公开(公告)号：CA1195340A

公开(公告)日：1985-10-15

申请号：CA384483

申请日：1981-08-24

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  HAASE THOMAS A

IPC: C07C53/124 ,  B01J27/00 ,  B01J31/00 ,  B01J31/28 ,  C07C51/00 ,  C07C51/14 ,  C07C67/00

Abstract: A process for the selective hydrocarboxylation of propylene to produce predominantly isobutyric acid in the liquid phase is provided. The reaction of propylene, carbon monoxide and water is effected at a temperature of about 75.degree.C to about 150.degree.C and at a pressure of about 250 psi to about 5000 psi in the presence of a suitable solvent and a catalyst comprising palladium or a palladium compound, a phosphoamine promoter ligand compound and a hydrogen halide.

公开(公告)号：CA1196472A

公开(公告)日：1985-11-12

申请号：CA431393

申请日：1983-06-29

Applicant: STANDARD OIL CO OHIO

Inventor： VELENYI LOUIS J ,  HARDMAN HARLEY F ,  PESA FREDERICK A

IPC: B01J23/00 ,  C01C3/02

Abstract: (5477) PROCESS FOR THE PRODUCTION OF HYDROGEN CYANIDE FROM CARBON MONOXIDE AND AMMONIA A process for producing HCN by contacting CO and NH3 with a catalyst comprising a porous catalyst support, a Group VIII metal which is at least one of Fe, Ni, Co and Ru, and carbon, wherein the metal is disposed on the pore surfaces of the support and the carbon is randomly bonded to the metal. 4819A

公开(公告)号：CA1195678A

公开(公告)日：1985-10-22

申请号：CA416328

申请日：1982-11-25

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  GRAHAM ANNE M

IPC: B01J23/89 ,  B01J27/24 ,  C07C1/04 ,  C07C9/00 ,  C07C29/157 ,  C07C29/158 ,  C07C31/04 ,  C07C31/08 ,  C07C51/10 ,  C07C27/06 ,  B01J23/70

Abstract: A process is provided for the upgrading of synthesis gas to hydrocarbons and oxygenated hydrocarbons, particularly olefins and carboxylic acids by contacting synthesis gas with catalysts comprising the mixed oxides of ruthenium, copper, an alkali or alkaline earth metal, and optionally a metal selected from Ce, Cr, Fe, Mn, Mo, Th, Zn or mixtures thereof. The synthesis gas upgrading product may be contacted with a hydrogenation catalyst to provide alkanes, alcohols and esters, useful for fuels. Catalysts comprising the mixed oxides of ruthenium, copper, at least one alkali metal and at least one of rhodium, iridium, palladium, and platinum are further provided which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.

公开(公告)号：CA1151669A

公开(公告)日：1983-08-09

申请号：CA361379

申请日：1980-10-02

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  GRAHAM ANNE M

IPC: C07C120/12

Abstract: Nitriles are prepared by contacting an activated olefin, e.g. methyl acrylate, with gaseous hydrogen cyanide in the presence of a catalyst containing an element selected from the group consisting of Group IA and IIA.

公开(公告)号：CA1135693A

公开(公告)日：1982-11-16

申请号：CA348989

申请日：1980-04-01

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  GRAHAM ANNE M

IPC: C07D223/10 ,  B01J23/00 ,  B01J23/64 ,  B01J23/84 ,  B01J23/89 ,  C07B61/00 ,  C07D201/02 ,  C07D201/08 ,  C07D207/263 ,  C07D211/76 ,  C07D207/26

Abstract: Five, six and seven member nitrogen-containing saturated heterocyclic compounds can be prepared by the catalytic hydrogenation/cyclization of beta, gamma and delta-cyanoesters. Applicants have discovered that this reaction is especially effective when it is conducted in the presence of catalysts comprising at least one of ruthenium and iron.

公开(公告)号：CA1195677A

公开(公告)日：1985-10-22

申请号：CA414804

申请日：1982-11-03

Applicant: STANDARD OIL CO OHIO

Inventor： BLASKIE MARCUS W ,  FOX JOSEPH R ,  PESA FREDERICK A

IPC: B01J21/08 ,  B01J23/00 ,  B01J23/46 ,  B01J23/60 ,  B01J23/648 ,  B01J23/652 ,  B01J23/656 ,  B01J23/89 ,  C07B61/00 ,  C07C27/00 ,  C07C29/16 ,  C07C31/02 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125 ,  C07C45/50 ,  C07C67/00 ,  C07C27/20 ,  C07C29/36

Abstract: Olefins, carbon monoxide and hydrogen are catalytically reacted with rhodium catalysts to produce alcohols in a single step reaction.

公开(公告)号：CA1153752A

公开(公告)日：1983-09-13

申请号：CA379230

申请日：1981-06-08

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  HAASE THOMAS A

IPC: B01J31/20 ,  B01J31/40 ,  B01J23/74 ,  B01J23/90

Abstract: (5239) A process is provided which includes the separation of a hydrocarboxylation-type catalyst together with the hydrocarboxylation solvent from a reaction mixture containing an oxygenated cyanocompound product, the hydrocarboxylation catalyst and the hydrocarboxylation solvent by contacting the reaction mixture with a hydrocarbon to form a hydrocarbon/ solvent conjugate phase, and separating the resulting hydrocarbon phase from the solvent phase.

公开(公告)号：CA1140557A

公开(公告)日：1983-02-01

申请号：CA352483

申请日：1980-05-22

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  HAASE THOMAS A

IPC: C07C47/02 ,  C07C69/24 ,  C07F15/00

Abstract: Oxygenated organic compounds, e.g. esters, aldehydes, and amides, are prepared by reacting an olefinically unsaturated compound with carbon monoxide and a compound containing a replaceable hydrogen atom in the presence of a catslyst comprising cobalt or ruthenium carbonyl and a promoter ligand. The promoter ligand is selected from the group consisting of heterocyclic nitrogen compounds and phosphorus or sulfur oxides. These reactions are carried out under relatively mild conditions of temperature and pressure.

公开(公告)号：CA1249988A

公开(公告)日：1989-02-14

申请号：CA493804

申请日：1985-10-24

Applicant: STANDARD OIL CO OHIO

Inventor： DESMOND MICHEAL J ,  PESA FREDERICK A ,  CURRIE JANIE K

IPC: C01B39/04 ,  B01J29/18 ,  C01B39/06 ,  C01B39/26 ,  C01B33/28

Abstract: A method is disclosed for making molecular sieving high silica mordenite comprising the steps of: (A) providing a mixture comprising: water; an oxide of silicon source; an oxide of aluminum source; a mineralizing agent; and a synthesis directing nitrogen containing organic dye; and (B) maintaining said mixture at a temperature of about 80.degree.C to about 300.degree.C for an effective period of time to provide said mordenite.

公开(公告)号：CA1181093A

公开(公告)日：1985-01-15

申请号：CA407002

申请日：1982-07-09

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  BURRINGTON JAMES D ,  PESA FREDERICK A ,  HARDMAN HARLEY F

IPC: B01J31/00 ,  B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07C67/00 ,  C07C253/00 ,  C07C255/04 ,  C07C255/09 ,  C07D307/60 ,  C07C121/26 ,  C07C121/30

Abstract: A novel process is provided for dimerizing acrylonitrile to 1,4-dicyanobutenes and/or adiponitrile which comprises compacting acrylonitrile with a catalyst at a temperature of 20 to 250.degree.C in the presence of hydrogen, the catalyst comprising a polymer support having a ruthenium complex bonded thereto, the polymer support comprising an organic polymer backbone having trivalent pendant atoms selected from P, As, Sb, Bi and N covalently bonded thereto and randomly distributed in the polymer.