METHOD OF MANUFACTURE FOR METHACRYLIC DERIVATIVES

    公开(公告)号:KR800001330B1

    公开(公告)日:1980-10-28

    申请号:KR770001767

    申请日:1977-08-01

    Abstract: Methacrolein and either methacrylonitrile or isobutylene were prepd. by ammoxidn. and dehydrogenation of methy1 tertBu ether or isobutylene dimer. Thus a slurry was prepd. from 1.29parts 85% H3PO4 and aq. solns. of NH4 heptamolybdate 47.5, Co(NH3)26H2O 29.4, Ni(NO3)26H2O 16.3, Fe(NO3)9H2O 27.2, Ni(NO3)35H2O 10.9, HNO31.5, and KNO3 0.16parts and 13.15 parts silica. The slurry was dried, calcined at 274-88≦̸C, mixed with 1% graphite, formed into tablets, and calcined 5 hr at 560≦̸C to give a catalyst of compn. 82.5% K0.07Ni2.5Co0.45Fe3Bip0.5Mo12O50-17.5% SiO2.

    OXIDATION CATALYSTS
    2.
    发明授权

    公开(公告)号:KR800000424B1

    公开(公告)日:1980-05-26

    申请号:KR750001572

    申请日:1975-07-19

    Abstract: Oxidation catalyst, useful for oxidation reaction such as oxidation of olefine, dehydrogenation and oxidation of methyl substituted aromatic compd., was prepd. by composing in the compd.(I; X = Y,Xr,Ag,S,Ce,Th,Pr,Ru,Ga,Ta,La; A = alkali metal,Tl,or its mixture;D = Ni,Co,Mg,Ca,Sr,Zn,Cd,or its mixture; E = P,As,B,W,Sb or its mixture ; O

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