公开(公告)号：DE10001779A1

公开(公告)日：2001-07-19

申请号：DE10001779

申请日：2000-01-18

Applicant: BASF AG

Inventor： BAUM EVA ,  GROSCH GEORG HEINRICH ,  HARRE KATHRIN ,  WINKLER JUERGEN

IPC: B01J27/26 ,  C08G65/26 ,  C08G18/48 ,  B01J31/26 ,  C08G2/06

Abstract: Multi-metal cyanide (MMC) compound(s) (I) and acid compound(s) (III) are used as catalysts in a process for the production of polyether-alcohols by the catalytic addition reaction of alkylene oxides with H-functional starter substances. An Independent claim are also included for: (1) catalysts of formula (II) for use in this process; (2) production of MMC compounds (II) by mixing solutions of metal salts and hexacyanometallate compounds in presence of Lewis acids or compounds which form Lewis acid centres when incorporated into the catalyst; (3) MMC compounds obtained by this method. M a(M (CN)b(A)c)d.fM gXn.eL.iS (II) M = Zn , Fe , Co , Ni , Mn , Co , Sn , Pb , Mo , Mo , Al , V , W , Cr , Cr , Cd , Hg , Pd , Pt , V , Mg , Ca , Ba and Cu ; M = Fe , Fe , Co , Co , Mn , Mn , V , V , Cr , Cr , Rh , Ru and Ir ; A, X = halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate and nitrate; L = a water-miscible ligand selected from alcohols, aldehydes, ketones, ethers, polyethers, esters, ureas, amides, nitriles, lactones, lactams and sulfides; S = a Lewis acid or a compound which leads to the formation of Lewis acid centres when incorporated into the catalyst; a, b, c, d, g, n = numbers consistent with the electrical neutrality of (II); e, f, h = 0 or more (integer or fraction); i = more than 0.

公开(公告)号：DE19949091A1

公开(公告)日：2001-04-26

申请号：DE19949091

申请日：1999-10-12

Applicant: BASF AG

Inventor： BAUM EVA ,  BAUER STEPHAN ,  HARRE KATHRIN ,  TISCHER GERLINDE ,  GROSCH GEORG-HEINRICH ,  PRETZSCH REGINA ,  OSTROWSKI THOMAS ,  PCOLINSKI MICHAEL JAMES ,  DINSCH STEFAN ,  ROTERMUND INGE ,  LORENZ REINHARD

IPC: C08G65/12 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G63/66 ,  C08G65/26 ,  C08G81/00 ,  C08L71/02 ,  C08G65/02 ,  C08G18/64 ,  C08G18/12 ,  C08G18/22

Abstract: The invention relates to polyester-polyether block copolymers which can be produced by the catalytically induced attachment of alkylene oxides to H functional starting materials. Said copolymers are characterised in that polyester alcohols are used as the H functional starting materials and multi-metal cyanide compounds are used as the catalysts.

公开(公告)号：AU7661000A

公开(公告)日：2001-04-23

申请号：AU7661000

申请日：2000-10-02

Applicant: BASF AG

Inventor： BAUM EVA ,  GROSCH GEORG HEINRICH ,  HARRE KATHRIN ,  WINKLER JURGEN ,  OSTROWSKI THOMAS ,  HOEPPNER GERD ,  PAREDIS ELS

IPC: C08G65/10 ,  C08G65/26 ,  C07D301/32