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    METHOD FOR THE AMOXYDATION OF OLEFINES
    6.
    发明专利
    METHOD FOR THE AMOXYDATION OF OLEFINES 未知

    公开(公告)号：BG62164B1

    公开(公告)日：1999-04-30

    申请号：BG9808893

    申请日：1993-09-02

    Applicant: STANDARD OIL CO OHIO

    Inventor： SEELY MICHAEL J ,  PAPARIZOS CHRISTOS ,  FRIEDRICH MARIA S ,  SURESH DEV D

    IPC: B01J23/00 ,  B01J27/02 ,  C07B33/00 ,  C07C253/26 ,  C07C255/08

    Abstract: By the method C3 to C5 monoolefines are amoxydated to theproduction of a,6-monononsaturated acrylonitriles having 3 to 5carbon atoms and HCN by the introduction of monoolefines,molecular oxygen and ammonia in a reaction zone in steam phasecontact with solid amoxydation catalyst. The mole ratio of themolecular oxygen and ammonia introduced was at least 1.5 and 1.0,respectively. The catalyst contains the elements included in theformulaV1SbaMnNnOxwhere a has the value from 0.5 to 2, M is one or more of theelements Sn, Ti, Fe and Ga, m takes the values 0.05 to 3,especially from 0.1 to 1; N means one more of the elements W, Bi,Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, B; n hasthe value 0-0.5. The catalyst is produced by the contact betweenvanadium and antimony compound in water dispersion, the vanadiumbeing in solution.

    7.
    发明专利
    未知

    公开(公告)号：DE69017996T2

    公开(公告)日：1995-07-20

    申请号：DE69017996

    申请日：1990-09-13

    Applicant: STANDARD OIL CO OHIO

    Inventor： FRIEDRICH MARIA S ,  SURESH DEV D ,  SEELY MICHAEL J

    IPC: C07B61/00 ,  C07C253/24 ,  B01J23/88 ,  C07C255/07 ,  C07C255/08

    Abstract: Disclosed is a process for making an alpha , beta -unsaturated mononitrile by the catalytic reaction of a paraffin containing 3-5 carbon atoms with molecular oxygen and ammonia by catalytic contact of the foregoing reactants in a reaction zone with a metal oxide catalyst composition that has 10-90 weight percent of a diluent/support and 90-10 weight percent of a catalyst containing the elements indicated by the empirical formula. AaDdBicFefMo12Ox in the proportions indicated by the said formula. said diluent/support containing 10 to 100 weight percent Al2O3 and zero to 90 weight percent SiO2 wherein A is one or more of Li, Na, K, Rb, Cs, Tl B, W , Sn and La: D is one or more of Cr, Sb, Pb, P, Cu, Ni, Co, Mn and Mg; a is zero to 10; c is 0.1 to 10; d is zero to 10; and f is 0.2 to 10; and wherein the reactants fed to the reaction zone contain a mole ratio of said paraffin:NH3 in the range from 2 to 16 and a mole ratio of said paraffin to O2 in the range from 1 to 10.

    9.
    发明专利
    未知

    公开(公告)号：DE69322383T2

    公开(公告)日：1999-04-29

    申请号：DE69322383

    申请日：1993-09-08

    Applicant: STANDARD OIL CO OHIO

    Inventor： FRIEDRICH MARIA S ,  SEELEY MICHAEL J ,  PAPARIZOS CHRISTOS ,  SURESH DEV D

    IPC: B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/847 ,  B01J23/889 ,  C01C3/02 ,  C07B61/00 ,  C07C253/26 ,  C07C255/08

    Abstract: Disclosed is a method for ammoxidizing C3 to C5 mono-olefins to a,b-mono-unsaturated acyclic nitriles having 3 to 5 carbon atoms and HCN by introducing such mono-olefins molecular oxygen and ammonia into a reaction zone into vapor phase contact with a solid ammoxidation catalyst, wherein the mol ratio of introduced molecular oxygen and ammonia to said introduced mono-olefin is at least 1.5 and 1.0, respectively, wherein said catalyst contains the elements and proportions indicated by the empirical formula: V1SbaMmNnOx where a = 0.5 to 2 M = one or more of: Sn, Ti, Fe, and Ga m = 0.05 to 3, usually at least 0.1 and at most 1 N = one or more of: W, Bi, Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, B n = 0.0 to 0.5, and wherein the preparation of the catalyst includes contacting in an aqueous dispersion a vanadium compound and an antimony compound while said vanadium is in solution.

    10.
    发明专利
    未知

    公开(公告)号：DE69017996D1

    公开(公告)日：1995-04-27

    申请号：DE69017996

    申请日：1990-09-13

    Applicant: STANDARD OIL CO OHIO

    Inventor： FRIEDRICH MARIA S ,  SURESH DEV D ,  SEELY MICHAEL J

    IPC: C07B61/00 ,  C07C253/24 ,  B01J23/88 ,  C07C255/07 ,  C07C255/08

    Abstract: Disclosed is a process for making an alpha , beta -unsaturated mononitrile by the catalytic reaction of a paraffin containing 3-5 carbon atoms with molecular oxygen and ammonia by catalytic contact of the foregoing reactants in a reaction zone with a metal oxide catalyst composition that has 10-90 weight percent of a diluent/support and 90-10 weight percent of a catalyst containing the elements indicated by the empirical formula. AaDdBicFefMo12Ox in the proportions indicated by the said formula. said diluent/support containing 10 to 100 weight percent Al2O3 and zero to 90 weight percent SiO2 wherein A is one or more of Li, Na, K, Rb, Cs, Tl B, W , Sn and La: D is one or more of Cr, Sb, Pb, P, Cu, Ni, Co, Mn and Mg; a is zero to 10; c is 0.1 to 10; d is zero to 10; and f is 0.2 to 10; and wherein the reactants fed to the reaction zone contain a mole ratio of said paraffin:NH3 in the range from 2 to 16 and a mole ratio of said paraffin to O2 in the range from 1 to 10.

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