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公开(公告)号:WO2005061447A3
公开(公告)日:2007-01-04
申请号:PCT/EP2004014444
申请日:2004-12-17
Applicant: BASF AG , BOTTKE NILS , TROPSCH JUERGEN , NARBESHUBER THOMAS , STEPHAN JUERGEN , ROEPER MICHAEL , HEIDEMANN THOMAS , STEINBRENNER ULRICH , BENFER REGINA
Inventor: BOTTKE NILS , TROPSCH JUERGEN , NARBESHUBER THOMAS , STEPHAN JUERGEN , ROEPER MICHAEL , HEIDEMANN THOMAS , STEINBRENNER ULRICH , BENFER REGINA
IPC: C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
CPC classification number: C07C6/04 , C07C2/08 , C07C2/66 , C07C5/2506 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C15/107
Abstract: The production of alkylaryl compounds comprises the following stages: a) reaction of a C4/C5 olefin mixture on a metathesis catalyst to produce a C 4-8 olefin mixture containing 2-pentene and the optional isolation of the C 4-8 olefin mixture; b) isolation of between 5 and 100 % of the 2-pentene obtained in step a) and subsequent reaction on an isomerisation catalyst to form a mixture of 2-pentene and 1-pentene, which is returned to stage a); c) dimerisation of the C 4-8 olefin mixture obtained in stage b) after the isolation process, to form a mixture containing C 8-16 olefins, isolation of the C 8-16 olefins and optional isolation of a partial stream of the latter; d) reaction of the C 8-16 olefin mixtures obtained in stage c) or the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst, to form alkyl aromatic compounds, whereby prior to the reaction an additional 0 to 60 wt. % linear olefins, in relation to the C 8-16 olefin mixtures obtained in stage c), can be added; e) optional sulphonation of the alkyl aromatic compounds obtained in stage d) and neutralisation to form alkylaryl sulphonates, whereby prior to the sulphonation an additional 0 to 60 wt. % linear alkyl benzols, in relation to the alkyl aromatic compounds obtained in stage d), can be added, provided that there were no admixtures in stage d); f) optional mixing of the alkylaryl sulphonates obtained in stage e) with between 0 and 60 wt. %, linear alkylaryl sulphonates, in relation to the alkylaryl sulphonates obtained in stage e), provided that there were no admixtures in stages d) and e).
Abstract translation: 烷基芳基化合物通过C4 / C5烯烃混合物的超过一个C含有2-戊烯 4-8 SUB>烯烃混合物的制备复分解催化剂的C 的)反应,和可选地移除该制剂 4-8 SUB>烯烃混合物,b)中的5%至100%的分离在步骤a)所得2-戊烯和异构化催化剂的2-戊烯与1-戊烯的混合物随后的反应,在阶段a) 再循环,C)C的分离之后,在步骤b中得到的二聚) 4-8 SUB>在二聚催化剂存在下烯烃混合物,得到含烯烃-C 8-16 SUB>混合物, 的C 8-16 SUB>烯烃,和任选除去一个部分流体,D)在步骤C中获得的化合物反应)C 8-16 SUB>烯烃混合物或所述部分与芳族料流的分离 在烷基化催化剂的存在下烃以形成烷基芳香族Ve的 rbindungen,其中 SUB>烯烃,e)可以反应,0〜60重量%之前添加到直链烯烃,基于在步骤c得到的)C在磺化 8-16,任选地 获得步骤d)的烷基芳族化合物中和以得到烷基芳基磺酸盐,其中之前的磺化,0至60重量%,基于在步骤d)中获得的烷基,可被加入到直链烷基苯的芳族化合物中,如果在步骤d没有掺合)下进行 中,f)如果到60重量%)的0)在步骤e中得到的烷基芳基磺酸盐的适当的混合,基于在步骤e烷芳基磺酸盐所获得的),线性烷基芳基磺酸盐,如果在步骤没有外加剂d)和e被执行。
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公开(公告)号:WO2004092096A3
公开(公告)日:2004-11-25
申请号:PCT/EP2004003928
申请日:2004-04-14
Applicant: BASF AG , STEINBRENNER ULRICH , NARBESHUBER THOMAS , UNGER JOERG , ZEHNER PETER , ZIMDAHL SOEREN , BENFER REGINA
Inventor: STEINBRENNER ULRICH , NARBESHUBER THOMAS , UNGER JOERG , ZEHNER PETER , ZIMDAHL SOEREN , BENFER REGINA
IPC: C07C2/66 , C07C15/107 , C07C303/06 , C07C303/08 , C07C309/31 , C07C2/70
CPC classification number: C07C303/08 , C07C2/66 , C07C15/107 , C07C303/06 , C07C309/31
Abstract: The invention relates to a method for producing alkyl aromatic compounds by reacting C3-30 olefins or alcohols, from which C3-30 olefins are formed under the reaction conditions, with an aromatic hydrocarbon in the presence of an alkylation catalyst. The reaction is carried out in a reactor cascade consisting of at least two reactors, whereby each of the reactors contain the alkylation catalyst, at least 80 % of the aromatic hydrocarbon is fed into the first reactor of the reactor cascade, and at least 40 % of the olefins are fed in an intermediate manner after the first reactor.
Abstract translation: 在由C3-30烯烃或醇从在烷基化催化剂的存在下在反应条件下C3-30烯烃形成与芳族烃时,该反应在至少两个反应器级联反应为烷基芳族化合物的制备方法 反应器中进行,每个所述含烷基化催化剂的反应器中,芳烃的至少80%的被进料到反应器级联的第一反应器中,烯烃的至少40%被供给至第一反应器之间。
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公开(公告)号:WO2004035530A3
公开(公告)日:2004-06-10
申请号:PCT/EP0311378
申请日:2003-10-14
Applicant: BASF AG , STEINBRENNER ULRICH , HEIDEMANN THOMAS , NARBESHUBER THOMAS , MAAS HEIKO , PRINZ MARTINA , BOTTKE NILS , TROPSCH JUERGEN , BENFER REGINA , FUNKE FRANK , STEPHAN JUERGEN
Inventor: STEINBRENNER ULRICH , HEIDEMANN THOMAS , NARBESHUBER THOMAS , MAAS HEIKO , PRINZ MARTINA , BOTTKE NILS , TROPSCH JUERGEN , BENFER REGINA , FUNKE FRANK , STEPHAN JUERGEN
IPC: C07C29/17 , C07C303/06 , C07C303/08 , C07C309/31 , C07C9/16 , C07C15/107 , C07C31/125 , C11D1/24
CPC classification number: C07C303/06 , C07C29/175 , C07C303/08 , C07C309/31 , C07C31/125
Abstract: The invention relates to a method for producing alkylaryl sulfonates, the alkylaryl sulfonates obtained according to said method, alcohol mixtures and olefin mixtures obtained as intermediate products, alkylaromatic compounds obtained therefrom, the use of said alkylaryl sulfonates as surfactants, and detergents containing said surfactants.
Abstract translation: 本发明涉及一种用于烷基芳基磺酸盐的制备方法,通过该方法获得和可作为烷基芳基磺酸盐中间体醇的混合物,以及由其烷基芳族化合物得到的烯烃混合物,使用烷基芳基磺酸盐表面活性剂和洗涤剂和含有它们的清洁剂。
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公开(公告)号:CA2417820C
公开(公告)日:2009-11-03
申请号:CA2417820
申请日:2001-08-10
Applicant: BASF AG
Inventor: MAAS HEIKO , NARBESHUBER THOMAS , ROPER MICHAEL
IPC: C07C303/32 , C07B61/00 , C07C15/107 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
Abstract: The invention relates to a process for the preparation of alkylarylsulfonate s by a) reaction of a C4-olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C10-12-olefins, and optional removal of the C10-12-olefins, c) reaction of the C10-12-olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with line ar alkylarylsulfonates.
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公开(公告)号:CA2544867A1
公开(公告)日:2005-07-07
申请号:CA2544867
申请日:2004-12-17
Applicant: BASF AG
Inventor: TROPSCH JUERGEN , ROEPER MICHAEL , STEPHAN JUERGEN , NARBESHUBER THOMAS , BOTTKE NILS , HEIDEMANN THOMAS , STEINBRENNER ULRICH , BENFER REGINA
IPC: C07C303/00 , C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
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公开(公告)号:CA2543744A1
公开(公告)日:2005-05-12
申请号:CA2543744
申请日:2004-10-29
Applicant: BASF AG
Inventor: STEPHAN JUERGEN , STEINBRENNER ULRICH , NARBESHUBER THOMAS , BOSCH MARCO , BOTTKE NILS , BENFER REGINA
Abstract: The invention relates to a method for producing alkylaryl compounds, by reacting a C10-14 monoolefin mixture with an aromatic hydrocarbon, in the presence of an alkylation catalyst to give alkylaromatic compounds and, optionally, by subsequent sulphonation and neutralisation of the obtained alkylaryl compounds. Said method is characterised in that, on average, in sa id C10-14 monoolefins, more than 0% and up to 100% of methyl branches are locat ed in the longest carbon chain and less than 50% of the methyl branches are located at the 2-, 3- and 4-position, counting from the ends of the longest carbon chain.
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公开(公告)号:DE59910856D1
公开(公告)日:2004-11-18
申请号:DE59910856
申请日:1999-07-15
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , NARBESHUBER THOMAS , GEHRER EUGEN , FISCHER ROLF , STEINBRENNER ULRICH , LIANG SHELUE
Abstract: A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 60 mol % and an average molecular weight Mn of 800-3000 dalton by cationic polymerization in the liquid phase of isobutene over an acidic, essentially halogen-free heterogeneous catalyst, wherea) a hydrocarbon mixture of essentially C4-hydrocarbons comprising isobutene in an amount of from 10 to 80% by weight is used as the starting material andb) polymerization is carried out continuously at from -30 to 0° C. with average starting material residence times of one hour or less, where the temperature and the residence time are selected such that the isobutene conversion is less than 60% and, after separation from the resulting polyisobutene, the isobutene is either enriched in the partially converted hydrocarbon mixture and returned to the polymerization or passed to another isobutene reaction coupled with the polymerization.
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公开(公告)号:AU2003294692A1
公开(公告)日:2004-05-04
申请号:AU2003294692
申请日:2003-10-14
Applicant: BASF AG
Inventor: STEINBRENNER ULRICH , HEIDEMANN THOMAS , NARBESHUBER THOMAS , MAAS HEIKO , PRINZ MARTINA , BOTTKE NILS , TROPSCH JURGEN , BENFER REGINA , FUNKE FRANK , STEPHAN JURGEN
IPC: C07C29/17 , C07C303/06 , C07C303/08 , C07C309/31 , C07C303/00
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公开(公告)号:BR0115857A
公开(公告)日:2003-10-14
申请号:BR0115857
申请日:2001-11-16
Applicant: BASF AG
Inventor: NARBESHUBER THOMAS , STEINBRENNER ULRICH , KRACK GERHARD
IPC: C07B61/00 , C07C2/08 , C07C2/66 , C07C15/00 , C07C15/107 , C07C303/32 , C07C309/28 , C07C309/31 , C11D1/22
Abstract: The preparation of alkylaryl compounds takes place by 1) preparation of a mixture of, on statistical average, predominantly monobranched C10-14-olefins by a) reaction of a C4-olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, followed by dimerization of the resulting 2-pentene and/or 3-hexene over a dimerization catalyst to give a mixture comprising C10-12-olefins, and optionally removal of the C10-12-olefins, or b) extraction of predominantly monobranched paraffins from kerosene cuts and subsequent dehydrogenation, or c) Fischer-Tropsch synthesis of olefins or paraffins, where the paraffins are dehydrogenated, or d) dimerization of shorter-chain internal olefins, or e) isomerization of linear olefins or paraffins, where the isomerized paraffins are dehydrogenated, 2) reaction of the olefin mixture obtained in stage 1) with an aromatic hydrocarbon in the presence of an alkylation catalyst which contains zeolites of the faujasite type.
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公开(公告)号:DE10150944A1
公开(公告)日:2002-05-02
申请号:DE10150944
申请日:2001-10-16
Applicant: BASF AG
Inventor: NARBESHUBER THOMAS , GEHRER EUGEN , BALFANZ ULRICH
Abstract: A catalyst with a bulk density of not more than 1.3 kg/l is used in a method for the alkylation of aromatics with olefins on a heterogeneous supported catalyst containing an oxide support material and a catalytically active amount of an oxygen-containing molybdenum and/or tungsten compound.
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