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公开(公告)号:JPS6239168B2
公开(公告)日:1987-08-21
申请号:JP1372879
申请日:1979-02-08
Applicant: TORAY INDUSTRIES
Inventor: IIDA HIROSHI , OKAMOTO MASARU , YANAGI MASAKATA
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公开(公告)号:JPS6215572B2
公开(公告)日:1987-04-08
申请号:JP14783478
申请日:1978-12-01
Applicant: TORAY INDUSTRIES
Inventor: IIDA HIROSHI , OKAMOTO MASARU , MORIKAWA MASANOBU
IPC: C08G63/00 , C08G63/68 , C08G63/685
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公开(公告)号:JPS6067530A
公开(公告)日:1985-04-17
申请号:JP17639283
申请日:1983-09-26
Applicant: TORAY INDUSTRIES
Inventor: INOUE SHIYUNEI , OKAMOTO MASARU , ABE KOUICHI
IPC: C08G63/00 , C08G63/66 , C08G63/68 , C08G63/682
Abstract: PURPOSE:To provide a polyester capable of giving, in good formability, formed article of high strength and high modulus with adequately high melting point, having both specific two sorts of carboxylate units. CONSTITUTION:The objective copolyester having (A) 50-98mol% of a carboxylate unit of formula I and (B) 50-2mol% of a second carboxylate unit of formula II (R is of formula III or IV). The manufacturing process is as follows: (1) 50-98mol%, on a recurring unit basis, of polyethylene-1,2-bis(2-chlorophenoxy) ethane-4,4'-dicarboxylate with an intrinsic viscosity 0.4-1.20 and (2) 50-2mol% of an acyloxy aromatic carboxylic acid are made to react, at 250-300 deg.C, to prepare a prepolymer while eliminating the oxy acid generated. The resulting prepolymer is heated to 290-310 deg.C under a reduced pressure
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公开(公告)号:JPS5893719A
公开(公告)日:1983-06-03
申请号:JP19179081
申请日:1981-12-01
Applicant: TORAY INDUSTRIES
Inventor: OKAMOTO MASARU , INOUE SHIYUNEI , YANAGI MASAKATA
Abstract: PURPOSE:To obtain a copolyester excellent in melt flow property and capable of providing high strength and high modulus molding, by reacting an acyloxyaromatic carboxylic acid with a specified polyethylene terephthalate copolymer and poly condensing the product. CONSTITUTION:90-30mol% acyloxyaromatic carboxylic acid is reacted and polycondensed with 10-70mol% polyethylene terephthalated copolymer consisting of 40-80mol% polyethylene 4,4'-diphenyldicarboxylate units and 60-20mol% polyethylene terephthalated units. As the acyloxyaromatic carboxylic acid, p- acetoxybenzoic acid is particularly preferred. When the amount of an acyloxyaromatic carboxylic acid used is below 30mol% or above 80mol%, the copolyester finally produced does not have sufficient strength or modulus, which is not desirable.
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公开(公告)号:JPS5714643A
公开(公告)日:1982-01-25
申请号:JP8779880
申请日:1980-06-30
Applicant: TORAY INDUSTRIES
Inventor: IIDA HIROSHI , OKAMOTO MASARU , YANAGI MASAKATA
IPC: C08L67/00 , C08G59/00 , C08G59/18 , C08K3/34 , C08K7/14 , C08L7/00 , C08L21/00 , C08L23/00 , C08L63/00 , C08L63/10 , C08L67/02 , C08L101/00
Abstract: PURPOSE:The titled composition having improved processing characteristics of injection molding, providing a molded article having improved mechanical properties and surface smoothness, obtained by blending a polyethylene terephthalate with glass fibers, olefin type copolymer, finely divided talc and a lubricant with a specific melting point. CONSTITUTION:(A) 100pts.wt. polyethylene terephthalate having a relative viscosity preferably 1.2-2.0 is blended with (B) 1-150pts.wt. glass fibers as a reinforcing agent, (C) 0.1-100pts.wt. olefin type copolymer consisting of an alpha-olefin and (1-50wt%) alpha,beta-unsaturated acid glycidyl ester shown by the formula (R is H or lower alkyl), and (D) 0.05-50pts.wt. talc having diameters with volume particle diameter
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公开(公告)号:JPS5632537A
公开(公告)日:1981-04-02
申请号:JP10823579
申请日:1979-08-27
Applicant: TORAY INDUSTRIES
Inventor: IIDA HIROSHI , OKAMOTO MASARU , INOUE SHIYUNEI
IPC: C08L67/00 , C08K3/20 , C08K3/34 , C08K5/05 , C08K5/09 , C08K5/10 , C08K5/20 , C08K7/14 , C08K13/04 , C08L67/02
Abstract: PURPOSE:To titled composition suitable for a molded article having improved surface gloss and mechanical properties by an injection molding machine using relatively low-temperature mold, obtained by adding glass fibers with a specific average fiber length and a specific nuclearing agent and lubricant to polyethylene terephthalate. CONSTITUTION:100pts.wt. polyethylene terephthalate is blended with 5-100 pst.wt. glass fibers with an average fiber length 0.15-0.4mm., 0.1-2pts.wt. neutral clay, oxide of metal belonging to II group of periodic table, silicate, stearate of metal belonging to I or II groups, benzoate, terephthalate or monomethylterephthalate as a nuclearing agent, and 0.01-5pts.wt. montanate of metal belonging to I-III groups of periodic table or a montanate partly neutralized by 2-10C aliphatic diol, 10-40C higher fatty acid amide, fatty polyol dibenzoate or polyalkylene glycol dibenzoate, etc. as lubricant.
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公开(公告)号:JPS5569620A
公开(公告)日:1980-05-26
申请号:JP14113378
申请日:1978-11-17
Applicant: TORAY INDUSTRIES
Inventor: IIDA HIROSHI , OKAMOTO MASARU , MORIKAWA MASANOBU
Abstract: PURPOSE:Azomethinebisbenzoic acid is employed as a part of the dicarboxylic acid component, thus producing said polyester copolymer with high trasparency, toughness, high stiffness and heat resistance that is suitable used to inject moldings requiring high dimensional accuracy. CONSTITUTION:The polycondensation reaction between the aromatic dicaroxylic acid component containing 1-30, preferably 3-20mol% of azomethinebisbenzoic acid or its alkyl ester of the formula (R is H, 1-10C alkyl) and the aliphatic and/or alicyclic diol component is conducted to produce said polyester copolymer. EFFECT:Oriented films with high Young's modulus, heat resistance and dimensional stability are obtained by drawing the undrawn films made from said copolymer.
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公开(公告)号:JPS5566949A
公开(公告)日:1980-05-20
申请号:JP13997078
申请日:1978-11-14
Applicant: TORAY INDUSTRIES
Inventor: IIDA HIROSHI , OKAMOTO MASARU , MORIKAWA MASANOBU
Abstract: PURPOSE:A modified polyester composition capable of forming a high modulus film and molded article with improved toughness and heat resistance, and high modules fibers with improved heat resistance, obtained by blending a thermoplastic polyester with a phenolic compound in a molten state. CONSTITUTION:100 Parts by wt of a thermoplastic polyester is blended with 0.5- 50 parts by wt. of a phenolic compound shown by the formula I or II (R is an aliphatic group; A is a phenolic residue having one on two aromatic rings in a molten state. Polethylene terephthalate, polybutylene terephthalate, and polycyclohexanedimethylene terephthalate may be preferably cited as the thermoplastic polyester. Arylene bis (dialkyl carbonate) and its oligomer may be cited as the phenolic compound.
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公开(公告)号:JP2000313794A
公开(公告)日:2000-11-14
申请号:JP36647699
申请日:1999-12-24
Applicant: TORAY INDUSTRIES
Inventor: TANAKA OSAMU , OKAMOTO MASARU , GOTO YOSHIAKI
Abstract: PROBLEM TO BE SOLVED: To obtain a polyester resin composition capable of giving molded products having heavyweight feeling, texture and gloss each inherent in pottery and having a combination of impact resistance and chemical resistance as well. SOLUTION: This composition comprises 31-50 wt.% of a polybutylene terephthalate resin, 10-50 wt.% of a polyethylene terephthalate resin, 0-20 wt.% of a copolyester comprising at least two kinds of one or both of diol component and dicarboxylic acid component, and 10-46 wt.% of barium sulfate.
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公开(公告)号:JP2000240284A
公开(公告)日:2000-09-05
申请号:JP36212799
申请日:1999-12-21
Applicant: TORAY INDUSTRIES , SHIYOUKI KANAGATA KK
Inventor: OKAMOTO MASARU , GOTO YOSHIAKI , GOTO EIZO , MIZOSHITA MASAYUKI , ISAYAMA SHUICHI
Abstract: PROBLEM TO BE SOLVED: To provide a mortar adhesion auxiliary tool surely preventing the mortar from peeled off without turning a connector into a waste material by dispensing with a conventional connector detachment work. SOLUTION: This is an adhesion auxiliary tool for mortar to be applied on the surface of a skeleton concrete 20, and it is so constituted that a lot of lock parts 2 engaged with the mortar and a variable coupling part 5 arranged in such a state as surrounding the outside of the lock parts 2 are integrally molded by resin to the skeleton concrete surface side end of the connector part 1 which is connected to a spacer bolt 21 set in the concrete mold 24 and a frame support projection 4 brought into contact with the inside face of the concrete mold is integrally connected to the upper edge of the variable coupling part 5.
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