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    METHOD OF MANUFACTURE FOR METHACRYLIC DERIVATIVES
    1.
    发明授权
    METHOD OF MANUFACTURE FOR METHACRYLIC DERIVATIVES 失效

    公开(公告)号：KR800001330B1

    公开(公告)日：1980-10-28

    申请号：KR770001767

    申请日：1977-08-01

    Applicant: STANDARD OIL CO OHIO

    Inventor： CALLAHAN J ,  HARDMAN H ,  GRASSELLI R

    IPC: C07C57/04

    Abstract: Methacrolein and either methacrylonitrile or isobutylene were prepd. by ammoxidn. and dehydrogenation of methy1 tertBu ether or isobutylene dimer. Thus a slurry was prepd. from 1.29parts 85% H3PO4 and aq. solns. of NH4 heptamolybdate 47.5, Co(NH3)26H2O 29.4, Ni(NO3)26H2O 16.3, Fe(NO3)9H2O 27.2, Ni(NO3)35H2O 10.9, HNO31.5, and KNO3 0.16parts and 13.15 parts silica. The slurry was dried, calcined at 274-88≦̸C, mixed with 1% graphite, formed into tablets, and calcined 5 hr at 560≦̸C to give a catalyst of compn. 82.5% K0.07Ni2.5Co0.45Fe3Bip0.5Mo12O50-17.5% SiO2.

    2.
    发明专利
    未知

    公开(公告)号：NO117119B

    公开(公告)日：1969-07-07

    申请号：NO16337466

    申请日：1966-06-09

    Applicant: STANDARD OIL CO OHIO

    Inventor： GRASSELLI R ,  CALLAHAN J

    IPC: B01J27/192 ,  C07C5/48

    Abstract: 1,154,029. Oxydehydrogenation catalyst. STANDARD OIL CO. 9 June, 1966 [10 June, 1965], No. 25829/66. Heading B1E. [Also in Division C5] A catalyst for the oxydehydrogenation of C 4 to C 10 monoolefins to conjugated dienes has the composition A a B b Fe c Bi d P e Mo f O 2 , where A is Group VIII transition metal other than Fe, B is at least one of Sb, Sn, Cu and As, and a is 0.1 to 12, b is 0 to 12, c is 0.1 to 12, d is 0.1 to 12, e is 0 to 12, f is 6 to 12, and the Mo@ may be at least partially replaced by W. The catalyst may be used alone or on a carrier material, for example silica, alumina, thoria, zirconia, titania, boron phosphate, silicon carbide, pumice, diatomaceous earth or clay ,the carrier being used in amount less than 95% by weight of the final catalyst composition. The catalysts may be made by dissolving soluble salts of the metals in water or acid and heating the mixture with an aqueous silica dispersion until a gel forms. The gel is heated to dry it then calcined in air.

    4.
    发明专利
    未知

    公开(公告)号：SE310168B

    公开(公告)日：1969-04-21

    申请号：SE559364

    申请日：1964-05-06

    Applicant: STANDARD OIL CO OHIO

    Inventor： CALLAHAN J ,  KNIPPLE W

    IPC: B01J21/00 ,  B01J23/16 ,  B01J23/18 ,  B01J23/644 ,  B01J23/68 ,  B01J23/843 ,  B01J27/18 ,  B01J37/00 ,  C07C5/48 ,  C07C45/35 ,  B01J11/06 ,  C07C121/32

    Abstract: An attrition-resistant oxidation catalyst comprising antimony oxide and at least one other metal oxide, where the metal may be U, Fe, Mn, Th, Ce, Mo, Sn is prepared by activating a catalyst comprising the combined oxides in an oxidizing atmosphere at a temperature of from 800-2000 DEG F., reducing the product to a powder, mixing the powder with water and an inert carrier material, drying, and heating the mixture preferably in a non-reducing or inert atmosphere at a temperature of from 750-2000 DEG F. The carrier material may be a silica sol derived from water glass or other silicates or silicon halides; phosphates of B, Al, Zr are also mentioned. Silica may be incorporated in the oxide mixture before activating at 800-2000 DEG F. Examples refer to oxides of (1) Sb+U, (2) Sb+Fe, (3) Sb+Th, (4) Sb+Ce, (5) Sb+Mo, (6) Sb+Mn, (7) Sb+Sn; all with SiO2 as carrier. The average particle size suitable for use in fluidized beds is stated to be below 20m . Extrudates of 4 mm. are also mentioned.

    7.
    发明专利
    未知

    公开(公告)号：NO115134B

    公开(公告)日：1968-08-05

    申请号：NO16015965

    申请日：1965-10-20

    Applicant: STANDARD OIL CO OHIO

    Inventor： GRASSELLI R ,  CALLAHAN J ,  MILBERGER E

    IPC: C07C47/22 ,  B01J8/26 ,  B01J21/08 ,  B01J23/00 ,  B01J23/12 ,  B01J23/18 ,  B01J35/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08

    Abstract: 1,126,617. Unsaturated aldehydes and nitriles. STANDARD OIL CO. 14 Oct., 1965 [4 Nov., 1964], No. 43643/65. Heading C2C. A process for the production of olefinically unsaturated nitriles and/or olefinically unsaturated aldehydes comprises introducing molecular oxygen into the bottom zone of a reaction enclosure comprising at least two communicating reaction zones at different levels each containing a fluidized solids catalyst capable of catalysing the reaction of olefines with molecular oxygen and optionally ammonia, the zones being separated by at least one foraminous member with at least some openings large enough to allow catalyst passage therethrough and the amount of open area in the foraminous members being at least 7.5 to 50% of the total internal cross-sectional area; introducing into a reaction zone other than that into which the molecular oxygen was introduced : (a) propylene or isobutylene, and, if the product is intended to be a nitrile, (b) ammonia; maintaining an elevated temperature throughout the reaction zones; passing the reactant vapours upwards through the communicating zones containing the fluidized catalyst; and recovering the product produced, the volume of the reaction enclosure upstream of the reaction zone receiving the component (a) and the optional component (b) being from 5 to 75% of the total volume of the enclosure. The catalyst is preferably composed of a mixture of antimony oxide and the oxide of at least one other polyvalent metal, such as uranium, iron, thorium, cerium and manganese. The production of acrylonitrile, methacrylonitrile, acrolein and methacrolein is described.

    8.
    发明专利
    未知

    公开(公告)号：SE301972B

    公开(公告)日：1968-07-01

    申请号：SE797666

    申请日：1966-06-10

    Applicant: STANDARD OIL CO OHIO

    Inventor： GRASSELLI R ,  CALLAHAN J

    IPC: B01J27/192 ,  C07C5/48 ,  C07C11/18

    Abstract: 1,154,029. Oxydehydrogenation catalyst. STANDARD OIL CO. 9 June, 1966 [10 June, 1965], No. 25829/66. Heading B1E. [Also in Division C5] A catalyst for the oxydehydrogenation of C 4 to C 10 monoolefins to conjugated dienes has the composition A a B b Fe c Bi d P e Mo f O 2 , where A is Group VIII transition metal other than Fe, B is at least one of Sb, Sn, Cu and As, and a is 0.1 to 12, b is 0 to 12, c is 0.1 to 12, d is 0.1 to 12, e is 0 to 12, f is 6 to 12, and the Mo@ may be at least partially replaced by W. The catalyst may be used alone or on a carrier material, for example silica, alumina, thoria, zirconia, titania, boron phosphate, silicon carbide, pumice, diatomaceous earth or clay ,the carrier being used in amount less than 95% by weight of the final catalyst composition. The catalysts may be made by dissolving soluble salts of the metals in water or acid and heating the mixture with an aqueous silica dispersion until a gel forms. The gel is heated to dry it then calcined in air.

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