公开(公告)号：EA004864B1

公开(公告)日：2004-08-26

申请号：EA200101163

申请日：2000-05-16

Applicant: STANDARD OIL CO

Inventor： SEELY MICHAEL J ,  GODBOLE SANJAY P ,  SURESH DEV D

IPC: C01C3/02 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/03 ,  C07C255/08

Abstract: Визобретениипредложенспособувеличениявыходакак HCN, таки ацетонитрила, полученныхприпроизводствеакрилонитрила, которыйпредусматриваетвведениеуглеводорода, выбранногоизгруппы, вкоторуювходятпропилени пропан, неочищенногокетонаи/илисмесипоменьшеймередвухкетонов, аммиакаи воздухав зонуреакции, котораясодержиткатализатораммоксидирования, проведениереакциимеждууглеводородом, кетоном, аммиакоми кислородомнадуказаннымкатализаторомприповышеннойтемпературе, чтопозволяетполучитьакрилонитрил, цианидводородаи ацетонитрил, споследующейрекуперациейакрилонитрила, ацетонитрилаи цианидаводородаизреактора.

公开(公告)号：TR200103384T2

公开(公告)日：2002-04-22

申请号：TR200103384

申请日：2000-05-16

Applicant: STANDARD OIL CO

Inventor： SEELY MICHAEL J ,  GODBOLE SANJAY P ,  SURESH DEV D

IPC: C01C3/02 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/03 ,  C07C255/08

Abstract: A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zone containing an ammoxidation catalyst, reacting the hydrocarbon, the ketone, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.

公开(公告)号：AU7813601A

公开(公告)日：2002-02-25

申请号：AU7813601

申请日：2001-08-02

Applicant: STANDARD OIL CO

Inventor： PAPARIZOS CHRISTOS ,  SEELY MICHAEL J ,  FRIEDRICH MARIA STRADA ,  SURESH DEV D

IPC: B01J23/88 ,  B01J23/78 ,  B01J23/83 ,  B01J23/84 ,  B01J23/887 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08 ,  B01J23/00

Abstract: A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum, cobalt, cerium, antimony, at least one of nickel or magnesium, and at least one of lithium, sodium, potassium, rubidium, or thallium, and characterized by the following empirical formula: A a B b C c Fe d Bi e Co f Ce g Sb h Mo m O x wherein A is at least one of Cr, P, Sn, Te, B, Ge, Zn, In, Mn, Ca, W, or mixtures thereof B is at least one of Li, Na, K, Rb, Cs, Tl, or mixtures thereof C is least one of Ni, Mg or mixtures thereof a is 0 to 4.0 b is 0.01 to 1.5 c is 1.0 to 10.0 d is 0.1 to 5.0 e is 0.1 to 2.0 f is 0.1 to 10.0 g is 0.1 to 2.0 h is 0.1 to 2.0 m is 12.0 to 18.0 and x is a number determined by the valence requirements of the other elements present. The catalyst is useful in processes for the ammoxidation of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile and mixtures thereof, respectively.

公开(公告)号：CA2417987A1

公开(公告)日：2002-02-21

申请号：CA2417987

申请日：2001-08-02

Applicant: STANDARD OIL CO

Inventor： FRIEDRICH MARIA STRADA ,  SURESH DEV D ,  SEELY MICHAEL J ,  PAPARIZOS CHRISTOS

IPC: B01J23/88 ,  B01J23/78 ,  B01J23/83 ,  B01J23/84 ,  B01J23/887 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

Abstract: A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum, cobalt, cerium, antimony, at least one of nickel or magnesium, and at least one of lithium, sodium, potassium, rubidium, or thallium, and characterized by the following empirical formula: AaBbCcFedBieCofCegSbhMomOx wherein A is at least one of Cr, P, Sn, Te, B, Ge , Zn, In, Mn, Ca, W, or mixtures thereof, B is at least one of Li, Na, K, Rb, Cs, Tl, or mixtures thereof, C is least one of Ni, Mg or mixtures thereof, a is 0 to 4.0, b is 0.01 to 1.5, c is 1.0 to 10.0, d is 0.1 to 5.0, e is 0.1 t o 2.0, f is 0.1 to 10.0, g is 0.1 to 2.0, h is 0.1 to 2.0, m is 12.0 to 18.0 a nd x is a number determined by the valence requirements of the other elements present. The catalyst is useful in processes for the ammoxidation of an olef in selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile and mixtures thereof, respectively.

公开(公告)号：BG102971A

公开(公告)日：1999-08-31

申请号：BG10297198

申请日：1998-12-01

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV D ,  SEELY MICHAEL J ,  PAPARIZOS CHRISTOS ,  DRENSKY TAMA L ,  FRIEDRICH MARIA S

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/64 ,  B01J23/88 ,  B01J23/92 ,  B01J27/057 ,  B01J27/192 ,  B01J38/00 ,  B01J38/68 ,  B01J21/00

Abstract: The methods of the regeneration of molybdenum catalyst forammoxidation includes the restoration of the molybdenum lossduring the ammoxidation reaction by applying ammonium dimolybdate.3 claims

公开(公告)号：ES2125954T3

公开(公告)日：1999-03-16

申请号：ES93307073

申请日：1993-09-08

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA S ,  SEELEY MICHAEL J ,  PAPARIZOS CHRISTOS ,  SURESH DEV D

IPC: B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/847 ,  B01J23/889 ,  C01C3/02 ,  C07B61/00 ,  C07C253/26 ,  C07C255/08

Abstract: Disclosed is a method for ammoxidizing C3 to C5 mono-olefins to a,b-mono-unsaturated acyclic nitriles having 3 to 5 carbon atoms and HCN by introducing such mono-olefins molecular oxygen and ammonia into a reaction zone into vapor phase contact with a solid ammoxidation catalyst, wherein the mol ratio of introduced molecular oxygen and ammonia to said introduced mono-olefin is at least 1.5 and 1.0, respectively, wherein said catalyst contains the elements and proportions indicated by the empirical formula: V1SbaMmNnOx where a = 0.5 to 2 M = one or more of: Sn, Ti, Fe, and Ga m = 0.05 to 3, usually at least 0.1 and at most 1 N = one or more of: W, Bi, Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, B n = 0.0 to 0.5, and wherein the preparation of the catalyst includes contacting in an aqueous dispersion a vanadium compound and an antimony compound while said vanadium is in solution.

公开(公告)号：DE69322383D1

公开(公告)日：1999-01-14

申请号：DE69322383

申请日：1993-09-08

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA S ,  SEELEY MICHAEL J ,  PAPARIZOS CHRISTOS ,  SURESH DEV D

IPC: B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/847 ,  B01J23/889 ,  C01C3/02 ,  C07B61/00 ,  C07C253/26 ,  C07C255/08

Abstract: Disclosed is a method for ammoxidizing C3 to C5 mono-olefins to a,b-mono-unsaturated acyclic nitriles having 3 to 5 carbon atoms and HCN by introducing such mono-olefins molecular oxygen and ammonia into a reaction zone into vapor phase contact with a solid ammoxidation catalyst, wherein the mol ratio of introduced molecular oxygen and ammonia to said introduced mono-olefin is at least 1.5 and 1.0, respectively, wherein said catalyst contains the elements and proportions indicated by the empirical formula: V1SbaMmNnOx where a = 0.5 to 2 M = one or more of: Sn, Ti, Fe, and Ga m = 0.05 to 3, usually at least 0.1 and at most 1 N = one or more of: W, Bi, Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, B n = 0.0 to 0.5, and wherein the preparation of the catalyst includes contacting in an aqueous dispersion a vanadium compound and an antimony compound while said vanadium is in solution.

公开(公告)号：DE69414660D1

公开(公告)日：1998-12-24

申请号：DE69414660

申请日：1994-02-04

Applicant: STANDARD OIL CO OHIO

Inventor： BIGLER KENNETH L ,  BOTT PAUL E ,  FRIEDRICH MARIA S ,  KECKLER KENNETH P ,  KOCJANCIC FRANK J ,  MIKO STEVE J ,  REILING VINCENT G ,  ROWE STEVEN J ,  SEELY MICHAEL J ,  SHAW WILFRID G ,  SHUKI ALBERT R ,  SOCKELL EDWARD J ,  SURESH DEV D ,  TROTT LOUIS R

IPC: B01D53/58 ,  C01C3/02 ,  B01J23/88 ,  C07B61/00 ,  C07C5/08 ,  C07C253/24 ,  C07C253/26 ,  C07C253/32 ,  C07C255/00 ,  C07C255/08

Abstract: A process for the substantial reduction or complete elimination of ammonium sulfate generated during the production of acrylonitrile by the direct ammoxidation of propylene/propane, ammonia and an oxygen containing gas (e.g. air) over a fluid bed catalyst wherein the improvement comprises introducing methanol into said reactor in the upper portion of the reactor at a location where the methanol reacts with at least a portion if not substantially all of the excess ammonia without affecting the acrylonitrile yield. Preferably, methanol is introduced into the reactor at below its coking temperature. In particular, when an oxygen lean fluid bed catalyst is utilized, an additional oxygen containing gas is introduced into the reaction at a distance between about 8 to 14 inches from the methanol feed location.

公开(公告)号：DE69011495T3

公开(公告)日：1998-07-16

申请号：DE69011495

申请日：1990-12-13

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA S ,  SEELY MICHAEL J ,  SURESH DEV D

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/186 ,  B01J27/19 ,  B01J27/192 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

Abstract: Olefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile, and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and molecular oxygen-containing gas in the presence of a catalyst containing the oxides of bismuth, molybdenum, iron, nickel and magnesium, at least one element selected from the group comprising potassium and cesium, and optionally one element selected from the group comprising cobalt, phosphorus, manganese, tellurium, sodium, cerium, chromium, antimony and tungsten wherein the sum of cesium and potassium is at least 0.1 to 0.4.

公开(公告)号：ES2057448T5

公开(公告)日：1998-07-01

申请号：ES90313574

申请日：1990-12-13

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA S ,  SEELY MICHAEL J ,  SURESH DEV D

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/186 ,  B01J27/19 ,  B01J27/192 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

Abstract: Olefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile, and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and molecular oxygen-containing gas in the presence of a catalyst containing the oxides of bismuth, molybdenum, iron, nickel and magnesium, at least one element selected from the group comprising potassium and cesium, and optionally one element selected from the group comprising cobalt, phosphorus, manganese, tellurium, sodium, cerium, chromium, antimony and tungsten wherein the sum of cesium and potassium is at least 0.1 to 0.4.