93.
    发明专利
    未知

    公开(公告)号:AT151765T

    公开(公告)日:1997-05-15

    申请号:AT91920675

    申请日:1991-11-29

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP91/02268 Sec. 371 Date Jun. 7, 1993 Sec. 102(e) Date Jun. 7, 1993 PCT Filed Nov. 29, 1991 PCT Pub. No. WO92/10489 PCT Pub. Date Jun. 25, 1992.2-Amino-4-oxo-4H-benzopyrans I I (m=0, 1 or 2; R1-R4 have the meanings stated in the description) and the salts of I, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and 2-amino-4-oxo-4H-benzopyrans I' as antidotes.

    PROCESS FOR PRODUICNG 3-METHYLQUINOLINE-8-CARBOXYLIC ACID AND ITS DERIVATIVES

    公开(公告)号:HU205081B

    公开(公告)日:1992-03-30

    申请号:HU583390

    申请日:1990-09-07

    Applicant: BASF AG

    Abstract: Process for the preparation of 3-methylquinoline-8-carboxylic acid I and its derivatives by reacting o-toluidine II or its derivatives with methacrolein III in the presence of iodine or an iodine compound, in 70-90% by weight sulphuric acid, and oxidation of the resulting 3,8-dimethylquinoline IV or its derivatives with nitric acid in a solution of sulphuric acid in the presence of vanadium ions, characterised in that, in a first step, the by-products of the reaction are decomposed by oxidation in the reaction solution of 3,8-dimethylquinoline IV in sulphuric acid, the resulting 3,8-dimethylquinoline solution is concentrated by distillation, and subsequently the 3,8-dimethylquinoline is oxidised in situ with nitric acid to give 3-methylquinolinecarboxylic acid.

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