102.
    发明专利
    未知

    公开(公告)号:DE59701672D1

    公开(公告)日:2000-06-15

    申请号:DE59701672

    申请日:1997-09-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/05204 Sec. 371 Date Apr. 1, 1999 Sec. 102(e) Date Apr. 1, 1999 PCT Filed Sep. 23, 1997 PCT Pub. No. WO98/15589 PCT Pub. Date Apr. 16, 1998Polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butyne-1,4-diol, diesters of these polymers with C2-C20-monocarboxylic acids or monoesters of these polymers with C1-C10-monocarboxylic acids are prepared by polymerization of tetrahydrofuran in the presence of one of the telogens water, 1,4-butanediol, 2-butyne-1,4-diol, polytetrahydrofuran having a molecular weight of from 200 to 700 Dalton, a C1-C10-monocarboxylic acid or an anhydride of a C2-C20-monocarboxylic acid or a mixture of these telogens over a heterogeneous supported catalyst which comprises a catalytically active amount of an oxygen-containing molybdenum and/or tungsten compound on an oxidic support material and which has been calcined at from 5OO DEG C. to 1OOO DEG C. after application of the precursor compounds of the oxygen-containing molybdenum and/or tungsten compounds onto the support material precursor, wherein the catalyst is activated by treatment with a reducing agent before it is used as a polymerization catalyst.

    Method for producing halogen-free reactive polyisobutene

    公开(公告)号:AU5282699A

    公开(公告)日:2000-02-28

    申请号:AU5282699

    申请日:1999-07-15

    Applicant: BASF AG

    Abstract: A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 60 mol % and an average molecular weight Mn of 800-3000 dalton by cationic polymerization in the liquid phase of isobutene over an acidic, essentially halogen-free heterogeneous catalyst, wherea) a hydrocarbon mixture of essentially C4-hydrocarbons comprising isobutene in an amount of from 10 to 80% by weight is used as the starting material andb) polymerization is carried out continuously at from -30 to 0° C. with average starting material residence times of one hour or less, where the temperature and the residence time are selected such that the isobutene conversion is less than 60% and, after separation from the resulting polyisobutene, the isobutene is either enriched in the partially converted hydrocarbon mixture and returned to the polymerization or passed to another isobutene reaction coupled with the polymerization.

    105.
    发明专利
    未知

    公开(公告)号:ES2133991T3

    公开(公告)日:1999-09-16

    申请号:ES96929205

    申请日:1996-08-05

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/03441 Sec. 371 Date Jan. 27, 1998 Sec. 102(e) Date Jan. 27, 1998 PCT Filed Aug. 5, 1996 PCT Pub. No. WO97/06189 PCT Pub. Date Feb. 20, 1997A process for the preparation of halogen-free, reactive polyisobutene having a content of terminal double bonds of more than 50 mol % and an average molecular weight Mn of from 500 to 5000 dalton by the cationic polymerization of isobutene or isobutene-containing hydrocarbon mixtures in the liquid phase, wherein the polymerization is carried out at a temperature of from -30 DEG to +40 DEG C. over a heterogeneous polymerization catalyst containing at least one element acting as promoter and selected from Group IB, Group IIB, Group IIIB, Group IVB, Group VB, Group VIIB, or Group VIIIB of the Periodic Table or from Group IIA, Group IIIA, Group IVA, Group VA, or Group VIA of the Periodic Table or a number of said elements in each case in the form of an oxygen-containing compound and zirconium in the form of an oxygen-containing compound, said polymerization catalyst containing no industrially effective amounts of halogens.

    METHOD OF PRODUCING POLYTETRAHYDROFURANE

    公开(公告)号:HUT78051A

    公开(公告)日:1999-07-28

    申请号:HU9901081

    申请日:1995-09-21

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03651 Sec. 371 Date Mar. 10, 1997 Sec. 102(e) Date Mar. 10, 1997 PCT Filed Sep. 21, 1995 PCT Pub. No. WO96/09335 PCT Pub. Date Mar. 28, 1996A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C1-C10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C1-C10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500 DEG to 1000 DEG C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.

    METODO PARA LA PRODUCCION DE POLIISOBUTENO REACTIVO, EXENTO DE HALOGENOS.

    公开(公告)号:MX9801040A

    公开(公告)日:1998-05-31

    申请号:MX9801040

    申请日:1996-08-05

    Applicant: BASF AG

    Abstract: Se describe un método para producir poliisobuteno reactivo exento de halogenos que tiene más del 50% molar de dobles enlaces terminales y un peso molecular promedio Mn de 500 a 5000 Daltons mediante la polimerizacion cationica de isobuteno o bien de mezclas de hidrocarburos que contienen isobuteno en la fase líquida, la polimerizacion se lleva a acabo a una temperatura comprendida entre -30 degree C y +40 degree C en un catalizador de polimerizacion heterogéneo que incluye al menos un elemento que actua como promotor seleccionado dentro del primer, segundo, tercer, cuarto, quinto, séptimo y octavo subgrupo de la tabla periodica de los elementos o bien a partir del segundo, tercer, cuarto, quinto o sexto grupo principal de la tabla periodica de la tabla periodica o bien varios elementos de este tipo, cada uno en forma de un compuesto que contiene oxígeno, más zirconio en forma de un compuesto que contiene oxígeno, el catalizador no contiene cantidades técnicamente significativa de halogenos.

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