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    HERBICIDES 3-(BENZAZOL-4-YL)PYRIMIDINE-DIONE-DERIVATIVES
    101.
    发明专利
    HERBICIDES 3-(BENZAZOL-4-YL)PYRIMIDINE-DIONE-DERIVATIVES 未知

    公开(公告)号：SK7502000A3

    公开(公告)日：2001-01-18

    申请号：SK7502000

    申请日：1998-12-11

    Applicant: BASF AG

    Inventor： REINHARD ROBERT ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SCHAFER PETER ,  ZAGAR CYRILL ,  HEISTRACHER ELISABETH ,  OTTEN MARTINA ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

    IPC: C07D239/54 ,  A01N43/54 ,  A01N43/647 ,  A01N43/707 ,  A01N43/74 ,  A01N43/76 ,  A01N43/78 ,  C07D403/04 ,  C07D413/04 ,  C07D417/04 ,  C07F9/6558

    Abstract: The invention relates to 3-(benzazol-4-yl)pyrimidine-dione-derivatives of formula (I) and the salts thereof, whereby X = O, S; R = H, NH2, C1-C6-alkyl, C1-C6-alkyl halide; R = H, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl; R = H, halogen, C1-C6-alkyl; R = H, halogen; R = CN, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkoxyl, C1-C6-alkoxyl halide; =Y- = a group =N-N(R )-, =C(ZR )-N(R )-, =C(ZR )-O-, =C(ZR )-S-; R = C1-C6-alkyl, C1-C4-alkyl halide, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkyl-SO2, C1-C6-alkyl-CO, C1-C6-alkyl halide-CO, C1-C6-alkyl-CS, C1-C6-alkoxyl-CO, C1-C6-alkoxyl-CS or optionally substituted C1-C6-alkyl; Z = chemical bond, O, S, -S(O)-, -SO2-, -NH-, -N(R )-; R , R = C1-C6-alkyl, C1-C6-alkyl halide, hydroxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkoxyl-C1-C4-alkyl, C1-C4-alkoxyl halide-C1-C4-alkyl, C3-C4-alkenyloxyl-C1-C4-alkyl, C3-C4-alkynyloxyl-C1-C4-alkyl, C3-C8-cycloalkoxyl-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio halide-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkynylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfinyl halide-C1-C4-alkyl, C3-C4-alkenylsulfinyl-C1-C4-alkyl, C3-C4-alkynylsulfinyl-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-alkenyl halide, C3-C6-alkynyl, cyano-C3-C6-alkynyl, C3-C6-alkynyl halide, HO-CO-C1-C4-alkyl, (C1-C4-alkoxyl)CO-C1-C4-alkyl, (C1-C4-alkyl)CS-C1-C4-alkyl, H2N-CO-C1-C4-alkyl, C1-C4-alkyl-NHCO-C1-C4-alkyl, di(C1-C4-alkyl)NCO-C1-C4-alkyl, di(C1-C4-alkyl)phosphonyl-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-linked heterocyclyl or heterocyclyl-C1-C4-alkyl, whereby each heterocyclyl ring can contain a CO-ring link or CS-ring link, or provided that Z = chemical bond, R also H, OH, CN, SH, NH2, halogen, -CH(OH)-CH2-R , -CH(halogen)-CH2-R , -CH2-CH(halogen)-R , -CH=CH-R or -CH=C(halogen)-R , whereby R = COOH, (C1-C4-alkoxyl)carbonyl, (C1-C4-alkylthio)carbonyl, CONH2, C1-C4-alkyl-NHCO or di(C1-C4-alkyl)NCO, or R + R = an optionally substituted 1,3-propylene-, tetramethylene-, pentamethylene- or ethylene oxyethylene-chain.

    New benzyl, benzoyl or anilino-substituted triazinedionethiones, useful as pre- or post-emergence, total or selective herbicides
    102.
    发明专利
    New benzyl, benzoyl or anilino-substituted triazinedionethiones, useful as pre- or post-emergence, total or selective herbicides 未知

    公开(公告)号：DE19924805A1

    公开(公告)日：2000-11-30

    申请号：DE19924805

    申请日：1999-05-29

    Applicant: BASF AG

    Inventor： MENKE OLAF ,  MENGES MARKUS ,  HAMPRECHT GERHARD ,  PUHL MICHAEL ,  REINHARD ROBERT ,  SAGASSER INGO ,  ZAGAR CYRILL ,  WESTPHALEN KARL-OTTO ,  OTTEN MARTINA ,  WALTER HELMUT

    IPC: A01N43/64 ,  C07D251/38 ,  A01N43/68 ,  A01N43/82 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/04 ,  C07D413/12 ,  C07D419/04 ,  C07D419/12

    Abstract: 5-Benzyl-, 5-benzoyl- or 5-anilino-triazinedionethiones (I) are new. Triazinedionethiones of formula (I) and their salts and enol ethers are new. X = CH2, C(O) or NH; R1, R2 = Me or NH2; R3 = H, CN, SCN, halo, T', OT' or ST'; T' = 1-4C haloalkyl; R4 = as R4; T, alkenyloxy or alkynyloxy; alkoxycarbonyl, alkenyloxycarbonyl, alkynyloxycarbonyl, alkylaminocarbonyl, hydroxyalkylcarbonyl, NHSO2T or NH2 (all optionally substituted (os) by OT, COOT, NH2 or NHSO2T); T = 1-4C alkyl; one of R5, R6 = H, CN, NO2, halo or OT; the other R5, R6 = H, CN, NO2, halo or NH2; alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, alkenyloxy, 5-7C cycloalkenyloxy, alkenylthio, alkynylthio, alkylcarbonyloxy, alkylcarbonylthio, alkoxycarbonyloxy, alkenylcarbonyloxy, alkenylcarbonylthio, alkynylcarbonyloxy, alkynylcarbonylthio, alkylsulfonyl or alkylsulfonyloxy (all os by 1-4 R'6);-C(Y)-R14, -C(R14)(Z1R15)(Z2R16), C(R14)=C(R17)-CN, C(R14)=C(R17)-COR18, CHR14CHR17-COR18, C(R14)=C(R17)CH2COR18, C(R14)=C(R17)-C(R19)=C(R20)-COR18, C(R14)=C(R17)-CH2CHR21-COR18, COOR22, -CC-CONHOR9, -CC-CON(R22)OR9, -CC-CSNHOR9, -CC-CSN(R22)OR9, -CC-C(R10)=NOR9, -C(R14)=C(R17)-CONHOR9, C(R14)=C(R17)-CON(R22)OR9, C(R14)=C(R17)-CSNHOR9, C(R14)=C(R17)-CSN(R22)OR9, C(R14)=C(R17)-C(R10)=NOR9, NR24R25, -CC-Q or C(R14)=C(R17)-Q; or (iv) CON(R22)OR9, -C(R10)=NOR9, -C(Z1R15)(Z2R16)OR23, -C(Z1R15)(Z2R16)SR23, -C(Z1R15)(Z2R16)NR24R25, Q, COOR23, COSR23, alkylthioalkylcarbonyl or alkyliminooxycarbonyl; R'6 = halo, NO2, CN, OH, cycloalkyl, alkoxy, cycloalkoxy, 3-6C alkenyloxy, 3-6C alkynyloxy, alkoxyalkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, 1-6C alkylideneaminooxy, Ph', OPh', SO2Ph', Het, -O-Het, =O, COR7, COOR7, COSR7, CONR7R8, OCOCR7, OCOOR7, OCOSR7, OCOCNR7R8, NR7R8, =NOR9, -C(R10)=NOR9 or SiR11R12R13; Ph' = phenyl (os by 1-3 of halo, NO2, CN, alkyl, haloalkyl, alkoxy and alkoxycarbonyl); Het = 3-7 heterocyclyl (os by 1-3 of halo, NO2, CN, alkyl, haloalkyl, alkoxy and alkylcarbonyl); Z1, Z2 = O or S; Q = (a); Q1 = 1-3C alkylene (os by alkyl); Q2 = O or S; R7 = H, alkyl, cycloalkyl, 3-6C alkenyl, 3-6C alkynyl, alkoxyalkyl, alkoxycarbonylalkyl, (3-6C) alkenyloxycarbonylalkyl, Ph' or Ph'-alkyl; R8 = H, OH, alkyl, cycloalkyl, alkoxy, alkoxycarbonylalkoxy, 3-6C alkenyl or 3-6C alkenyloxy; NR7R8 = Het; R9 = H, alkyl, haloalkyl, cycloalkyl, 3-6C alkenyl, 3-6C alkynyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl, cyanoalkyl, alkylcarbonylakyl, alkoxycarbonylalkyl, alkoxycarbonylalkenyl, alkylcarbonyloxyalkyl or Ph'-alkyl; R10 = H or halo; alkyl, haloalkyl, alkoxy, haloalkoxy, 3-6C alkenyloxy, alkylthio, haloalkylthio, alkylcarbonyloxy, haloalkylcarbonyloxy, alkylsulfonyloxy or haloalkylsulfonyloxy (all os by OH, CN, COOH, alkoxy, alkylthio, alkylcarbonyl, alkoxycarbonyl, mono- or dialkylaminocarbonyl or alkylcarbonyloxy); 3-7 azaheterocycle, bonded at N via a carbonyl bridge; alkylcarbonyl, haloalkylcarbonyl, alkoxycarbonyl, alkoxycarbonyloxy, alkylcarbonylthio, haloalkylcarbonylthio, alkoxycarbonylthio, alkenyl, alkenylthio, 3-6C alkynyl, 3-6C alkynyloxy, 3-6C alkynylthio, alynylcarbonyloxy, 3-6C alkynylsulfonyloxy, cycloalkyl, cycloalkoxy, cycloalkylthio, cycloalkylcarbonyloxy or cycloalkylsulfonyloxy; or Ph', Ph'O, Ph'S, Ph'COO, Ph'SO2O, Ph'-alkyl, Ph'-alkoxy, Ph'-alkylthio, or Ph'-alkylsulfonyloxy; R14 = H, CN, alkyl, haloalkyl, alkenyl, alkynyl, cycloalkyl, alkoxyalkyl or alkoxycarbonyl; R15, R16 = alkyl, haloalkyl, 3-6C alkenyl, 3-6C alkynyl or alkoxyalkyl; R15 + R16 = 2-4 (un)saturated C, substituted by 1-3 of CN, NO2, halo, alkyl, alkenyl, alkoxy, alkenyloxy, alkynyloxy, haloalkyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, 3-6C alkenyloxyalkyl, (3-6C) alkynyloxyalkyl, cycloalkyl, cycloalkoxy, COOH, alkoxycarbonyl, alkylcarbonyloxy or Ph' and/or having 1 or 2 members forming part of a 3-7 ring, and os by 1 or 2 of CN, alkyl, alkenyl, alkoxy, cyanoalkkyl, haloalkyl and alkoxycarbonyl; R17 = H, CN, halo, alkyl, haloalkyl, alkoxy, alkylcarbonyl or alkoxycarbonyl; R18 = H, OR23 SR23, alkyl (os by 1 or 2 alkoxy), alkenyl, alkynyl, haloalkyl, cycloalkyl, alkylthioalkyl, alkyliminooxy, NR24R25 or Ph'; Ph'' = phenyl (os by 1-3 of CN, NO2, halo, alkyl, 3-6C alkenyl, haloalkyl, alkoxy and alkoxycarbonyl); R19 = H, CN, halo, alkyl, 3-6C alkenyl, 3-6C alkynyl, alkoxyalkyl, alkylcarbonyl, alkoxycarbonyl, NR24R25 or Ph''; R20 = H, CN, halo, alkyl, alkoxy, haloalkyl, alkylcarbonyl or alkoxycarbonyl; R21 = H, CN, alkyl or alkoxycarbonyl; R22, R23 = H; alkyl, haloalkyl, alkenyl or alkynyl (all os by 1 or 2 of CN, halo, OH, COOH, alkoxy, alkylthio, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy, (3-6C) alkenyloxycarbonyl or 3-7 azaheterocycle (optionally containing O or S), bonded at N via a carbonyl bridge); or alkylcarbonyl, haloalkylcarbonyl, alkoxycarbonyl, mono- or dialkylaminoalkyl, alkoxyiminoalkyl, cycloalkyl, Ph' or Ph'-alkyl; R24, R25 = H, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylcarbonyl, alkoxycarbonyl, alkoxycarbonylalkyl, alkoxycarbonylalkenyl (os in the alkenyl part by 1-3 halo and CN), alkylsulfonyl, alkoxycarbonylalkylsulfonyl, Ph'', Ph''SO2, Ph''CH2 or Ph''CH2SO2; NR24R25 = (un)saturated 4-7 ring, optionally containing a further O, S, N, NH or N(alkyl); Y = O, S or N(R28); R28 = H, OH, alkyl, 3-6C alkenyl, 3-6C alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkoxy, 3-6C alkenyloxy, 3-6C alkynyloxy, cycloalkoxy, 5-7C cycloalkenyloxy, haloalkoxy, 3-6C haloalkenyloxy, hydroxyalkoxy, cyanoalkyl, cycloalkylalkoxy, alkoxyalkoxy, alkoxy-(3-6C) alkenyloxy, alkylcarbonyloxy, haloalkylcarbonyloxy, alkylcarbonylalkyl, alkylcarbonylalkoxy, alkoxycarbonylalkyl, alkoxycarbonylalkoxy, alkylthioalkoxy, dialkylaminoalkoxy or Ph''; Ph''-alkoxy, Ph''-(3-6C) alkenyloxy or Ph''-(3-6C) alkynyloxy ( 1 or 2 CH2 in the C chains may be replaced by O, S or N(alkyl)); Het, Het-alkoxy, Het-(3-6C) alkenyloxy or Het-(3-6C) alkynyloxy (1 or 2 CH2 in the C chains may be replaced by O, S or N(alkyl)); or NR29R30; R29, R30 = H, alkyl, 3-6C alkenyl, 3-6C alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylcarbonyl, alkoxycarbonyl, alkoxycarbonylalkyl, alkoxycarbonylalkenyl (os in the alkenyl part by 1-3 of halo and CN) or Ph''; and NR29R30 = (un)saturated 4-7 ring, optionally containing a further O, S, N, NH or N(alkyl). An Independent claim is included for the preparation of (I).

    Herbicidal 3-(benzazol-4-yl)pyrimidinedione derivatives.
    107.
    发明专利
    Herbicidal 3-(benzazol-4-yl)pyrimidinedione derivatives. 未知

    公开(公告)号：ZA9811490B

    公开(公告)日：2000-06-15

    申请号：ZA9811490

    申请日：1998-12-15

    Applicant: BASF AG

    Inventor： REINHARD ROBERT ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SCHAEFER PETER ,  ZAGAR CYRILL ,  HEISTRACHER ELISABETH ,  OTTEN MARTINA ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

    IPC: C07D239/54 ,  A01N43/54 ,  A01N43/647 ,  A01N43/707 ,  A01N43/74 ,  A01N43/76 ,  A01N43/78 ,  C07D403/04 ,  C07D413/04 ,  C07D417/04 ,  C07F9/6558 ,  C07D ,  A01N

    Abstract: The invention relates to 3-(benzazol-4-yl)pyrimidine-dione-derivatives of formula (I) and the salts thereof, whereby X = O, S; R = H, NH2, C1-C6-alkyl, C1-C6-alkyl halide; R = H, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl; R = H, halogen, C1-C6-alkyl; R = H, halogen; R = CN, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkoxyl, C1-C6-alkoxyl halide; =Y- = a group =N-N(R )-, =C(ZR )-N(R )-, =C(ZR )-O-, =C(ZR )-S-; R = C1-C6-alkyl, C1-C4-alkyl halide, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkyl-SO2, C1-C6-alkyl-CO, C1-C6-alkyl halide-CO, C1-C6-alkyl-CS, C1-C6-alkoxyl-CO, C1-C6-alkoxyl-CS or optionally substituted C1-C6-alkyl; Z = chemical bond, O, S, -S(O)-, -SO2-, -NH-, -N(R )-; R , R = C1-C6-alkyl, C1-C6-alkyl halide, hydroxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkoxyl-C1-C4-alkyl, C1-C4-alkoxyl halide-C1-C4-alkyl, C3-C4-alkenyloxyl-C1-C4-alkyl, C3-C4-alkynyloxyl-C1-C4-alkyl, C3-C8-cycloalkoxyl-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio halide-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkynylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfinyl halide-C1-C4-alkyl, C3-C4-alkenylsulfinyl-C1-C4-alkyl, C3-C4-alkynylsulfinyl-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-alkenyl halide, C3-C6-alkynyl, cyano-C3-C6-alkynyl, C3-C6-alkynyl halide, HO-CO-C1-C4-alkyl, (C1-C4-alkoxyl)CO-C1-C4-alkyl, (C1-C4-alkyl)CS-C1-C4-alkyl, H2N-CO-C1-C4-alkyl, C1-C4-alkyl-NHCO-C1-C4-alkyl, di(C1-C4-alkyl)NCO-C1-C4-alkyl, di(C1-C4-alkyl)phosphonyl-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-linked heterocyclyl or heterocyclyl-C1-C4-alkyl, whereby each heterocyclyl ring can contain a CO-ring link or CS-ring link, or provided that Z = chemical bond, R also H, OH, CN, SH, NH2, halogen, -CH(OH)-CH2-R , -CH(halogen)-CH2-R , -CH2-CH(halogen)-R , -CH=CH-R or -CH=C(halogen)-R , whereby R = COOH, (C1-C4-alkoxyl)carbonyl, (C1-C4-alkylthio)carbonyl, CONH2, C1-C4-alkyl-NHCO or di(C1-C4-alkyl)NCO, or R + R = an optionally substituted 1,3-propylene-, tetramethylene-, pentamethylene- or ethylene oxyethylene-chain.

    Substituted 2-phenyl-3(2H)-pyridaziones.
    108.
    发明专利
    Substituted 2-phenyl-3(2H)-pyridaziones. 未知

    公开(公告)号：ZA988447B

    公开(公告)日：2000-03-22

    申请号：ZA988447

    申请日：1998-09-16

    Applicant: BASF AG

    Inventor： SCHAEFER PETER ,  MENGES MARKUS ,  HAMPRECHT GERHARD ,  RACK OLAF MENKE MICHAEL ,  REINHARD ROBERT ,  ZAGAR CYRILL ,  MUENSTER PETER ,  OTTEN MARTINA ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

    IPC: A01N43/58 ,  C07D237/20 ,  C07D237/22 ,  C07D405/10 ,  C07D ,  A01N

    Abstract: Substituted 2-phenyl-3(2H)-pyridazinones Iand salts thereof, wheren=0, 1, 2; R1=C1-C4-alkyl, C1-C4-haloalkyl;R2=H, halogen; R3=halogen, CN;R4=H, NO2, CN, CHO, NH-OH, C1-C4-alkyl, C1-C4-halogenalkyl, -OR5, -CH=N-OR6, -CH=C(R7)-CO-OR8, -CO-OR9, C1-C6-alkyl-SO2-NH, di(C1-C6-alkylsulfonyl)amino orR5=C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, (C1-C6-alkoxy)carbonyl-C1-C4-alkyl, (C3-C6-alkenyloxy)carbonyl-C1-C4-alkyl, (C3-C6-alkynyloxy)carbonyl-C1-C4-alkyl, C1-C4-alkoxy(C1-C4-alkoxy)carbonyl-C1-C4-alkyl;R6=H, C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)carbonyl-C1-C4-alkyl;R7=H, halogen, C1-C4-alkyl; R8=H, C1-C6-alkyl;R9=H, C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkoxy, hydroxycarbonyl-C1-C4-alkyl, (C1-C6-alkoxy)carbonyl-C1-C4-alkyl, (C3-C6-alkenyloxy)carbonyl-C1-C4-alkyl, (C3-C6-alkynyloxy)carbonyl-C1-C4-alkyl, C1-C4-alkoxy-(C1-C4-alkoxy)carbonyl-C1-C4-alkyl;R10=H, C1-C6-alkyl, COOH, (C1-C6-alkoxy)carbonyl;and their use as herbicides and for the desiccation/defoliation of plants are described.

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