公开(公告)号：US20190062193A1

公开(公告)日：2019-02-28

申请号：US16061929

申请日：2016-12-16

Applicant: Heraeus Quarzglas GmbH & Co. KG

Inventor： Matthias OTTER ,  Walter LEHMANN ,  Michael HÜNERMANN ,  Nils Christian NIELSEN ,  Nigel Robert WHIPPEY ,  Boris GROMANN ,  Abdoul-Gafar KPEBANE ,  Matthias SÖHN

IPC: C03B20/00 ,  C03B17/04 ,  C03B37/012 ,  C03B37/027 ,  C03C3/06 ,  C03C1/02

CPC classification number: C03B20/00 ,  C03B17/04 ,  C03B19/106 ,  C03B19/1095 ,  C03B37/01211 ,  C03B37/027 ,  C03B2201/04 ,  C03C1/022 ,  C03C1/026 ,  C03C3/06 ,  C03C12/00 ,  C03C2201/02 ,  C03C2201/11 ,  C03C2201/23 ,  C03C2201/26 ,  C03C2201/32 ,  C03C2201/40 ,  C03C2201/54 ,  C03C2203/10 ,  C03C2203/40 ,  C03C2203/44 ,  C03C2203/50

Abstract: The invention relates to a process for the preparation of a quartz glass body comprising the process steps i.) Providing a silicon dioxide granulate, wherein the silicon dioxide granulate was made from pyrogenic silicon dioxide powder and the silicon dioxide granulate has a BET surface area in a range from 20 to 40 m2/g, ii.) Making a glass melt out of silicon dioxide granulate in an oven and iii.) Making a quartz glass body out of at least part of the glass melt, wherein the oven has at least a first and a further chamber connected to one another via a passage, wherein the temperature in the first chamber is lower than the temperature in the further chambers. The invention further relates to a quartz glass body which is obtainable by this process. The invention further relates to a light guide, an illuminant and a formed body, which are each obtainable by further processing of the quartz glass body.

公开(公告)号：US10018780B2

公开(公告)日：2018-07-10

申请号：US15725014

申请日：2017-10-04

Applicant: YANGTZE OPTICAL FIBRE AND CABLE JOINT STOCK LIMITED COMPANY

Inventor： Lei Zhang ,  Shengya Long ,  Jihong Zhu ,  Jun Wu ,  Ruichun Wang

IPC: G02B6/02 ,  G02B6/00 ,  G02B6/036 ,  C03C13/04

CPC classification number: G02B6/03683 ,  C03C3/06 ,  C03C13/045 ,  C03C13/046 ,  C03C2201/12 ,  C03C2201/31 ,  C03C2201/32 ,  C03C2201/42 ,  C03C2201/50 ,  C03C2201/54 ,  C03C2213/00 ,  G02B6/02009

Abstract: A doping optimized single-mode optical fiber with ultra low attenuation includes a core layer and cladding layers. The cladding layers has an inner cladding layer surrounding the core layer, a trench cladding layer surrounding the inner cladding layer, an auxiliary outer cladding layer surrounding the trench cladding layer, and an outer cladding layer surrounding the auxiliary outer cladding layer. The content of fluorine in the core layer is ≤0.5 wt %, ΔGe≤0.12%, Δn1≤0.12%. The content of fluorine in the inner cladding layer is 0.5-1.5 wt %, Δn2≤−0.14%. The content of fluorine in the trench cladding layer is 1-3 wt %, Δn3≤−0.25%. The content of fluorine in the auxiliary outer cladding layer is 0.5-2 wt %, Δn4≤−0.14%. The outer cladding layer is a pure silicon dioxide glass layer and/or a metal-doped silicon dioxide glass layer.

公开(公告)号：US09817184B2

公开(公告)日：2017-11-14

申请号：US15290105

申请日：2016-10-11

Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.

Inventor： Yoshiaki Tamura ,  Tetsuya Haruna ,  Masaaki Hirano ,  Hirotaka Sakuma

IPC: G02B6/02 ,  G02B6/036 ,  C03C13/04

CPC classification number: G02B6/03694 ,  C03C13/045 ,  C03C13/046 ,  C03C2201/11 ,  C03C2201/12 ,  C03C2201/50 ,  C03C2201/54 ,  C03C2213/00 ,  G02B6/03611

Abstract: An optical fiber having a reduced attenuation includes a silica glass core and a silica glass cladding. The silica glass core has substantially no germanium and includes a first core and a second core. The second core encloses the first core, the refractive index of the second core is larger than the refractive index of the first core, and the average value of halogen concentration of the second core is 5000 ppm or more. The silica glass cladding surrounds the second core and contains substantially no germanium. The refractive index of the cladding is smaller than the refractive index of the first core.

公开(公告)号：US09580350B2

公开(公告)日：2017-02-28

申请号：US14921487

申请日：2015-10-23

Applicant: Corning Incorporated

Inventor： Sezhian Annamalai ,  Carlos Alberto Duran ,  Kenneth Edward Hrdina

IPC: C03C3/06 ,  C03C3/076 ,  C03C10/00 ,  C03B19/14 ,  C03B19/06 ,  C03B19/12 ,  C03B32/00

CPC classification number: C03C3/06 ,  C03B19/06 ,  C03B19/12 ,  C03B19/1453 ,  C03B32/00 ,  C03B2201/10 ,  C03B2201/23 ,  C03B2201/30 ,  C03B2201/32 ,  C03B2201/40 ,  C03B2201/42 ,  C03B2201/50 ,  C03B2201/54 ,  C03C3/076 ,  C03C10/0009 ,  C03C2201/10 ,  C03C2201/23 ,  C03C2201/30 ,  C03C2201/32 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2201/50 ,  C03C2201/54 ,  C03C2201/58 ,  C03C2203/54

Abstract: Ultralow expansion titania-silica glass. The glass has high hydroxyl content and optionally include one or more dopants. Representative optional dopants include boron, alkali elements, alkaline earth elements or metals such as Nb, Ta, Al, Mn, Sn Cu and Sn. The glass is prepared by a process that includes steam consolidation to increase the hydroxyl content. The high hydroxyl content or combination of dopant(s) and high hydroxyl content lowers the fictive temperature of the glass to provide a glass having a very low coefficient of thermal expansion (CTE), low fictive temperature (Tf), and low expansivity slope.

Abstract translation: 超低膨胀二氧化钛 - 二氧化硅玻璃。 玻璃具有高羟基含量，并且任选地包括一种或多种掺杂剂。 代表性的可选掺杂剂包括硼，碱元素，碱土金属元素或诸如Nb，Ta，Al，Mn，Sn Cu和Sn的金属。 玻璃通过包括蒸汽固结以增加羟基含量的方法制备。 高羟基含量或掺杂剂和高羟基含量的组合降低了玻璃的假想温度，以提供具有非常低的热膨胀系数（CTE），低假想温度（Tf）和低膨胀斜率的玻璃。

公开(公告)号：US09324894B2

公开(公告)日：2016-04-26

申请号：US14358237

申请日：2012-09-27

Applicant: AGC GLASS EUROPE

Inventor： Audrey Dogimont ,  Sebastien Hennecker ,  Thomas Lambricht

IPC: B32B17/00 ,  B32B15/00 ,  H01L31/048 ,  C03C3/087 ,  C03C3/095 ,  C03C4/00 ,  G02B1/10 ,  G02B1/11 ,  G02B5/08 ,  H01L31/052 ,  H01L31/0392

CPC classification number: H01L31/0481 ,  C03C3/087 ,  C03C3/095 ,  C03C4/0092 ,  C03C2201/20 ,  C03C2201/32 ,  C03C2201/3423 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2201/54 ,  C03C2204/00 ,  G02B1/10 ,  G02B1/105 ,  G02B1/11 ,  G02B1/18 ,  G02B5/08 ,  H01L31/0392 ,  H01L31/048 ,  H01L31/0525 ,  Y02E10/50

Abstract: The invention relates to an extra-clear glass sheet, i.e. a glass sheet with high energy transmission, which can be used in particular in the field of solar energy. Specifically, the invention relates to a glass sheet having a composition that includes, in an amount expressed in wt % for the total weight of the glass: 60-78% of SiO2; 0-10% of Al2O3; 0-5% of B2O3; 0-15% of CaO; 0-10% of MgO; 5-20% of Na2O; 0-10% of K2O; 0-5% of BaO, wherein the total amount of iron (in the form of Fe2O3) is 0.002-0.03%, and the composition includes a ratio of manganese/(total iron) of 1 to 8.5, the manganese content being expressed in the form of MnO in wt % relative to the total weight of the glass.

Abstract translation: 本发明涉及一种特别透明的玻璃板，即具有高能量传输的玻璃板，其特别可用于太阳能领域。 具体地说，本发明涉及一种玻璃片，其组成包括以玻璃总重量的wt％表示的量：60-78％的SiO 2; 0-10％的Al2O3; 0-5％的B2O3; 0-15％的CaO; 0-10％的MgO; 5-20％的Na2O; 0-10％K2O; 0-5％的BaO，其中铁（以Fe 2 O 3形式）的总量为0.002-0.03％，组成包括锰/（总铁）的比例为1至8.5，锰含量表示在 MnO的形式相对于玻璃的总重量为wt％。

公开(公告)号：US20130105734A1

公开(公告)日：2013-05-02

申请号：US13810008

申请日：2010-07-14

Applicant: Mingjie Zhou ,  Yanbo Qiao ,  Wenbo Ma

Inventor： Mingjie Zhou ,  Yanbo Qiao ,  Wenbo Ma

IPC: C03C21/00 ,  C09K11/77 ,  C03C4/12

CPC classification number: C03C21/005 ,  C03C3/06 ,  C03C4/12 ,  C03C23/0095 ,  C03C2201/10 ,  C03C2201/3423 ,  C03C2201/3458 ,  C03C2201/36 ,  C03C2201/54 ,  C03C2203/50 ,  C09K11/7774

Abstract: A preparation method of rare earth ions doped alkali metal silicate luminescent glass is provided. The steps involves: step 1, mixing the source compounds of cerium, terbium and alkali metals and putting the mixture into solvent to get a mixed solution; step 2, impregnating the nanometer micropores glass with the mixed solution obtained in step 1; step 3: calcining the impregnated nanometer micropores glass obtained in step 2 in a reducing atmosphere, cooling to room temperature, then obtaining the cerium and terbium co-doped alkali metal silicate luminescent glass. Besides, the rare earth ions doped alkali metal silicate luminescent glass prepared with aforesaid method is also provided. In the prepared luminescent glass, cerium ions can transmit absorbed energy to terbium ions under the excitation of UV light due to the co-doping of cerium ions. As a result, the said luminescent glass has higher luminous intensity than the glass only doped with terbium.

Abstract translation: 提供了稀土离子掺杂的碱金属硅酸盐发光玻璃的制备方法。 步骤包括：步骤1，将铈，铽和碱金属的源化合物混合并将混合物置于溶剂中以得到混合溶液; 步骤2，用步骤1中获得的混合溶液浸渍纳米微孔玻璃; 步骤3：将在步骤2中获得的浸渍的纳米微孔玻璃在还原气氛中煅烧，冷却至室温，然后获得共混掺杂的铈和铽的碱金属硅酸盐发光玻璃。 此外，还提供了用上述方法制备的稀土离子掺杂的碱金属硅酸盐发光玻璃。 在制备的发光玻璃中，由于铈离子的共掺杂，铈离子可以在UV光的激发下将吸收的能量传递给铽离子。 结果，所述发光玻璃比仅掺杂铽的玻璃具有更高的发光强度。

公开(公告)号：US20100041538A1

公开(公告)日：2010-02-18

申请号：US12440683

申请日：2007-09-11

Applicant: Kazuyoshi Arai ,  Tsutomu Takahata ,  Shinkichi Hasimoto ,  Masahito Uchida ,  Nobusuke Yamada ,  Yoshinori Harada ,  Hideharu Horikoshi

Inventor： Kazuyoshi Arai ,  Tsutomu Takahata ,  Shinkichi Hasimoto ,  Masahito Uchida ,  Nobusuke Yamada ,  Yoshinori Harada ,  Hideharu Horikoshi

IPC: C03C3/04 ,  C03C10/00

CPC classification number: C03C4/0085 ,  C03B19/066 ,  C03B20/00 ,  C03B2201/03 ,  C03B2201/04 ,  C03C3/06 ,  C03C4/10 ,  C03C2201/23 ,  C03C2201/50 ,  C03C2201/54 ,  Y02P40/57

Abstract: Fused silica glass having an internal transmittance of UV with 245 nm wavelength, being at least 95% at 10 mm thickness, a OH content of not larger than 5 ppm, and a content of Li, Na, K, Mg, Ca and Cu each being smaller than 0.1 ppm. Preferably the glass has a viscosity coefficient at 1215° C. of at least 1011.5 Pa·s; and a Cu ion diffusion coefficient of not larger than 1×10−10 cm2/sec in a depth range of greater than 20 μm up to 100 μm, from the surface, when leaving to stand at 1050° C. in air for 24 hours. The glass is made by crystobalitizing powdery silica raw material; then, fusing the crystobalitized silica material in a non-reducing atmosphere. The glass exhibits a high transmittance of ultraviolet, visible and infrared rays, has high purity and heat resistance, and exhibits a reduced diffusion rate of metal impurities, therefore, it is suitable for various optical goods, semiconductor-production apparatus members, and liquid crystal display production apparatus members.

Abstract translation: 具有245nm波长的UV的内部透射率，10mm厚度至少95％，OH含量不大于5ppm，Li，Na，K，Mg，Ca和Cu的含量的熔融石英玻璃 小于0.1ppm。 优选地，玻璃的1215℃下的粘度系数至少为1011.5Pa·s; 在大于20μm至100μm的深度范围内的Cu离子扩散系数不大于1×10 -10 cm 2 / sec，在1050℃在空气中放置24小时时， 。 玻璃由硅胶粉末二氧化硅原料精制而成; 然后，在非还原气氛中将经晶化的二氧化硅材料熔融。 该玻璃的紫外线，可见光和红外线的透射率高，纯度高，耐热性高，金属杂质的扩散速度降低，因此适用于各种光学制品，半导体制造装置部件和液晶 展示生产设备成员。

公开(公告)号：US20080098771A1

公开(公告)日：2008-05-01

申请号：US11975143

申请日：2007-10-17

Applicant: Vincenzo Giardino ,  Lucia Gini

Inventor： Vincenzo Giardino ,  Lucia Gini

IPC: C03B8/00

CPC classification number: C03C3/097 ,  C03C1/006 ,  C03C4/0007 ,  C03C2201/06 ,  C03C2201/28 ,  C03C2201/54 ,  C03C2203/22

Abstract: An improved sol-gel process is disclosed for the making of large synthetic silica based bioactive materials objects crack-free. A series of ordered mesoporous SiO2—CaO—P2O5 sol-gel glasses which are highly bioactive are synthesized through a sol-gel process. The mesoporous glasses are highly bioactive compared with conventional ones, due to the increased textural characteristics, i.e. surface area. The bioactivity tests point out that the surface area, porosity, and 3D-structure become more important than chemical composition during the apatite crystallization stage in these materials, due to the very high textural parameters obtained. The product is intended to be used for tissue engineering applications.

Abstract translation: 公开了一种改进的溶胶 - 凝胶方法，用于制造无合金二氧化硅的生物活性物质。 通过溶胶 - 凝胶合成了一系列具有高度生物活性的有序介孔SiO 2 -C 2 O 2 P 2 O 5 O 5溶胶凝胶玻璃 处理。 由于增加的结构特征，即表面积，介孔玻璃与常规玻璃相比具有高生物活性。 生物活性测试指出，由于获得的非常高的结构参数，表面积，孔隙率和3D结构在这些材料中的磷灰石结晶阶段期间比化学成分更重要。 该产品旨在用于组织工程应用。

公开(公告)号：US07181116B2

公开(公告)日：2007-02-20

申请号：US11131927

申请日：2005-05-18

Applicant: George H. Sigel, Jr. ,  Daniel S. Homa

Inventor： George H. Sigel, Jr. ,  Daniel S. Homa

IPC: G02B6/02 ,  C03B37/18

CPC classification number: C03B37/01807 ,  C03B2201/28 ,  C03B2201/31 ,  C03B2201/36 ,  C03B2201/50 ,  C03B2201/54 ,  C03B2203/22 ,  C03B2207/81 ,  C03B2207/90 ,  C03C13/045 ,  C03C2201/32 ,  C03C2201/36 ,  C03C2201/50 ,  C03C2201/54

Abstract: A preform for a low loss fiber optic cable and method and apparatus for fabricating such a preform is provided. The method includes providing AlCl3 and CVD precursors and locally doping CaCl3. Alkali and/or alkaline earth fluxing agents can be introduced. The alkali and/or alkaline earths are doped along with the aluminum into the silica glass core.

Abstract translation: 提供了一种用于低损耗光纤电缆的预成型件以及用于制造这种预制件的方法和装置。 该方法包括提供AlCl 3和CVD前体并局部掺杂CaCl 3。 可以引入碱和/或碱土助熔剂。 碱和/或碱土金属与铝一起掺入石英玻璃芯中。

公开(公告)号：US20070004579A1

公开(公告)日：2007-01-04

申请号：US11261005

申请日：2005-10-28

Applicant: Dana Bookbinder ,  Kenneth Hrdina ,  Glenn Kohnke ,  Lisa Moore ,  Susan Schiefelbein ,  Charlene Smith ,  Ulrich Neukirch

Inventor： Dana Bookbinder ,  Kenneth Hrdina ,  Glenn Kohnke ,  Lisa Moore ,  Susan Schiefelbein ,  Charlene Smith ,  Ulrich Neukirch

IPC: C03C3/06 ,  C03B32/00 ,  C03C23/00

CPC classification number: C03C3/06 ,  C03C4/0071 ,  C03C4/0085 ,  C03C2201/21 ,  C03C2201/23 ,  C03C2201/54

Abstract: Disclosed in the application are a synthetic silica glass having low fluence-dependent transmission, particularly at about 193 nm, and a process for making the same. The glass may desirably exhibit a low level of fluorescence at 290 and 390 nm when activated at about 248 nm. The glass may desirably exhibit low level of LIWFD, [SiH*] and/or [ODC].

Abstract translation: 在本申请中公开了具有低注射度依赖性透射率，特别是约193nm的合成二氧化硅玻璃及其制造方法。 当在约248nm激活时，该玻璃可期望地在290和390nm处表现出低水平的荧光。 玻璃可能期望显示低水平的LIWFD，[SiH *]和/或[ODC]。