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公开(公告)号:DE3169510D1
公开(公告)日:1985-05-02
申请号:DE3169510
申请日:1981-05-11
Applicant: BASF AG
Inventor: MAROSI LASZLO DR , SCHLIMPER HANS-ULRICH DR , SCHWARZMANN MATTHIAS DR , STABENOW JOACHIM DR
Abstract: A process for the preparation of zeolites of the ZSM-5 structural type from a mixture of SiO2 and Al(OH)3 by hydrothermal crystallization in an aqueous amine solution, in the absence of alkali, at from 100 DEG to 200 DEG C., wherein the crystallization is carried out in the presence of a triamine, tetraamine and/or higher amine and the reaction mixture is formulated to have an SiO2/Al2O3 molar ratio defined by an equation which involves the chain length and number of amine groups of the amine employed, as well as to have certain molar ratios of H2O/amine and amine/Al2O3, and the use of these zeolites as catalysts for the conversion of alcohols and/or dialkyl ethers to olefins and/or aromatics.
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公开(公告)号:DE3300982A1
公开(公告)日:1984-07-19
申请号:DE3300982
申请日:1983-01-14
Applicant: BASF AG
Abstract: The application relates to a process for the preparation of olefins by reaction of methanol and/or dimethyl ether in the presence of zeolite catalysts at elevated temperature, in which, as catalysts, borosilicate zeolites are used which are shaped with binder mixtures of silica and alumina whose aluminium content is
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公开(公告)号:DE2965077D1
公开(公告)日:1983-04-28
申请号:DE2965077
申请日:1979-10-18
Applicant: BASF AG
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公开(公告)号:DE2861030D1
公开(公告)日:1981-11-26
申请号:DE2861030
申请日:1978-11-11
Applicant: BASF AG
Inventor: MROSS WOLF DIETER DR , TITZENTHALER ECKART DR , KOOPMANN JUERGEN DR , SCHWARZMANN MATTHIAS DR , VOGT VOLKER DR
IPC: B01J23/66 , B01J23/78 , B01J31/22 , C07B61/00 , C07D301/10 , C07D303/04
Abstract: A catalyst for the manufacture of ethylene oxide, giving improved yield and having a long life, based on an alkali metal-modified silver catalyst on an oxide carrier is obtained by providing the silver-containing catalyst, in the reduced state, with the alkali metal by applying an alcoholic alkali metal salt solution which also contains an organic oxygen compound or nitrogen compound which forms complexes with silver ions.
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公开(公告)号:DE2654028A1
公开(公告)日:1978-06-01
申请号:DE2654028
申请日:1976-11-27
Applicant: BASF AG
Inventor: FRANK GERHARD DR , KAEMPFER KNUT DR , SCHWARZMANN MATTHIAS DR
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公开(公告)号:DE2228332A1
公开(公告)日:1974-01-10
申请号:DE2228332
申请日:1972-06-10
Applicant: BASF AG
Inventor: BROECKER FRANZ JOSEF DR , HENERS JUERGEN DR , MAROSI LASZLO DR , SCHWARZMANN MATTHIAS DR , LAURER PETER RUDOLF DR
IPC: B01J23/72 , B01J23/74 , B01J23/745 , C11C3/12 , B01J11/22
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公开(公告)号:DE2022820A1
公开(公告)日:1972-01-13
申请号:DE2022820
申请日:1970-05-11
Applicant: BASF AG
Inventor: JOERG DR HARTMANN HANS , WILHELM DR LEONHARD KARL , OHLINGER MANFRED DR , SCHWARZMANN MATTHIAS DR
Abstract: 1345039 Chromium dioxide BADISCHE ANILIN- & SODA-FABRIK AG 10 May 1971 [11 May 1970] 13959/71 Heading C1A [Also in Division H1] Ferromagnetic chromium dioxide is made by heating chromium trioxide at 250-500‹ C. and 50-3000 ats. in presence of water, acicular crystals of iron and/or iron oxides (0À1-10 wt. per cent based on CrO 3 ) and at least one other modifying element (in elemental or compound form). The total amount of modifying elements (calculated as elemental form) present may be 0À2-25 wt. per cent based on CrO 3 . Specified foreign elements are metals of Groups 5A and 6A, P, As, Sb, Se, Te and Ni. The iron may be present as γ-Fe (III) oxide or α-FeOOH (2À5:1 to 10:1 aspect ratio, 0À4-1 Á). The chromium dioxide may be made by a one-stage process, involving heating CrO 3 , H 2 O and additives at 280-350‹ C. and 150-700 ats. for 1 to 10 hours. Alternatively, in a two-stage process, the CrO 3 is heated to 300-360‹ C. for 30-60 mins., and then 280-500‹ C. for 10 mins to 10 hours, a pressure of 50-300 ats. being maintained in the latter stage, and the foreign elements being added at either stage. In examples, the modifying compounds are (1) TeO 2 +γ-Fe 2 O 3 ; (2) Sb 3 O 3 +α-FeOOM; (3) TeO 2 +α-FeOOM; (4) TeO 2 +Fe; (5) Sb 2 O 3 +α-Fe 2 O 3 ; (6) Sb 2 O 3 + γ-Fe 2 O 3 .
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公开(公告)号:DE1768239A1
公开(公告)日:1971-10-28
申请号:DE1768239
申请日:1968-04-19
Applicant: BASF AG
Inventor: SCHWARZMANN MATTHIAS DR , GOTSMANN GUENTHER DR
IPC: C07F9/54
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