公开(公告)号：MX9704701A

公开(公告)日：1997-10-31

申请号：MX9704701

申请日：1995-12-16

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  WULFF-DORING JOACHIM

IPC: B01J25/00 ,  B01J25/02 ,  B01J37/00 ,  C07B31/00 ,  C07C253/30

Abstract: La presente invencion se refiere a un catalizador de hidrogenacion basado en un aleacion de aluminio y de un metal de transicion que se elabora preparado un material amasado a partir de la aleacion y un ayudante, la conversion del material amasado en piezas moldeadas, la calcinacion de las piezas moldeadas y el tratamiento de las piezas moldeadas calcinadas con un hidroxido de metal alcalino, mediante un proceso en el que el ayudante que se utiliza es: (a) alcohol polivinilico y agua o (b) ácido esteárico, y el catalizador preparado de acuerdo con la invencion se utiliza para la hidrogenacion e hidrogenolisis, en particular la hidrogenacion parcial de alfa, omega-dinitrilos alifáticos para obtener alfa, omega-aminonitrilos alifáticos.

公开(公告)号：CA2251539A1

公开(公告)日：1997-10-16

申请号：CA2251539

申请日：1997-04-04

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  HARDER WOLFGANG ,  MELDER JOHANN-PETER ,  FISCHER ROLF ,  VOIT GUIDO ,  SCHNURR WERNER

IPC: B01J25/02 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention concerns a method of simultaneously producing 6aminocapronitrile (ACN) and hexamethylenediamine (HMD) by reacting adipodinitrile (ADN) with hydrogen in the presence of a catalyst containing nickel, at a temperature not below room temperature and at an elevated hydrogen partial pressure, optionally in the presence of a solvent. If the yield, based on the amount of ADN consumed, and/or the selectivity, based on the amount of ACN produced, drop(s) below a defined value, a) the reaction of ADN with hydrogen is interrupted by stopping the feed of ADN and, if present, also the solvent; b) the catalyst is treated with hydrogen at a temperature in the range 150 to 400 ~C, using a hydrogen pressure of 0.1 to 30 MPa and a treatment time of 2 to 48 h; and c) the hydrogenation is subsequently continued using the catalyst treated in stage (b).

公开(公告)号：FI972762A

公开(公告)日：1997-06-26

申请号：FI972762

申请日：1997-06-26

Applicant: BASF AG

Inventor： MELDER JOHANN-PETER ,  SCHNURR WERNER ,  FLICK KLEMENS ,  EBEL KLAUS ,  WITZEL TOM ,  FISCHER ROLF ,  HARDER WOLFGANG ,  REHFINGER ALWIN

IPC: B01J23/76 ,  B01J23/89 ,  B01J23/889 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24 ,  C07C

Abstract: Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process which comprises using a catalyst which (a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and (b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and (c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal. with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or rhodium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.

公开(公告)号：AU4386796A

公开(公告)日：1996-07-19

申请号：AU4386796

申请日：1995-12-16

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  EBEL KLAUS ,  SCHNURR WERNER ,  MELDER JOHANN-PETER ,  HARDER WOLFGANG

IPC: B01J23/80 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24

Abstract: Aliphatic alpha , omega -aminonitriles are prepared by partial hydrogenation of aliphatic alpha , omega -dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst, by a process in which the catalyst used is obtainable by thermal decomposition of a metal compound selected from the group consisting of metal carbonyl compounds, metal salts of C1-C6-carboxylic acids and C2-C6-dicarboxylic acids and metal complexes with diketones to give the corresponding metal and/or a metal oxide thereof, with the proviso that the metal used is nickel or cobalt.

公开(公告)号：AU4386696A

公开(公告)日：1996-07-19

申请号：AU4386696

申请日：1995-12-16

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  WULFF-DOERING JOACHIM

IPC: B01J25/00 ,  B01J25/02 ,  B01J37/00 ,  C07B31/00 ,  C07C253/30

Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

公开(公告)号：CA2304848C

公开(公告)日：2008-07-15

申请号：CA2304848

申请日：1998-09-08

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF HARTMUTH ,  MERGER MARTIN ,  VOIT GUIDO ,  ANSMANN ANDREAS ,  FLICK KLEMENS

IPC: B01J23/78 ,  C07C253/30 ,  B01J23/745 ,  C07B61/00 ,  C07C255/24 ,  C07C255/26

Abstract: The invention relates to a method for producing aliphatic alpha, omega-amino nitriles in the presence of a catalyst composed of (a) iron or an iron based compound or a mixture thereof, (b) 0.01 to 5 wt. % in relation to (a) a promotor based on 2, 3, 4, or 5 elements selected from the group comprising aluminum, silicium, zirconium, titanium and vanadium and (c) 0 to 0.5 wt. % in relation to (a) a compound based on an alkaline metal or alkaline-earth metal. The inventive method is characterized in that the applied aliphatic alpha, omega-amino dinitrile contains 1.0 wt. ppm or more phosphor. Catalysts are obtainable through the reduction and optional successive passivation of a magnetite, whereby the catalysts have a BET surface of 3 to 10 m2/g, a total pore volume of 0.05 to 0.2 ml/g, an average pore diameter of 0.03 to 0.1 mm and a pore volume portion in the range of 0.01 to 0.1 mm of 50 to 70 %.

公开(公告)号：MY120420A

公开(公告)日：2005-10-31

申请号：MYPI9700229

申请日：1997-01-22

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH ,  HEINEKE DANIEL ,  FLICK KLEMENS

IPC: B01J23/36 ,  B01J23/44 ,  B01J23/46 ,  B01J37/16 ,  C07B61/00 ,  C07D301/00 ,  C07D303/04

Abstract: A PROCESS FOR PREPARING 1,2-BUTYLENE OXIDE BY CATALYTIC HYDROGENATION OF VINYLOXIRANE OVER A HETEROGENEOUS CATALYST COMPRISES USING A CATALYST PREPARED BY APPLYING AT LEAST ONE ELEMENT OF GROUPS 7 TO 11 OF THE PERIODIC TABLE IN THE FORM OF A SOL TO AN INERT SUPPORT.

公开(公告)号：MY118922A

公开(公告)日：2005-02-28

申请号：MYPI9804366

申请日：1998-09-23

Applicant: BASF AG

Inventor： BOHNSACK ANDREAS ,  VOIT GUIDO ,  LUYKEN HERMANN ,  FLICK KLEMENS ,  MERGER MARTIN ,  BASSLER PETER ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/745 ,  C07C253/30 ,  C07B61/00 ,  C07C255/24 ,  C07C255/26

Abstract: ALIPHATIC ALPHA, OMEGA-AMINONITRILES ARE PREPARED IN THE PRESENCE OF A CATALYST WHICH CONTAINS(A)IRON OR A COMPOUND BASED ON IRON OR A MIXTURE THEREOF, (B)FROM 0.01 TO 5BY WEIGHT, BASED ON (a), OF A PROMOTER BASED ON 2, 3, 4, AND 5 ELEMENTS SELECTED FROM A GROUP CONSISTING OF ALUMINUM, SILICON, ZIRCONIUM, TITANIUM AND VANADIUM AND (C)FROM 0 TO 0.5BY WEIGHT, BASED ON(a), OF A COMPOUND BASED ON AN ALKALI METAL OR ALKALINE EARTH METAL, BY A PROCESS IN WHICH THE ALIPHATIC ALPHA, OMEGA-DINITRILE USED CONTAINS 2.0 PPM BY WEIGHT OF MORE OF PHOSPHORUS. CATALYSTS ARE OBTAINABLE BY THE REDUCTION AND, IF REQUIRED, SUBSEQUENT PASSIVATION OF A MAGNETITE, THE CATALYSTS HAVING A BET SURFACE AREA OF FROM 3 TO 10 M2/G, WITH A TOTAL PORE VOLUME OF FROM 0.05 TO 0.2 M1/G, AN AVERAGE PORE DIAMETER OF FROM 0.03 TO 0.1 µM AND A PORE VOLUME FRACTION OF FROM 50 TO 70IN THE RANGE OF FROM 0.01 TO 0.1 µM.

公开(公告)号：MY116967A

公开(公告)日：2004-04-30

申请号：MYPI9704170

申请日：1997-09-09

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  VOIT GUIDO ,  LUYKEN HERMANN ,  FLICK KLEMENS ,  BABLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A PROCESS FOR COPRODUCTION OF 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE STARTING FROM A MIXTURE COMPRISING A PHOSPHORUS-CONTAINING COMPOUND AND ESSENTIALLY ADIPONITRILE AND OBTAINED BY REACTION OF BUTADIENE WITH HYDROCYANIC ACID IN THE PRESENCE OF A CATALYST COMPRISING A PHOSPHORUS-CONTAINING COMPOUND COMPRISES (1)REDUCING THE WEIGHT PROPORTION OF PHOSPHORUS-CONTAINING COMPOUND, CALCULATED AS PHOSPHORUS, IN THE MIXTURE, (2)PARTIALLY HYDROGENATING THE RESULTING MIXTURE IN THE PRESENCE OF A CATALYST TO FORM AN (ALPHA),( )-AMINONITRILE, AND (3)REMOVING 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE FROM THE MIXTURE.

公开(公告)号：CZ292717B6

公开(公告)日：2003-12-17

申请号：CZ324898

申请日：1997-04-03

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF-HARTMUTH

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The present invention relates to a process for preparing compounds containing NHi2 groups by hydrogenating compounds having at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures being higher thane room temperature and an elevated hydrogen partial pressure in the presence or absence of a solvent, which preparation process comprises (a) using a catalyst comprising a cobalt- and/or iron catalyst, (b) interrupting the hydrogenation when the hydrogenated compound transformation degree and/or selectivity of the required product drops below a defined limit or when the amount of undesired byproducts increases above a defined limit by stopping the feed of the compound to be hydrogenated, (c) treating the catalyst at a temperature ranging from 150 to 400 degC with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 hours, and (d) subsequently continuing the hydrogenation of the compound having at least one unsaturated carbon-nitrogen bond as well as the regeneration of cobalt- and/or iron-containing catalysts.