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公开(公告)号:DE2861030D1
公开(公告)日:1981-11-26
申请号:DE2861030
申请日:1978-11-11
Applicant: BASF AG
Inventor: MROSS WOLF DIETER DR , TITZENTHALER ECKART DR , KOOPMANN JUERGEN DR , SCHWARZMANN MATTHIAS DR , VOGT VOLKER DR
IPC: B01J23/66 , B01J23/78 , B01J31/22 , C07B61/00 , C07D301/10 , C07D303/04
Abstract: A catalyst for the manufacture of ethylene oxide, giving improved yield and having a long life, based on an alkali metal-modified silver catalyst on an oxide carrier is obtained by providing the silver-containing catalyst, in the reduced state, with the alkali metal by applying an alcoholic alkali metal salt solution which also contains an organic oxygen compound or nitrogen compound which forms complexes with silver ions.
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公开(公告)号:DE2751767A1
公开(公告)日:1979-05-23
申请号:DE2751767
申请日:1977-11-19
Applicant: BASF AG
Inventor: MROSS WOLF-DIETER DR , TITZENTHALER ECKART DR , KOOPMANN JUERGEN DR , SCHWARZMANN MATTHIAS DR , VOGT VOLKER DR
IPC: B01J23/66 , C07D301/10 , C07D303/04
Abstract: A catalyst for ethylene oxide prodn. is prepd. by gas-phase reaction of ethylene with O2. The catalyst comprises a support, 2-12% Ag, and (based on Ag) 0.05-0.35 atom % K, 0.003-0.25 atom % Rb, 0.0005-0.2 atom % Cs or an equiv. amt. of a mixt. of these alkali metals. The process comprises impregnating the Ag-contg. support (opt. also contg. Na and/or Li) with a soln. (pref. alcoholic) contg. a cpd. of K, Rb and/or Cs and an amine and/or ammonia. The presence of an amine and/or ammonia in the impregnation soln. improves the selectively of the catalyst. The process is applicable to fresh catalysts rather than used or thermally stabilised catalysts.
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公开(公告)号:AT265223B
公开(公告)日:1968-10-10
申请号:AT154967
申请日:1967-02-16
Applicant: BASF AG
Inventor: WEITZ HANS-MARTIN DR , HAUSDOERFER BERTHOLD DR , KOOPMANN JUERGEN DR
Abstract: 1,168,695. Mixing apparatus. BADISCHE ANILIN-& SODA-FABRIK A.G. 15 Feb., 1967 [16 Feb., 1966], No. 7234/67. Heading B1C. [Also in Division C2] An apparatus for mixing gases, e.g. bromine and butadiene, in such a way as to produce turbulent flow (the Reynold number being above 2300), comprises a loop-shaped reactor 4 into which the gases are continuously introduced via nozzles 3 and 7 at such a velocity that the impulse transmitted to the gas causes it to circulate. The gases may be produced by evaporating liquids stored in tanks 1 and 5. Any liquid condensing in the bottom of the reactor may be recirculated via pump 9, condenser 10 and nozzle 8; discharge is effected through tank 11.
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公开(公告)号:DE4435176A1
公开(公告)日:1996-04-04
申请号:DE4435176
申请日:1994-09-30
Applicant: BASF AG
Inventor: GROENING CARSTEN DR , EBEL KLAUS DR , KAIBEL GERD DR , THERRE JOERG DR , KOOPMANN JUERGEN DR , MENIG HELMUTH DR , FRITZ GERHARD DR , DIETZ RAINER
Abstract: Prepn. of methyl glyoxal dimethyl acetal comprises reacting methyl glyoxal and methanol in the presence of a catalyst, in which the acetal is recovered by heating in the presence of water to bring about azeotropic distillation.
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公开(公告)号:DE2150690A1
公开(公告)日:1973-04-19
申请号:DE2150690
申请日:1971-10-12
Applicant: BASF AG
Inventor: RENAUER ERICH DR , SCHNEIDER CURT DR , WIRTH FRIEDRICH DR , KOOPMANN JUERGEN DR , SUTER HUBERT DR , AMMON HANS V DIPL-ING , POEHLER GUENTHER DR
IPC: C07D307/60 , B01J27/00 , C07B61/00 , C07C51/215 , C07C51/25 , C07C57/14
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公开(公告)号:DE2641000A1
公开(公告)日:1978-03-16
申请号:DE2641000
申请日:1976-09-11
Applicant: BASF AG
Inventor: MROSS WOLF DIETER DR , TITZENTHALER ECKART DR , SCHARZMANN MATTHIAS DR , KOOPMANN JUERGEN DR
IPC: B01J23/66 , C07D301/10 , C07D303/02
Abstract: Catalysts for ethylene oxide prepn. from ethylene and O2 comprise Ag and alkali metals or their cpds. deposited on a support. The catalysts contain (a) 0.1-2 atom % Na and (b) either 0.05-0.35 atom % K, 0.003-0.25 atom % Rb, 0.0005-0.2 atom % Cs or a corresp. amt. of a mixt. thereof. All percentages are based on the Ag content. The Ag content is pref. 2-12 (esp. 5-10) wt.% based on the wt. of the catalyst. The catalysts are pref. prepd. by impregnating the support with an aq. soln. of an Ag complex salt (e.g. an Ag-amine carboxylate) and suitable alkali metal cpds. (e.g. hydroxides), steaming the resulting composite until the Ag cpd. decomposes, and calcining the product at 100-400 degrees C to constant wt. Other standard methods can also be used. The catalysts have higher activity and selectivity than conventional Ag catalysts promoted with alkali(ne earth) metals, and/or have a longer life.
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公开(公告)号:DE2622228A1
公开(公告)日:1977-12-08
申请号:DE2622228
申请日:1976-05-19
Applicant: BASF AG
Inventor: MROSS WOLF DIETER DR , TITZENTHALER ECKART DR , SCHWARZMANN MATTHIAS DR , KOOPMANN JUERGEN DR
IPC: B01J23/66 , C07D301/10
Abstract: Catalysts for ethylene oxide prepn. from ethylene and O2 comprise Ag and alkali metals or their cpds. deposited on a support. The catalysts contain (a) 0.1-2 atom % Na and (b) either 0.05-0.35 atom % K, 0.003-0.25 atom % Rb, 0.0005-0.2 atom % Cs or a corresp. amt. of a mixt. thereof. All percentages are based on the Ag content. The Ag content is pref. 2-12 (esp. 5-10) wt.% based on the wt. of the catalyst. The catalysts are pref. prepd. by impregnating the support with an aq. soln. of an Ag complex salt (e.g. an Ag-amine carboxylate) and suitable alkali metal cpds. (e.g. hydroxides), steaming the resulting composite until the Ag cpd. decomposes, and calcining the product at 100-400 degrees C to constant wt. Other standard methods can also be used. The catalysts have higher activity and selectivity than conventional Ag catalysts promoted with alkali(ne earth) metals, and/or have a longer life.
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公开(公告)号:AT260894B
公开(公告)日:1968-03-25
申请号:AT472866
申请日:1966-05-18
Applicant: BASF AG
Inventor: WEITZ HANS-MARTIN DR , MERGER FRANZ DR , KOOPMANN JUERGEN DR
Abstract: 1,140,131. 1,4 - Dicyanobutene - (2). BADISCHE ANILIN- & SODA-FABRIK A.G. 18 May, 1966 [19 May, 1965], No. 22063/66. Heading C2C. [Also in Division C1] 1,4 - Dicyanobutene - (2) is obtained by reacting at an elevated temperature 1,2- dibromobutene-(3) and/or 1,4-dibromobutene- (2) with at least the stoichiometric amount of HCN in the presence of a copper salt in an aqueous acid medium at a pH of - 1 to + 3 using a buffer substance which exhibits buffering action in the said pH range as an acid acceptor, the acid acceptor being present in an amount of at least 1 equivalent per mole of dibromobutene, separating the resultant 1,4-dicyanobutene-(2) from the reaction mixture, oxidizing the HBr present in the aqueous solution to elementary Br 2 , separating Br 2 and returning the aqueous solution containing the acid acceptor to the reaction. The reaction may be carried out continuously or batchwise. The acid acceptors specified are alkali metal salts or alkaline earth salts of medium strength acids. The reaction solution may contain catalysts for the reoxidation of the bromine anions. Examples are given for the production of 1,4- dicyanobutene-(2) and an apparatus is described which is suitable for carrying out the continuous process.
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公开(公告)号:DE3061082D1
公开(公告)日:1982-12-23
申请号:DE3061082
申请日:1980-02-04
Applicant: BASF AG
Inventor: MROSS WOLF DIETER DR , TITZENTHALER ECKART DR , KOOPMANN JUERGEN DR , VOGT VOLKER DR , SCHWARZMANN MATTHIAS DR
IPC: B01J23/66 , B01J23/96 , B01J38/48 , C07B61/00 , C07D301/10
Abstract: Supported catalysts containing silver and alkali metals, for the preparation of ethylene oxide from ethylene and oxygen in the gas phase, are prepared or regenerated by modifying, respectively, a new or spent supported catalyst which already contains metallic silver and may or may not contain the light alkali metals lithium and/or sodium and, where a spent catalyst is concerned, also contains the heavy alkali metals potassium, rubidium and/or cesium, with a solution containing the heavy alkali metals, the modifier solution used containing (a) a surfactant and/or a reducing agent, in the case of the preparation of a new catalyst or (b) a surfactant, in the case of the regeneration of a spent catalyst.
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公开(公告)号:DE2819595A1
公开(公告)日:1978-12-07
申请号:DE2819595
申请日:1978-05-05
Applicant: BASF AG
Inventor: MROSS WOLF-DIETER DR , TITZENTHALER ECKART DR , KOOPMANN JUERGEN DR , VOGT VOLKER DR , SCHWARZMANN MATTHIAS DR
IPC: B01J23/66 , C07B61/00 , C07D301/10 , B01J23/50 , C07D303/04
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