米颗粒稳定剂和在初始温度为20℃以下具有氧化剂的水性反应混合物; b）通过机械剪切混合物并将其通过镗孔形成氢氧化铈纳米颗粒的悬浮液的方法; 和c）通过增加初始温度并使一次铈离子氧化成第二铈离子，形成平均直径在约1mm至约15mm范围内的铈纳米颗粒的方法。 可以通过连续工艺形成二氧化铈纳米颗粒。
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2.发明专利
公开(公告)号：JP2014058448A
公开(公告)日：2014-04-03
申请号：JP2013258488
申请日：2013-12-13
Applicant: Cerion Technology Inc , セリオン テクノロジー インコーポレイテッド
Inventor： ALBERT GARY DIFRANCESCO , ALLSTON THOMAS D , RICHARD K HAILSTONE , ANDREAS LANGNER , REED KENNETH J
Abstract: PROBLEM TO BE SOLVED: To provide cerium dioxide nanoparticles CeMOincluding at least one transition metal (M) and a method for preparing such particles.SOLUTION: In a process for forming cerium dioxide nanoparticles including at least one transition metal (M), a product flow including transition metal-containing cerium dioxide nanoparticles CeMO(x bears a value of approximately 0.3 to approximately 0.8) is generated by using a suspension of cerium hydroxide nanoparticles prepared by mechanically shearing an aqueous admixture including an oxidant at an amount effective for oxidizing trivalent cerium ions into tetravalent cerium ions. The nanoparticles thus obtained have a cubic fluorite-type structure, an average rheological diameter of approximately 1 to approximately 10 nm, and a geometric diameter of less than approximately 4 nm. A particle dispersion system within a non-polar medium can be prepared by using transition metal-containing crystalline cerium dioxide nanoparticles.
Abstract translation: 要解决的问题：提供包含至少一种过渡金属（M）的二氧化铈纳米颗粒CeMO和制备这种颗粒的方法。解决方案：在形成二氧化铈纳米颗粒的方法中，包括至少一种过渡金属（M），产物流 包括含过渡金属的二氧化铈纳米颗粒通过使用通过机械剪切包含氧化剂的水性混合物以有效氧化三价铈离子的量制备的氢氧化铈纳米颗粒的悬浮液来产生CeMO（x值约为0.3至约0.8） 成四价铈离子。 由此获得的纳米颗粒具有立方萤石型结构，平均流变学直径为约1至约10nm，几何直径小于约4nm。 可以通过使用含过渡金属的结晶二氧化铈纳米颗粒来制备非极性介质中的颗粒分散体系。
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公开(公告)号：CA2798986A1
公开(公告)日：2011-11-17
申请号：CA2798986
申请日：2011-05-13
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J , DIFRANCISCO ALBERT GARY , PROK GARY R , HAILSTONE RICHARD K
Abstract: A process for making cerium-containing oxide nanoparticles includes providing an aqueous reaction mixture containing a source of cerous ion, optionally a source of one or more metal ions (M) other than cerium, a source of hydroxide ion, at least one monoether carboxylic acid nanoparticle stabilizer wherein the molar ratio of said monoether carboxylic acid nanoparticle stabilizers to total metal ions is greater than 0.2, and an oxidant at an initial temperature in the range of about 20°C to about 95°C. Temperature conditions are provided effective to enable oxidation of cerous ion to ceric ion, thereby forming a product dispersion of cerium-containing oxide nanoparticles, optionally containing one or more metal ions (M), Ce1-xMxO2-d, wherein "x" has a value from about 0.0 to about 0.95. The nanoparticles may have a mean hydrodynamic diameter from about 1 nm to about 50 nm, and a geometric diameter of less than about 45 nm.
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公开(公告)号：CA2792409A1
公开(公告)日：2011-09-15
申请号：CA2792409
申请日：2011-03-08
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J , DIFRANCISCO ALBERT GARY , HAILSTONE RICHARD K , PROK GARY R , ALLSTON THOMAS D
IPC: B22F9/16 , B22F1/00 , C10L1/12 , C10M125/10
Abstract: A method for forming a structured doped cerium oxide nanoparticle including the steps of forming a first aqueous cerium(lll) reaction mixture, with optional metal/s other than cerium, a base, and a stabilizer; introducing an oxidant to singly oxidize cerium (III), followed by thermal formation of a doped cerium oxide nanoparticle core; then providing a second reaction mixture of one or more metal ions other than cerium, and optionally cerium (III) ions and sufficient cerium (III) oxidant, followed by thermally converting the mixture into a shell around the doped cerium oxide nanoparticle core, wherein the ratio of metal ions in the core differs from the ratio of metal ions in the shell. The disclosed structured doped cerium oxide nanoparticle may exhibit cubic fluorite crystal structure and possess a diameter in the range 1 nm-20 nm. A dispersion of the developed nanoparticle may be used as a fuel additive.
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公开(公告)号：CA2839886A1
公开(公告)日：2008-03-13
申请号：CA2839886
申请日：2007-09-04
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J
Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxide ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 20° C.; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of cerium hydroxide nanoparticles; and c) raising the initial temperature to achieve oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanoparticles having a mean diameter in the range of about 1 nm to about 15 nm. The cerium dioxide nanoparticles may be formed in a continuous process.
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Patent Agency Ranking
公开(公告)号：AU2011253488A1
公开(公告)日：2012-12-20
申请号：AU2011253488
申请日：2011-05-13
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J , DIFRANCISCO ALBERT GARY , PROK GARY R , HAILSTONE RICHARD K
Abstract: A process for making cerium-containing oxide nanoparticles includes providing an aqueous reaction mixture containing a source of cerous ion, optionally a source of one or more metal ions (M) other than cerium, a source of hydroxide ion, at least one monoether carboxylic acid nanoparticle stabilizer wherein the molar ratio of said monoether carboxylic acid nanoparticle stabilizers to total metal ions is greater than 0.2, and an oxidant at an initial temperature in the range of about 20°C to about 95°C. Temperature conditions are provided effective to enable oxidation of cerous ion to ceric ion, thereby forming a product dispersion of cerium-containing oxide nanoparticles, optionally containing one or more metal ions (M), Ce
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公开(公告)号：WO2011112244A3
公开(公告)日：2011-11-10
申请号：PCT/US2011000429
申请日：2011-03-08
Applicant: CERION TECHNOLOGY INC , REED KENNETH J , DIFRANCISCO ALBERT GARY , HAILSTONE RICHARD K , PROK GARY R , ALLSTON THOMAS D
Inventor： REED KENNETH J , DIFRANCISCO ALBERT GARY , HAILSTONE RICHARD K , PROK GARY R , ALLSTON THOMAS D
CPC classification number: B01J23/10 , B01J23/002 , B01J23/83 , B01J37/0221 , B01J37/031 , B01J37/035 , B82Y30/00 , B82Y40/00 , C01F17/0018 , C01F17/0043 , C01G49/00 , C01G49/009 , C01P2002/52 , C01P2004/03 , C01P2004/04 , C01P2004/45 , C01P2004/64 , C01P2004/84 , C10L1/1233 , C10L10/02 , C10M125/10 , C10M2201/062 , C10N2220/082 , C10N2250/12 , Y10S977/775 , Y10S977/811 , Y10S977/89 , Y10S977/902
Abstract: A method for forming a structured doped cerium oxide nanoparticle including the steps of forming a first aqueous cerium(lll) reaction mixture, with optional metal/s other than cerium, a base, and a stabilizer; introducing an oxidant to singly oxidize cerium (III), followed by thermal formation of a doped cerium oxide nanoparticle core; then providing a second reaction mixture of one or more metal ions other than cerium, and optionally cerium (III) ions and sufficient cerium (III) oxidant, followed by thermally converting the mixture into a shell around the doped cerium oxide nanoparticle core, wherein the ratio of metal ions in the core differs from the ratio of metal ions in the shell. The disclosed structured doped cerium oxide nanoparticle may exhibit cubic fluorite crystal structure and possess a diameter in the range 1 nm-20 nm. A dispersion of the developed nanoparticle may be used as a fuel additive.
Abstract translation: 一种用于形成结构掺杂的氧化铈纳米颗粒的方法，包括以下步骤：用除铈以外的任选金属，碱和稳定剂形成第一含水铈（III）反应混合物; 引入氧化剂以单独氧化铈（III），然后热成型掺杂的氧化铈纳米颗粒核心; 然后提供除铈以外的一种或多种金属离子和任选的铈（III）离子和足够的铈（III）氧化剂的第二反应混合物，随后将混合物热转化成掺杂的氧化铈纳米颗粒核周围的壳，其中 核中金属离子的比例与壳中金属离子的比例不同。 所公开的结构掺杂的氧化铈纳米颗粒可呈现立方萤石晶体结构，其直径范围为1nm-20nm。 所开发的纳米颗粒的分散体可以用作燃料添加剂。
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公开(公告)号：AU2011224865A1
公开(公告)日：2012-10-04
申请号：AU2011224865
申请日：2011-03-08
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J , DIFRANCISCO ALBERT GARY , HAILSTONE RICHARD K , PROK GARY R , ALLSTON THOMAS D
IPC: B01J23/00 , B01J23/10 , C10M125/10
Abstract: A method for forming a structured doped cerium oxide nanoparticle including the steps of forming a first aqueous cerium(lll) reaction mixture, with optional metal/s other than cerium, a base, and a stabilizer; introducing an oxidant to singly oxidize cerium (III), followed by thermal formation of a doped cerium oxide nanoparticle core; then providing a second reaction mixture of one or more metal ions other than cerium, and optionally cerium (III) ions and sufficient cerium (III) oxidant, followed by thermally converting the mixture into a shell around the doped cerium oxide nanoparticle core, wherein the ratio of metal ions in the core differs from the ratio of metal ions in the shell. The disclosed structured doped cerium oxide nanoparticle may exhibit cubic fluorite crystal structure and possess a diameter in the range 1 nm-20 nm. A dispersion of the developed nanoparticle may be used as a fuel additive.
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公开(公告)号：AU2008365234A1
公开(公告)日：2011-07-07
申请号：AU2008365234
申请日：2008-12-17
Applicant: CERION TECHNOLOGY INC
Inventor： GARY DIFRANCESCO ALBERT , ALLSTON THOMAS D , HAILSTONE RICHARD K , ANDREAS LANGNER , REED KENNETH J
Abstract: A process for making cerium dioxide nanoparticles containing at least one transition metal (M) utilizing a suspension of cerium hydroxide nanoparticles prepared by mechanical shearing of an aqueous mixture containing an oxidant in an amount effective to enable oxidation of cerous ion to eerie ion, thereby forming a product stream that contains transition metal-containing cerium dioxide nanoparticles, Cel-xMxO2, wherein "x" has a value from about 0.3 to about 0.8. The nanoparticles thus obtained have a cubic fluorite structure, a mean hydrodynamic diameter in the range of about 1 nm to about 10 nm, and a geometric diameter of less than about 4 run. The transition metal-containing crystalline cerium dioxide nanoparticles can be used to prepare a dispersion of the particles in a nonpolar medium.
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公开(公告)号：CA2747547A1
公开(公告)日：2010-06-24
申请号：CA2747547
申请日：2008-12-17
Applicant: CERION TECHNOLOGY INC
Inventor： DIFRANCESCO ALBERT GARY , ALLSTON THOMAS D , HAILSTONE RICHARD K , LANGNER ANDREAS , REED KENNETH J
Abstract: A process for making cerium dioxide nanoparticles containing at least one transition metal (M) utilizing a suspension of cerium hydroxide nanoparticles prepared by mechanical shearing of an aqueous mixture containing an oxidant in an amount effective to enable oxidation of cerous ion to eerie ion, thereby forming a product stream that contains transition metal-containing cerium dioxide nanoparticles, Cel-xMxO2, wherein "x" has a value from about 0.3 to about 0.8. The nanoparticles thus obtained have a cubic fluorite structure, a mean hydrodynamic diameter in the range of about 1 nm to about 10 nm, and a geometric diameter of less than about 4 run. The transition metal-containing crystalline cerium dioxide nanoparticles can be used to prepare a dispersion of the particles in a nonpolar medium.
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