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公开(公告)号：ZA864668B
公开(公告)日：1987-02-25
申请号：ZA864668
申请日：1986-06-23
Applicant: STANDARD OIL CO OHIO
Inventor： HARRIS JONATHAN H , TENHOVER MICHAEL A , GRASSELLI ROBERT K , HENDERSON RICHARD S
Abstract: Amorphous metal alloys having the formula M¹ a M² b M³ c whereM¹ is Fe, Co, Ni, Pd and combinations thereof;M² is Ti, Zr, Hf, V, Nb, Ta and combinations thereof;M³ is Rh, Os, Ir, Pt and combinations thereof;a ranges from about 0 to 60;b ranges from 10 to 70; andc ranges from about 5 to 70, with the proviso that a + b + c = 100.These alloys have utility as anodes in electrolytic processes and a process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having an amorphous metal alloy anode of the formula M¹ a M² b M³ c .
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公开(公告)号：BR8602910A
公开(公告)日：1987-02-17
申请号：BR8602910
申请日：1986-06-24
Applicant: STANDARD OIL CO OHIO
Inventor： HARRIS JONATHAN H , TENHOVER MICHAEL A , GRASSELLI ROBERT K
Abstract: Novel rhodium based amorphous metal alloys having the formula RhrAa where: A is B, P, As and mixtures thereof; r is from about 50 to 96 percent; and a is from about 4 to 50 percent. Novel rhodium based amorphous metal alloys are also based on the formula RhrBbDd where: D is Ir, Pd, Ru, Ti, Zr, Nb, Ta, Y, Hf and mixtures thereof; r is from about 50 to 96 percent; b is from about 4 to 50 percent; and d is from about 0 to 60 percent; and r + b + d = 100. Novel process for the generation of halogens from halide-containing solutions can be performed by employing the rhodium based metal alloys of the present invention.
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公开(公告)号：NO862525L
公开(公告)日：1986-12-29
申请号：NO862525
申请日：1986-06-23
Applicant: STANDARD OIL CO OHIO
Inventor： TENHOVER MICHAEL A , HENDERSON RICHARD S , HARRIS JONATHAN H , GRASSELLI ROBERT K , WARD MICHAEL D
Abstract: Amorphous metal alloys having the formula M¹ a M² b M³ c whereM¹ is Fe, Co, Ni, Pd and combinations thereof;M² is Ti, Zr, Hf, V, Nb, Ta and combinations thereof;M³ is Rh, Os, Ir, Pt and combinations thereof;a ranges from about 0 to 60;b ranges from 10 to 70; andc ranges from about 5 to 70, with the proviso that a + b + c = 100.These alloys have utility as anodes in electrolytic processes and a process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having an amorphous metal alloy anode of the formula M¹ a M² b M³ c .
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公开(公告)号：BR8601379A
公开(公告)日：1986-12-02
申请号：BR8601379
申请日：1986-03-26
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT K , TENHOVER MICHAEL A , HARRIS JONATHAN H
IPC: C22C38/00 , B22F9/00 , C01B3/00 , C22C5/00 , C22C14/00 , C22C19/00 , C22C45/02 , C22C45/10 , H01M4/38
Abstract: @ Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formula A a M b M' c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd, and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwherein a ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95; characterized in that 1) a substantial portion of A is disposed on the surface of said material and/or 2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with. a bulk storage material comprising a reversible hydrogen storage material.
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公开(公告)号：GB2141356A
公开(公告)日：1984-12-19
申请号：GB8419584
申请日：1983-12-21
Applicant: STANDARD OIL CO OHIO
Inventor： BURRINGTON JAMES D , PESA FRED A , MAHER ELIZABETH , GRASSELLI ROBERT K
IPC: B01J23/56 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , B01J31/28 , C07B61/00 , C07C45/00 , C07C45/69 , C07C45/72 , C07C69/593 , C07C45/73 , C07C47/12 , C07C57/13 , C07C67/00 , C07C231/00 , C07C231/12 , C07C233/04 , C07C233/09 , C07C253/00 , C07C55/02 , C07C67/465 , C07C121/00 , C07C121/20
Abstract: A catalyst and a liquid phase process are provided for the dimerization of acrylic compounds. The process includes contacting an acrylic compound with the catalyst in the presence of hydrogen, wherein the catalyst comprises an inorganic oxide catalyst support, trivalent pendant atoms covalently bonded to the support and ruthenium complexed with said trivalent pendant atoms.
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Patent Agency Ranking106.发明专利
公开(公告)号：CS220305B2
公开(公告)日：1983-03-25
申请号：CS592874
申请日：1974-08-28
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT K , MILLER ARTHUR F , SHAW WILFRID G
IPC: C07C27/14 , B01J23/88 , B01J23/882 , B01J23/883 , B01J23/887 , B01J23/888 , B01J23/89 , B01J27/192 , B01J27/198 , B01J27/199 , C07B35/04 , C07B61/00 , C07C5/333 , C07C5/48 , C07C27/00 , C07C27/12 , C07C45/00 , C07C45/34 , C07C45/35 , C07C47/20 , C07C47/22 , C07C51/25 , C07C57/05 , C07C67/00 , C07C253/00 , C07C255/08 , B01J23/76
Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.
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公开(公告)号：CA1117120A
公开(公告)日：1982-01-26
申请号：CA300424
申请日：1978-04-04
Applicant: STANDARD OIL CO OHIO
Inventor： BARTEK JOSEPH P , GRASSELLI ROBERT K
IPC: B01J23/00 , B01J27/186 , B01J27/192 , C07B61/00 , C07C1/00 , C07C5/48 , C07C15/44 , C07C15/46 , C07C15/58 , C07C67/00 , C07D213/06 , C07D213/127 , C07D213/16 , C07D215/04
Abstract: This invention relates to an improved process for the dehydrogenation of alkyl-substituted aromatic compounds to the corresponding, alkenyl-substituted aromatics in the presence of oxygen and in the presence of an improved metal phosphate catalyst composition.
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公开(公告)号：CA1114833A
公开(公告)日：1981-12-22
申请号：CA278088
申请日：1977-05-10
Applicant: STANDARD OIL CO OHIO
Inventor： MILLER ARTHUR F , ZAGATA ROBERT J , GRASSELLI ROBERT K
Abstract: (4905) PREPARATION OF UNSATURATED CARBOXYLIC ESTERS FROM PROPYLENE OR ISOBUTYLENE The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.
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公开(公告)号：CA1107753A
公开(公告)日：1981-08-25
申请号：CA180443
申请日：1973-09-06
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT K , SURESH DEV D
IPC: C07C69/65 , B01J23/00 , B01J23/30 , B01J25/00 , B01J27/00 , C07B61/00 , C07C51/04 , C07C57/04 , C07C67/05 , C07C67/39 , C07C67/44 , C07C69/54 , C07C69/653
Abstract: PREPERATION OF ESTERS FROM UNSATURATED ALKEHYDES AND ALCOHOLS Acrylic esters and methacrylic esters are formed directly from the aldehyde by reacting acrolein or methacrolein with molecular oxygen and an alcohol in the presence of an oxidation catalyst under the conditions normally associated with the reaction of the aldehyde to the acid.
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公开(公告)号：RO76127A
公开(公告)日：1981-03-30
申请号：RO9492778
申请日：1978-08-09
Applicant: STANDARD OIL CO OHIO
Inventor： BRAZDIL JAMES F , SURESCH DEV D , GRASSELLI ROBERT K
IPC: B01J23/24 , B01J23/31 , B01J23/88 , B01J27/057 , B01J27/192 , B01J35/00 , B01J37/02 , C07C45/34 , C07C45/35 , C07C51/25 , B01J23/54 , C07C57/055
Abstract: Process for forming multi-component oxide catalysts. According to the invention the key catalytic phase of the catalyst is preformed and the elements of the host-catalyst phase are added together or separately. The key catalytic phase contains a molybdate or a tungstate of Bi, Te, Sb, Sn Cu or mixtures thereof. A representative catalyst is 50% [Bi2Mo3O12] 1/2 [K0.1Ni2.5Co4.5Fe3P0.5Mo10.5 Ox] + 50% SiO2 In the production of this catalyst a preformed bismuth molybdate slurry is added to a host-catalyst slurry. The mixture was then dried, calcined, ground and calcined once again.
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