Abstract:
본 발명은 석탄추출물 내의 황화합물을 제거하기 위하여 황 제거용 2차 용매 및 이를 이용한 황화합물 제거방법에 관한 것으로서, 상세하게는 석탄추출물에 수소공여제 역할을 하는 2차 용매를 도입하여 석탄추출물 내 황화합물을 황화수소 가스 형태로 제거하는 것을 특징으로 하는 황화합물 제거방법에 대한 것이다.
Abstract:
PURPOSE: The pretreatment method of a sulfur oxide selectivity absorber and a sulfur oxide selectivity absorber pre-treated thereby are provided to efficiently remove a sulfur oxide in a fraction in which the sulfur oxide is included and increase the breakthrough adsorption capacity of the sulfur oxide and breakthrough drainage by passing through a treatment process before adsorption. CONSTITUTION: The silica based pretreatment method of a sulfur oxide selectivity absorber includes a step for performing an acid treatment on the silica surface. The pretreatment method additionally includes a step for drying the acid-treated silica surface, and the drying temperature is 100 ~ 200>=. The acid includes any one of sulfuric acid, nitric acid, hydrochloric acid, acetic acid, and hydrofluoric acid or a mixture thereof. The concentration of the acid is 0.1 ~ 10M. The contact time of the silica surface and acid is 1 minutes ~2 hours.
Abstract:
PURPOSE: A sulfur oxide selectivity absorber and a pretreatment method thereof are provided to effectively remove a sulfur oxide in a fraction in which the sulfur oxide is included by using a non-standardized porous silica and increase the breakthrough adsorption capacity of the sulfur oxide and a breakthrough drainage by presenting detailed absorber treatment conditions like the pore size of silica, a surface area, a surface processing method, and a heat treatment temperature. CONSTITUTION: A sulfur oxide selectivity absorber is based on silica, and the silica is porous silica having the pore size of 4 ~ 9nm. The surface area of the silica is 300 ~ 600m^2/g. The pore volume of the silica is 0.01 ~ 0.3cm^2/g. The pretreatment method of the sulfur oxide selectivity absorber includes a step for the heat treatment of the silica, and the heat treatment temperature is 100 ~ 300>=. Preferably, the heat treatment temperature of the silica is 100 ~ 200>=.
Abstract:
PURPOSE: A real time analysis method the oxygen content in a reaction product in an organism originated lipid deoxygenation reaction process is provided to easily and rapidly measure the oxygen content in a reaction product which is a performance index and a key of a deoxygenation reaction so that a real time diagnosis can be easy. CONSTITUTION: A real time analysis method the oxygen content in a reaction product in an organism originated lipid deoxygenation reaction process is as follows. A part of a reaction product is inserted into a Fourier transform infrared rays analysis device. The oxygen content is calculated by converting measured an absorbance with respect to a carbonyl functional group at a specific frequency into the oxygen content. The measured absorbance with respect to the carbonyl functional group is 1,720cm. The absorbance with respect to the carbonyl functional group is converted so that the oxygen content is calculated according to a predetermined equation.
Abstract:
PURPOSE: A hydrocarbon producing method of lipid originated from organisms and hydrotalcite is provided to reduce the operational cost and the installation cost by producing hydrocarbon without using a precious metal catalyst or hydrogen. CONSTITUTION: A hydrocarbon producing method of lipid originated from organisms and hydrotalcite comprises the following steps: contacting raw materials with the hydrotalcite at 200~450deg C with the pressure of 0.1~15MPa; and removing oxygen through a decarboxylating or decarbonylating reaction. The hydrotalcite contains 30~80wt% of magnesium and the balance of aluminum oxide, and has the form of layered double hydroxide.
Abstract:
PURPOSE: An apparatus for removing ammonia from gas discharged during a carbon dioxide depositing process using an ammonia solution is provided to effectively remove the ammonia using the chemical irreversible reaction. CONSTITUTION: An apparatus for removing ammonia from gas discharged during a carbon dioxide depositing process using an ammonia solution comprises the following: an absorbing tower(20), a removal tower(30), a scrubber tower(50), a returning tower, and an ammonia removal device(10). The absorbing tower selectively absorbs carbon dioxide from exhaust gas using the ammonia solution. The removal tower degasses the carbon dioxide from the removal tower. The scrubber tower collects the gaseous ammonia from the absorbing tower. The returning tower separates the gaseous ammonia and water from the ammonia solution. The ammonia removal device removes the ammonia.
Abstract:
An olefin selective adsorbent using copper-based complex metal chloride is provided to manufacture an adsorbent showing the quantity of adsorbed olefin and selectivity equal to those of a silver-ion impregnated adsorbent. An olefin selective adsorbent is an adsorbent for absorbing/separating olefin from olefin/paraffin compound. Ferric chloride(FeCl2) of 5 through 29.9 wt% and cupric chloride(CuCl) of 5 through 23.4wt% are dipped into a substrate in which specific surface area is 100 m^2/g or greater. The substrate having large specific surface area is selected from MCM-41, MCM-48, SBA-15, SBA-16 and KIT-6 which are aluminosilica gel, silica gel, alumina and middle-sized porous silica.
Abstract:
A method and an apparatus for enrichment of ethylene from FCC(Fluid Catalytic Cracking) off-gas are provided to treat a large volume of off-gas by desorbing and recovering the ethylene using a desorbent after adsorbing ethylene onto an olefin selective adsorbent, and to protect an adsorbent used in the enrichment of ethylene by removing water contained in the off-gas through a pre-treatment adsorption process. A method for separating ethylene from FCC off-gas comprises: a pre-treatment process including an adsorption step of introducing FCC off-gas to adsorb water and a desorption step of introducing an ethylene removing stream exhausted from the ethylene separation process to clean and desorb the adsorbed water; and an ethylene adsorbing and separating process including an adsorption step of introducing the pre-treated FCC off-gas into an adsorption tower to adsorb ethylene, and sending non-adsorbed components and an adsorbent in the adsorption tower to a distillation tower for separating the ethylene removing stream and an adsorbent, an ethylene cleaning step of introducing a portion of high concentration olefin obtained from an ethylene enriched stream/desorbent distillation tower into the adsorption tower to increase the purity of ethylene, and a desorption step of introducing a desorbent into the adsorption tower to desorb ethylene and sending the desorbed ethylene to a distillation tower for separating a mixture of the ethylene enriched stream and the desorbent to produce an ethylene enriched stream.