公开(公告)号：WO2014118054A1

公开(公告)日：2014-08-07

申请号：PCT/EP2014/051226

申请日：2014-01-22

Applicant: BASF SE

Inventor： GAAB, Manuela ,  KOSTUR, Milan ,  MÜLLER, Ulrich

IPC: B01J2/06 ,  B01J2/14 ,  B01J20/22 ,  B01J20/28 ,  B01J20/30

CPC classification number: B01J20/3078 ,  B01J20/226 ,  B01J20/28019 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3042 ,  B01J20/305 ,  C07C7/12

Abstract: The present invention relates to a method for preparing a MOF shaped body in the form of spheres, MOF shaped bodies in the form of spheres and the use of MOF shaped bodies in the form of spheres.

Abstract translation: 本发明涉及一种制备球体形式的MOF形体的方法，MOF形体以球体的形式，以及以球体形式使用的MOF形体。

公开(公告)号：WO2014068135A1

公开(公告)日：2014-05-08

申请号：PCT/EP2013/073020

申请日：2013-11-05

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  TELES, Joaquim, Henrique ,  VAUTRAVERS, Nicolas ,  HINRICHSEN, Bernd ,  COX, Gerhard ,  JACUBINAS, Richard

IPC: C01B39/48

CPC classification number: C01B39/48 ,  B01J29/7088 ,  B01J29/86 ,  B01J37/0045 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C07F7/22

Abstract: A tin containing zeolitic material having an MWW-type framework structure (Sn-MWW), having a tin content of at most 2 weight-%, calculated as element and based on the weight of the Sn-MWW, and having an X-ray diffraction pattern comprising peaks at 2 theta diffraction angles of (6.6 ± 0.1 ) °, (7.1 ± 0.1 ) °, and (7.9 ± 0.1 ) °.

Abstract translation: 具有MWW型骨架结构（Sn-MWW）的含锡沸石材料，锡含量为至多2重量％，以元素计，并以Sn-MWW的重量计，并具有X射线 （6.6±0.1）°，（7.1±0.1）°和（7.9±0.1）°的2θ衍射角处的峰的衍射图案。

公开(公告)号：WO2014060261A1

公开(公告)日：2014-04-24

申请号：PCT/EP2013/071042

申请日：2013-10-09

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  YANG, Jeff ,  MAURER, Stefan ,  GAAB, Manuela ,  SEIDEL, Karsten ,  GERLACH, Olga ,  MÜLLER, Ulrich

IPC: C01B37/00 ,  C01B39/02 ,  C01B39/12

CPC classification number: C01B37/007 ,  B01J29/7038 ,  C01B39/026 ,  C01B39/12

Abstract: A process for the post-treatment of a zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure, wherein the framework structure of the zeolitic material comprises X 2 O 3 and YO 2 , wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X 2 O 3 : YO 2 is greater than 0.02 : 1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X 2 O 3 : YO 2 of at most 0.02 : 1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75 °C.

Abstract translation: 一种用于后处理具有MWW骨架结构的沸石材料的方法，该方法包括（i）提供具有MWW骨架结构的沸石材料，其中沸石材料的骨架结构包含X 2 O 3和YO 2，其中Y是 四价元素，X是三价元素，其中X 2 O 3 :YO 2的摩尔比大于0.02:1; （ii）用液体溶剂系统处理（i）中提供的沸石材料，从而获得摩尔比X2O3：YO2至多0.02:1的沸石材料，并至少部分地将沸石材料与液体溶剂系统分离; （iii）用pH为5.5〜8，温度为至少75℃的液态水系统处理由（ⅱ）得到的沸石材料。

公开(公告)号：WO2014057416A1

公开(公告)日：2014-04-17

申请号：PCT/IB2013/059194

申请日：2013-10-08

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： WEICKERT, Mathias ,  MARX, Stefan ,  MÜLLER, Ulrich ,  RENZE, Peter ,  WINKLER, Christian-Andreas

IPC: F17C11/00

CPC classification number: F17C11/007

Abstract: Method of charging a sorption store with a gas, where the sorption store comprises a closed container (10) which is at least partly filled with an adsorption medium (40) and has an inlet (21 ) and an outlet (23) which can each be closed by a shut-off element (22, 24), which comprises the steps: (a) closing of the outlet shut-off element (24) and opening of the inlet shut-off element (22), (b) introduction of gas to be stored under a predetermined pressure through the inlet (21 ), (c) rapid opening of the outlet shut-off element (24) with the inlet shut-off element (22) open so that a gas flow having a predetermined flow rate is established in the container (10), (d) reduction of the flow rate as a function of the adsorption rate of the gas adsorbed in the store and (e) complete closing of the outlet shut-off element (24).

Abstract translation: 用气体填充吸附储存器的方法，其中吸附储存器包括至少部分地填充有吸附介质（40）的密闭容器（10），并具有可以各自的入口（21）和出口（23） 由关闭元件（22,24）关闭，其包括以下步骤：（a）关闭出口切断元件（24）并打开入口切断元件（22），（b）引入 通过入口（21）在预定压力下储存的气体，（c）使入口切断元件（22）打开以快速打开出口截止元件（24），使得具有预定的 在容器（10）中建立流量，（d）作为吸附在储存器中的气体的吸附速率的函数的流量的降低，以及（e）出口截止元件（24）的完全关闭。

公开(公告)号：WO2014045135A1

公开(公告)日：2014-03-27

申请号：PCT/IB2013/056778

申请日：2013-08-21

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： MAURER, Stefan ,  MÜLLER, Ulrich ,  SWAMINATHAN, Vijay Narayanan ,  HINDALEKAR, Shrirang Bhikaji ,  PANDYA, Amal

IPC: C07C15/54 ,  C07C69/76 ,  C07F3/02 ,  B01D53/04 ,  B01J20/22 ,  B01J31/16

CPC classification number: C07F3/02 ,  C07C65/19 ,  C07C69/92 ,  C07C69/94 ,  C07F7/0818 ,  Y02C20/20

Abstract: The present invention relates to acetylene bridged linkers, metal-organic frameworks produced thereof, processes for producing the linkers and the MOFs and their use.

Abstract translation: 本发明涉及乙炔桥连接体，由其制备的金属 - 有机骨架，生产接头和MOF的方法及其用途。

公开(公告)号：WO2013182974A1

公开(公告)日：2013-12-12

申请号：PCT/IB2013/054569

申请日：2013-06-03

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： FEYEN, Mathias ,  MÜLLER, Ulrich ,  RUETZ, Roger ,  BEIN, Thomas ,  MÖLLER, Karin

IPC: C01B39/04 ,  C01B39/48 ,  B01J29/50

CPC classification number: B01D53/9427 ,  B01D53/9418 ,  B01D2255/50 ,  B01D2258/012 ,  B01J29/7015 ,  B01J29/723 ,  B01J29/763 ,  B01J29/783 ,  B01J37/0018 ,  B01J2229/186 ,  C01B39/06 ,  C01B39/48 ,  C10G11/18 ,  C10G2300/405 ,  Y02C20/10 ,  Y02P20/153

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO 2 and X 2 O 3 , wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , and one or more tetraalkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R 1 , R 2 , and R 3 independently from one another stand for alkyl, wherein R 4 stands for cycloalkyl, and wherein the mixture provided in step (1) does not contain any substantial amount of a source for Z 2 O 5 , wherein Z is P, as well as to zeolitic materials which may be obtained ac- cording to the inventive process and to their use.

Abstract translation: 本发明涉及一种制备具有包含YO 2和X 2 O 3的CHA型骨架结构的沸石材料的方法，其中所述方法包括以下步骤：（1）提供包含一种或多种YO 2， 更多的X2O3源和一种或多种四烷基铵阳离子R1R2R3R4N +的化合物作为结构导向剂; （2）使步骤（1）中得到的混合物结晶得到具有CHA型骨架结构的沸石材料; 其中Y是四价元素，X是三价元素，其中R1，R2和R3彼此独立地代表烷基，其中R4代表环烷基，并且其中步骤（1）中提供的混合物不含任何实质的量 的Z2O5的来源，其中Z是P，以及可以根据本发明方法获得的沸石材料及其用途。

公开(公告)号：WO2011157839A1

公开(公告)日：2011-12-22

申请号：PCT/EP2011/060165

申请日：2011-06-17

Applicant: BASF SE ,  YILMAZ, Bilge ,  MÜLLER, Ulrich ,  PFAFF, Meike ,  XIAO, Feng-Shou ,  XIE, Bin ,  ZHANG, Halyan

Inventor： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  PFAFF, Meike ,  XIAO, Feng-Shou ,  XIE, Bin ,  ZHANG, Halyan

IPC: C01B37/02 ,  C01B39/46 ,  B01J29/70 ,  B01J29/72

CPC classification number: C01B39/02 ,  B01J20/186 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3007 ,  B01J29/70 ,  C01B37/02 ,  C01B39/46

Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having an LEV-type framework structure comprising YO 2 and optionally comprising X 2 O 3 , wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and one or more sources for YO 2 ; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the seed crystals comprise zeolitic material having an LEV-type framework structure, and to a zeolitic material having an LEV-type framework structure obtainable by said process, as well as to an organotemplate-free zeolitic material having an LEV-type framework structure comprising YO 2 and optionally comprising X 2 O 3 , wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, wherein said zeolitic material is non-calcined.

Abstract translation: 本发明涉及一种用于制备具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的无机模板合成方法，其中所述方法包括以下步骤：（1）制备包含晶种和一种 或更多来源的YO2; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，其中所述沸石材料任选地包含一种或多种碱金属M，并且其中所述晶种包含具有LEV型骨架结构的沸石材料和具有LEV型骨架结构的沸石材料， 通过所述方法可获得的LEV型骨架结构，以及具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的无有机模板沸石材料，其中Y是四价元素，X是三价元素，其中 沸石材料任选地包含一种或多种碱金属M，其中所述沸石材料是未煅烧的。

公开(公告)号：WO2010130610A1

公开(公告)日：2010-11-18

申请号：PCT/EP2010/056097

申请日：2010-05-05

Applicant: BASF SE ,  THE DOW CHEMICAL COMPANY ,  KAMPE, Philip ,  RESCH, Peter ,  CHIN, Soo, Yin ,  BAßLER, Peter ,  MÜLLER, Ulrich ,  SCHINDLER, Götz-Peter ,  GÖBBEL, Hans-Georg ,  TELES, Joaquim, Henrique ,  GUMLICH, Kai ,  GRAßLER, Thomas ,  BARTOSCH, Christian ,  JACUBINAS, Richard ,  WEIDENBACH, Meinolf

Inventor： KAMPE, Philip ,  RESCH, Peter ,  CHIN, Soo, Yin ,  BAßLER, Peter ,  MÜLLER, Ulrich ,  SCHINDLER, Götz-Peter ,  GÖBBEL, Hans-Georg ,  TELES, Joaquim, Henrique ,  GUMLICH, Kai ,  GRAßLER, Thomas ,  BARTOSCH, Christian ,  JACUBINAS, Richard ,  WEIDENBACH, Meinolf

IPC: C07D301/12

CPC classification number: C07D301/12 ,  Y02P20/52

Abstract: A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (Gl) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (Gl) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.

Abstract translation: 一种生产环氧丙烷的方法，包括在催化剂存在下使丙烯与过氧化氢反应得到包含环氧丙烷，未反应的丙烯和氧的混合物（G1） 从混合物（G1）中分离环氧丙烷以得到包含丙烯和氧的混合物（GII）; 并且在载体上含有元素和/或氧化形式的铜的催化剂的存在下，至少部分地通过与氢反应，将氢混合物（GII）加入到混合物（GII）中并且还原含氧物质，其中铜存在于 以全部催化剂为基础，以30〜80重量％的量进行支持，计算为CuO。

公开(公告)号：WO2010100205A2

公开(公告)日：2010-09-10

申请号：PCT/EP2010/052716

申请日：2010-03-03

Applicant: BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY ,  YILMAZ, Bilge ,  MÜLLER, Ulrich ,  PFAFF, Meike ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  DE VOS, Dirk ,  BAO, Xinhe ,  ZHANG, Weiping

Inventor： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  PFAFF, Meike ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  DE VOS, Dirk ,  BAO, Xinhe ,  ZHANG, Weiping

IPC: C01B33/38

CPC classification number: C01B33/20 ,  B01J20/10 ,  B01J20/30 ,  B01J21/16 ,  B01J29/049 ,  C01B33/38 ,  C01B37/00 ,  C01B37/02 ,  C01B39/02 ,  C01B39/04

Abstract: The present invention relates to A process for the preparation of a layered silicate containing at least silicon and oxygen, comprising (1) providing a mixture containing silica and/or at least one silica precursor, water, at least one tetraalkylammonium compound selected from the group consisting of diethyldimethylammonium compound, a triethylmethylammonium compound, and a mixture of a diethyldimethylammonium and a triethylmethylammonium compound, and at least one base, and optionally at least one suitable seeding material; and (2) heating of the mixture obtained according to (1) under autogenous pressure (hydrothermal conditions) to a temperature in the range of from to 120 to 160 °C for a period in the range of from 5 to 10 days to give a suspension containing the layered silicate.

Abstract translation: 本发明涉及一种制备至少含有硅和氧的层状硅酸盐的方法，其包括（1）提供含有二氧化硅和/或至少一种二氧化硅前体的混合物水，至少一种选自下列的四烷基铵化合物 由二乙基二甲基铵化合物，三乙基甲基铵化合物和二乙基二甲基铵和三乙基甲基铵化合物的混合物组成，以及至少一种碱和任选的至少一种合适的接种材料; 和（2）根据（1）得到的混合物在自生压力（水热条件）下加热至120至160℃的温度范围为5至10天，得到 含有层状硅酸盐的悬浮液。

公开(公告)号：WO2010012715A1

公开(公告)日：2010-02-04

申请号：PCT/EP2009/059716

申请日：2009-07-28

Applicant: BASF SE ,  LEUNG, Emi ,  MÜLLER, Ulrich ,  COX, Gerhard

Inventor： LEUNG, Emi ,  MÜLLER, Ulrich ,  COX, Gerhard

IPC: C07F1/00 ,  B01D53/04 ,  B01D53/86

CPC classification number: C07F1/005 ,  C07C53/06 ,  C07C53/10 ,  Y02E60/324 ,  Y02E60/327 ,  Y02E60/328 ,  C07C51/418

Abstract: Die vorliegende Erfindung betrifft ein poröses metallorganisches Gerüstmaterial enthaltend mindestens eine erste organische Verbindung und Ionen mindestens eines Metalls, wobei das Gerüst des Gerüstmaterials zumindest teilweise dadurch gebildet wird, dass die mindestens erste organische Verbindung zumindest teilweise zweizähnig an mindestens zwei Ionen des mindestens einen Metalls koordinativ bindet, wobei das mindestens eine Metall Lithium ist und wobei sich die mindestens erste Verbindung von Ameisensäure oder Essigsäure ableitet. Die Erfindung betrifft darüber hinaus Verfahren zu dessen Herstellung sowie Verwendung zur Gasspeicherung bzw. -trennung.

Abstract translation: 本发明涉及一种多孔金属有机骨架，其包括至少第一有机化合物和至少一种金属离子，其中所述支架材料的骨架是至少部分地形成由所述至少第一有机化合物至少部分二齿结合配位的至少一种金属的至少两种离子 其中，所述至少一种金属是锂，且其特征在于，甲酸或乙酸中的所述至少第一连接导出。 本发明还涉及用于其生产和使用用于气体或断开的存储方法。