公开(公告)号：JPH0122268B2

公开(公告)日：1989-04-25

申请号：JP15783880

申请日：1980-11-10

Applicant: KAO CORP

Inventor： YASUDA YUTAKA ,  DOBASHI KYOSHI ,  NISHIMURA TOSHIRO

IPC: C07D233/22 ,  B01F17/32 ,  C07D233/26 ,  C08K5/3445

公开(公告)号：JPS6354410A

公开(公告)日：1988-03-08

申请号：JP19687686

申请日：1986-08-22

Applicant: KAO CORP

Inventor： YASUDA YUTAKA ,  SHIDA JUN ,  SUZUKI YOICHI

IPC: C08F2/06 ,  C08F2/04 ,  C08F20/22 ,  C08F220/10 ,  C08F220/18 ,  C08F220/22 ,  C09K3/18

Abstract: PURPOSE:To obtain the title copolymer which is safe and is useful for surface modification of an oil-soluble substance, by solution-polymerizing a fluoroalkyl group-containing polymerizable monomer with a specified alkyl group-containing compound in an aliphatic hydrocarbon solvent. CONSTITUTION:10-80wt% fluoroalkyl group-containing polymerizable monomer such as a (meth)acrylate, vinyl ester, vinyl ether, fumarate (maleate) or alpha-olefin containing a polyfluoroalkyl group or a perfluoroalkyl group is copolymerized with 90-20wt% compound having at least one 8C or higher alkyl group, such as a (meth)acrylate, an alkylvinyl ester, an alkyl vinyl ether, an alkyl fumarate (maleate) or an alpha-olefin in a 5C or higher linear, branched or cyclic aliphatic hydrocarbon solvent (e.g., n-hexane).

公开(公告)号：JPS6295398A

公开(公告)日：1987-05-01

申请号：JP23332085

申请日：1985-10-21

Applicant: KAO CORP

Inventor： MUKAI TAKASHI ,  HAMAI TOSHIMASA ,  YASUDA YUTAKA

IPC: C10M173/00 ,  C10M101/02 ,  C10M101/04 ,  C10M105/34 ,  C10M133/06 ,  C10M133/08 ,  C10M149/04 ,  C10M149/06 ,  C10M149/10 ,  C10M149/14 ,  C10M149/22 ,  C10N20/04 ,  C10N30/00 ,  C10N30/06 ,  C10N40/24

Abstract: PURPOSE:A novel metal-rolling oil that is obtained by adding dispersants and an amine to individual lubricant oils, thus showing good adhesion to the metal part to be processed, high lubricity and high emulsion stability. CONSTITUTION:The objective metal-rolling oil contains (A) at least one of lubricant oil selected from fat and oil, mineral oil and fatty acid esters, (B) at least one of dispersants selected from water-soluble cationic and/or ampholytic polymers which bear 2 or more basic N atoms or cationic N atoms and a molecular weight of 1,000-1,000,000 on the average, and (C) an amine selected from polyamines, hydroxylamines, 2-22C alkyl or aryl monoamines ring-opening polymer of ethylene imine of less than 3,000 molecular weight of the formula I (R , R are alkyl; R is 1-4C alkylene; R is H, 1-3C alkyl; R is 1-5C alkylene; X is formula II, hydroxyl; n is 0-5).

公开(公告)号：JPS6212710A

公开(公告)日：1987-01-21

申请号：JP15275585

申请日：1985-07-11

Applicant: KAO CORP

Inventor： FUKAZAWA JUNICHI ,  SATO TOMOJI ,  YASUDA YUTAKA ,  SHIDA JUN

IPC: A61K8/00 ,  A61K8/72 ,  A61K8/81 ,  A61K8/92 ,  A61Q1/00 ,  A61Q1/02 ,  A61Q1/04 ,  A61Q1/06 ,  A61Q1/10 ,  A61Q1/12

Abstract: PURPOSE:An oily solid cosmetic of stick type, pencil type, etc., having improved water resistance, oil resistance, friction resistance, slightly causing color migration and color release, containing an oil-soluble high polymer substance, a volatile oil agent and solid fats and oils as essential components. CONSTITUTION:An oily solid cosmetic comprising (A) an oil-soluble high polymer substance, (B) 5-80wt% volatile oil agent (e.g., dimethylpolysiloxane) having =8C long-chain alkyl on the side chain, rubber-like polymer (e.g., polyisoprene), etc. The amount of the component A is 0.1-50wt% based on the component B. The cosmetic has >=40g breaking strength in a cylinder with 12mm diameter at 25 deg.C.

公开(公告)号：JPS61255355A

公开(公告)日：1986-11-13

申请号：JP9755385

申请日：1985-05-08

Applicant: KAO CORP

Inventor： TSUSHIMA RIKIO ,  FUKUYAMA YUKIHIRO ,  TAKEMURA KAZUNARI ,  YASUDA YUTAKA

IPC: G03G9/08 ,  G03G9/087 ,  G03G9/09 ,  G03G9/097

Abstract: PURPOSE:To obtain a toner contg. a colorant with superior dispersibility, having an increased blackening degree and causing hardly fog during copying by dispersing carbon black in a monomer having a polymerizable unsatd. group in the presence of a perbasic sulfurized alkylphenol-alkaline earth metallic salt compound. CONSTITUTION:This toner contains a polymer binder, carbon black and a perbasic sulfurized alkylphenol-alkaline earth metallic salt compound represented by formula I (where each of R and R' is 6-100C straight chain or branched alkyl, M is an alkaline earth metal, m=0-5 and n=1-3). The amount of the compound added is

公开(公告)号：JPS6094904A

公开(公告)日：1985-05-28

申请号：JP20227383

申请日：1983-10-28

Applicant: KAO CORP

Inventor： TAKEMA YOSHINORI ,  TSUSHIMA RIKIO ,  YASUDA YUTAKA ,  KOUNO YOSHINAO

IPC: C08F16/00 ,  A61K8/00 ,  A61K8/02 ,  A61K8/04 ,  A61K8/72 ,  A61K8/81 ,  A61Q3/02 ,  A61Q19/00 ,  C08F16/02 ,  C08F216/06

Abstract: PURPOSE:To provide a film-forming cosmetic, especially film-forming pack, resistant to hydrolysis with time, and having substituted storage stability, by using a copolymer of vinyl alcohol and an alkyl vinyl ether as a component. CONSTITUTION:The objective cosmetic contains the copolymer (especially having an average molecular weight of 30,000-200,000) composed of 98-80mol% (especially 95-85mol%) vinyl alcohol monomer and 2-20mol% (especially 5- 15mol%) 1-6C straight or branched chain alkyl vinyl ether monomer unit, as a main component. The content of the copolymer is preferably 1-40wt%. The cosmetic is a homogeneous paste or liquid having low viscosity, and accordingly, is can be spread easily and uniformly on the skin, and dried in a short time. USE:Film-forming agent for nail enamel, eyeliner, mascara, hair-dressing, etc., and thickener, emulsifier, binder, etc. for various cosmetics such as milky lotion, foundation, cream, face powder, shampoo, etc.

公开(公告)号：JPS5782338A

公开(公告)日：1982-05-22

申请号：JP15931880

申请日：1980-11-12

Applicant: Kao Corp

Inventor： YASUDA YUTAKA ,  DOBASHI KIYOSHI ,  NISHIMURA TOSHIROU

IPC: C07C55/02 ,  C07C51/00 ,  C07C57/13 ,  C07C67/00

Abstract: PURPOSE: To obtain the titled compound usable as an emulsifying agent, dispersing agent, modifying agent for a high polymer, etc., by adding an acrylic ester easily to a certain (specific) kind of 2-alkyl-2-imidazoline, and hydrolyzing the addition product with an alkali or an acid.
CONSTITUTION: An acrylic ester in a substantially anhydrous state is added to an imidazoline, e.g. 1-(2-hydroxyethyl)-2-undecyl-2-imidazoline, of formulaI(R
1 is 6W20C alkyl or alkenyl) to give an intermeidate of formula II (R
2 is alkyl), which is then hydrolyzed with an alkali or acid to afford a dibasic fatty acid of formula III.
EFFECT: High yield through easy routes.
COPYRIGHT: (C)1982,JPO&Japio

Abstract translation: 目的：为了获得可用作乳化剂的标题化合物，分散剂，高聚物等的改性剂，通过将丙烯酸酯容易地添加到某种（特定的）2-烷基-2-咪唑啉中，并水解 加成产物用碱或酸。 构成：将基本上无水状态的丙烯酸酯加入到咪唑啉中， 1-（2-羟基乙基）-2-十一烷基-2-咪唑啉，式Ⅰ（R1为6-20C烷基或烯基），得到式Ⅱ的中间体（R2为烷基），然后用碱或酸水解 得到式III的二元脂肪酸。 效果：通过简单的路线产量高。