公开(公告)号：KR101435910B1

公开(公告)日：2014-09-02

申请号：KR1020120126643

申请日：2012-11-09

Applicant: 한국에너지기술연구원

Inventor： 정태성 ,  김종남 ,  범희태 ,  한상섭 ,  윤형철 ,  양수현 ,  문철호

IPC: B01J20/06 ,  C01B32/50

CPC classification number: B01D53/1493 ,  B01D53/1475 ,  B01D2252/102 ,  B01D2252/204 ,  B01D2252/504 ,  B01D2252/602 ,  B01D2258/0283 ,  Y02C10/06

Abstract: 본 발명은 이산화탄소를 포함하는 석탄화력발전소 연소배가스로부터 이산화탄소를 흡수하는데 사용되는 개선된 이산화탄소 흡수용 조성물로서 암모니아수로부터 암모니아의 증발을 억제하고 이산화탄소 흡수 속도를 개선할 수 있는 이산화탄소 흡수용 조성물 및 이를 사용하는 이산화탄소의 흡수 방법 및 장치에 관한 것이다.

公开(公告)号：KR101398569B1

公开(公告)日：2014-05-23

申请号：KR1020130001224

申请日：2013-01-04

Applicant: 한국에너지기술연구원

Inventor： 장진영 ,  우영민 ,  이영재 ,  조종표 ,  김강출 ,  표영덕 ,  김종남 ,  윤형철 ,  유지행 ,  주종훈

IPC: F01N3/28 ,  F01N3/20 ,  B01D53/94

CPC classification number: Y02A50/2325 ,  F01N3/2053 ,  B01D53/94 ,  F01N3/28 ,  F01N13/009 ,  F01N2570/14

Abstract: The present invention relates to a catalyst purification device for the engine of a vehicle capable of purifying ammonia slip using an ammonia oxidation catalyst (AOC) according to the structure of an exhaust gas path and a control method thereof. More specifically, the present invention can oxidize the ammonia slip used not to be oxidized to a catalyst or an SCR catalyst by purifying the ammonia slip of exhaust gas caused from an engine for a vehicle, which is operated by each of fuel for a spark ignition engine and liquid ammonia fuel or mixing them, using an AOC catalyst device according to the set conditions of a vehicle and the exhaust gas, and can emit the lower amount of NOX caused when ammonia is oxidized than the emission standard of harmful ingredients of the exhaust gas because the minimum amount of the NOX is emitted to the outside by purifying the NOX using a second catalyst device; thereby preventing environmental contamination. Also, the present invention can minimize the amount of the ammonia emitted to the atmosphere since the activation hours of the catalyst is reduced by positioning an AOC catalyst close to the engine with a primary catalyst, and can extend the life of the catalyst since the catalyst is protected by changing the path if there is a possibility that the AOC catalyst is damaged by the high temperature of the exhaust gas.

Abstract translation: 本发明涉及一种能够根据排气路径的结构使用氨氧化催化剂（AOC）净化氨气的车辆用发动机的催化剂净化装置及其控制方法。 更具体地说，本发明可以通过净化由用于火花点火的燃料中的每一种操作的用于车辆的发动机引起的排气的氨气滑动，将不被氧化的氨滑移氧化成催化剂或SCR催化剂 发动机和液氨燃料或混合它们，使用AOC催化剂装置根据车辆的设定条件和废气，并且可以发出氨排放时比排气的有害成分的排放标准氧化的较低量的NOX 气体，因为通过使用第二催化剂装置净化NO x将NO x的最少量排放到外部; 从而防止环境污染。 另外，由于催化剂的活化时间通过用主催化剂将AOC催化剂靠近发动机定位而减少了催化剂的活化时间，本发明可以使氨的量最小化，并且可延长催化剂的寿命，因为催化剂 如果存在AOC催化剂被废气的高温破坏的可能性，则通过改变路径来保护。

公开(公告)号：KR101392828B1

公开(公告)日：2014-05-08

申请号：KR1020120139423

申请日：2012-12-04

Applicant: 한국에너지기술연구원

Inventor： 주종훈 ,  유지행 ,  윤형철 ,  김종남 ,  우영민 ,  장진영

IPC: C01C1/04 ,  B01J7/00

CPC classification number: C01C1/04 ,  C25B1/00 ,  C25B11/035 ,  C25B13/04

Abstract: The present invention relates to a method for producing ammonia, wherein the ammonia is produced from water vapor and nitrogen gas supplied together, while carrying out a reforming process of hydrocarbon based fuel gas through a ion-conducting gas separation membrane by receiving oxygen absorbed in the reforming process of hydrocarbon based fuel gas from water vapor supplied to the opposite side to the side to which the hydrocarbon based fuel gas of the gas separation membrane is supplied through an ion permeation method. The method of the present invention comprises: a step of supplying hydrocarbon based fuel gas, while maintaining the temperature of 500°C to 700°C in a device for producing ammonia of which an inner space is divided into a first space and a second space by a gas separation membrane, which is a border, to allow one side of the gas separation membrane to contact with the first space; a step of supplying water vapor (H_2O) and nitrogen (N_2) gas with the pressure of 1 to 10 atm to allow the other side of the gas separation membrane to contact with the second space; a step of obtaining synthesis gas, which is a reaction product generated in the first space; and a step of obtaining ammonia which is produced in the second space. The method for producing ammonia of the present invention can produce ammonia from water vapor and nitrogen without electric energy supplied from outside as well as has an advantage of reforming hydrocarbon based fuel gas at the same time.

Abstract translation: 本发明涉及一种生产氨的方法，其中氨是由一起供应的水蒸汽和氮气产生的，同时通过离子导电气体分离膜通过接收在 从供给到通过离子渗透法供给气体分离膜的烃系燃料气体的一侧的相反侧的水蒸气的烃系燃料气体的重整工序。 本发明的方法包括：在内部空间被分成第一空间和第二空间的生产氨的装置中同时保持500℃至700℃的温度的同时供给烃类燃料气体的步骤 通过作为边界的气体分离膜，允许气体分离膜的一侧与第一空间接触; 提供1〜10大气压的水蒸气（H_2O）和氮（N_2）气体，使气体分离膜的另一侧与第二空间接触的步骤; 获得作为在第一空间中产生的反应产物的合成气的步骤; 以及获得在第二空间中产生的氨的步骤。 本发明的生产氨的方法可以从水蒸汽和氮气中产生氨，而不会从外部供应电能，同时具有重整烃基燃料气体的优点。

公开(公告)号：KR101354905B1

公开(公告)日：2014-01-24

申请号：KR1020120028734

申请日：2012-03-21

Applicant: 한국에너지기술연구원

Inventor： 박종호 ,  정태성 ,  윤형철 ,  곽영태 ,  범희태 ,  박종기 ,  한상섭 ,  김종남 ,  조순행

IPC: C01B13/02 ,  B01J3/03 ,  B01J19/24 ,  B01D53/54

CPC classification number: B01D53/0476 ,  B01D53/0423 ,  B01D53/0438 ,  B01D2251/402 ,  B01D2251/408 ,  B01D2251/606 ,  B01D2253/112 ,  B01D2253/1124 ,  B01D2256/12 ,  B01D2257/104 ,  B01D2259/402 ,  B01J20/043 ,  C01B13/0262

Abstract: 본 발명은 연속 산소 흡탈착 장치 및 이를 이용한 연속 산소 흡탈착 방법에 관한 것으로서, 보다 자세하게는 BaMg(CO
3 )
2 입자 또는 BaMg(CO
3 )
2 의 외부에 MgCO
3 또는 Mg(OH)
2 가 부착된 입자에서 선택된 산소 선택성 흡탈착제가 충진된 다수의 흡탈착탑을 이용하여 고순도의 산소 제품을 생산하기 위한 연속 산소 흡탈착 장치 및 이를 이용한 연속 산소 흡탈착 방법에 관한 것이다. 본 발명에 따른 연속 산소 흡탈착 장치 및 이를 이용한 연속 산소 흡탈착 방법은 산소 혼합기체에 포함된 산소에 대한 흡착 선택성을 향상시켜 고순도의 산소 제품이 생산되도록 한 것으로써, 상기 압력변동흡착장치의 각 흡착관 내에 충진되는 흡탈착제를 BaMg(CO
3 )
2 입자 또는 BaMg(CO
3 )
2 의 외부에 MgCO
3 또는 Mg(OH)
2 가 부착된 입자로 사용함으로써 산소의 흡착 효율을 향상시킬 수 있는 장점이 있다. 더불어, 본 발명은 산소 흡탈착 공정 과정에서 최종 압력을 진공으로 유지시킴에 의해서 산소 회수율을 향상시키는 작용효과가 발휘된다.

公开(公告)号：KR1020140003260A

公开(公告)日：2014-01-09

申请号：KR1020120071377

申请日：2012-06-29

Applicant: 한국에너지기술연구원

Inventor： 박종호 ,  박종기 ,  윤형철 ,  정태성 ,  범희태

IPC: F25J1/00 ,  F25J5/00

CPC classification number: F25J1/0022 ,  F25J1/0052 ,  F25J1/0055 ,  F25J1/0214 ,  F25J1/0216 ,  F25J1/0262 ,  F25J1/0292

Abstract: A natural gas liquefaction system of the present invention comprises a pre-cooling unit, a gas and liquid separation unit, a first heat exchanging unit, a second heat exchanging unit, a first expansion unit, a second expansion unit, a first mixed refrigerant conversion unit, a pre-cooling refrigerant supplying unit, a natural gas supplying unit, and a mixer. A natural gas liquefaction method of the present invention comprises a first pre-cooling step (S01), a first mixed refrigerant separation step (S02), a first introduction step (S03), a first expansion refrigerant formation step (S04), a second introduction step (S05), a second expansion refrigerant formation step (S06), and a second freezing step (S07).

Abstract translation: 本发明的天然气液化系统包括预冷单元，气液分离单元，第一热交换单元，第二热交换单元，第一膨胀单元，第二膨胀单元，第一混合制冷剂转化器 单元，预冷却制冷剂供给单元，天然气供给单元和混合器。 本发明的天然气液化方法包括第一预冷却步骤（S01），第一混合制冷剂分离步骤（S02），第一引入步骤（S03），第一膨胀制冷剂形成步骤（S04），第二 引入步骤（S05），第二膨胀制冷剂形成步骤（S06）和第二冷冻步骤（S07）。

公开(公告)号：KR1020130129597A

公开(公告)日：2013-11-29

申请号：KR1020120053615

申请日：2012-05-21

Applicant: 한국에너지기술연구원 ,  에코바이오홀딩스 주식회사

Inventor： 김종남 ,  정태성 ,  윤형철 ,  박종호 ,  범희태 ,  송효순 ,  오석환

IPC: B01D53/14 ,  B01D53/46

CPC classification number: B01D53/1493 ,  B01D53/46 ,  B01D2257/7025

Abstract: This invention relates to at least one absorbent additive selected from DEPG and NMP which are additives added to an absorbent for an absorbing process separating methane from the biogas and the process separating methane gas from biogas. By using the absorbent additives, the pressure of the biogas being introduced to an absorption tower while the absorption amount of carbon dioxide is maintained, thereby reducing the cost of compression, and the absorption amount of carbon dioxide is maintained even when absorption temperature at the same absorption pressure is increased, thereby saving the cooling cost of absorbent.

Abstract translation: 本发明涉及至少一种选自DEPG和NMP的吸收剂，它们是添加到用于从沼气中分离甲烷的吸收方法的吸收剂中的添加剂和从沼气中分离甲烷气体的方法。 通过使用吸收剂添加剂，在保持二氧化碳的吸收量的同时将生物气体的压力引入吸收塔，从而降低压缩成本，并且即使在相同的吸收温度下也保持二氧化碳的吸收量 吸收压力增加，从而节省吸收剂的冷却成本。