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    Print pastes for printing materials having a smooth surface
    132.
    发明专利
    Print pastes for printing materials having a smooth surface 未知

    公开(公告)号：GB1098916A

    公开(公告)日：1968-01-10

    申请号：GB760766

    申请日：1966-02-22

    Applicant: BASF AG

    Inventor： GULBINS KLAUS ,  WILHELM HANS ,  LANGE GUENTER ,  SIXTUS HEINRICH ,  HARTMANN EDUARD

    IPC: C09D11/02

    Abstract: A print paste contains as the binder and as the colouring agent a film-forming copolymer of: (a) at least one dye which bears a polymerisable group; (b) at least one ester of a polymerizable carboxylic acid; and (c) at least one polymerizable hydrocarbon. At least one other comonomer may be included. Component (a) may be replaced by (c) at least one comonomer having a reactive group and (f) at least one dye having a group complementary to the reactive group in (e). Suitable dyes (a) include particularly those of the azo and anthraquinone series, but may also include, for example triphenylmethane dyes. The polymerizable groups are preferably acrylic, acryloylamino, acryloyloxyalkyl, acryloyloxyaryl and vinyl groups. In Example I a coloured copolymer I is prepared by copolymerization of a dye of formula methyl methacrylate, styrene and the butyl ether of methylolmethacrylamide in methyl ethyl ketone with azodiisobutyronitrile as catalyst. Copolymer II is prepared by solution polymerization of vinyl chloride, vinyl acetate and acrylic acid under the same conditions. A print paste is then prepared by dissolving copolymers I and II in methyl ethyl ketone. In Example II a dye of formula acrylonitrile, methyl methacrylate, ethyl acrylate, styrene and itaconic acid are copolymerized in M.E.K. in the presence of azodiisobutyronitrile and a print paste prepared by dissolving this in M.E.K.ALSO:A print paste contains as binder and colouring agent a film forming copolymer of (a) at least one dye which bears a polymerisable group; (b) at least one ester of a polymerisable carboxylic acid and (c) at least one polymerisable hydrocarbon. At least one other comonomer may be included. Component (a) may be replaced by (e) at least one comonomer having a reactive group and (b) at least on dye having a group complementary to the reactive group in (e). Suitable dyes are those of the azo and anthraquinone series and triphenylmethane dyes. The pastes are suitable for printing smooth materials particularly foils, films and sheets of plastics or aluminium. In Example 1 a gravure printing machine is used to print on unlacquered polyethylene film and polyvinyl chloride film.ALSO:A print paste contains as binder and colouring agent a film forming copolymer of (a) at least one dye which bears a polymerisable group; (b) at least one ester of a polymerisable carboxylic acid and (c) at least one polymerisable hydrocarbon. At least one other comonomer may be included. Component (a) may be replaced by (e) at least one comonomer having a reactive group and (f) at least one dye having a group complementary to the reactive group in (e). Suitable dyes are those of the azo and anthraquinone series and triphenyl methane dyes. The pastes are suitable for printing smooth materials particularly foils, films and sheets of plastics or aluminium. In Example 1 a gravure printing machine is used to print on unlacquered aluminium foil, polyethylene film and polyvinyl chloride film.

    Print pastes
    133.
    发明专利
    Print pastes 未知

    公开(公告)号：GB1097770A

    公开(公告)日：1968-01-03

    申请号：GB5337365

    申请日：1965-12-16

    Applicant: BASF AG

    Inventor： WILHELM HANS ,  GULBINS KLAUS ,  MARX MATTHIAS ,  LANG GUENTER ,  SCHWINDT WOLFGANG ,  FAULHABER GERHARD

    IPC: D06P1/00

    Abstract: A print paste consists of a hydrocarbon liquid phase and an aqueous phase and contains as colouring agent a coloured copolymer prepared from 10 to 70 parts by weight of an ester of (a) acrylic or methacrylic acid, and (b) an aliphatic or cycloaliphatic alcohol having at least six carbon atoms; 1 to 40 parts of a comonomer containing an N-methylol group or N-methylol ether group; 1 to 12 parts of a copolymerizable dye; 4 to 15 parts of an alpha, beta-unsaturated mono- or di-carboxylic acid; 0 to 20 parts of an unsaturated polymerizable hydroxy compound and 0 to 84 parts of one or more other monomers; at least 50% of the free carboxyl groups in the copolymer having been neutralized by ammonia or nitrogenous organic bases. Suitable N-methylol monomers are the alkyl ethers of N-methylol arylamide and N-methylol methacrylamide and of carboxylic imides. Preferred dyes are azo and anthraquinone dyes. The organic base may be an aliphatic or heterocyclic amine. The print paste may include an aminoplast-forming substance and a cure catalyst. In Example 1, a xylene solution of a copolymer formed from alpha - ethylhexyl acrylate, N - butoxymethyl acrylamide, styrene, butanediol monoacrylate, acrylic acid and 2,4,5-trichloro-41-(N-ethyl-N-acryloyloxyethyl)-azobenzene which has been neutralized with dimethyl ethanolamine is mixed with water, NH4NO3 and white spirit. The azo dye may be replaced by 4-nitro-41-(N - ethyl - N - acryloyloxyethyl) - azobenzene or 1 - amino - 2 - isopropylcarboxy - 4 - acryloylaminoanthraquinone. In Example 2, N-butoxymethyl methacrylamide and hydroxy-5 - tertiary butyl - 41 - acryloylaminoazobenzene replace the N-methylol ether and the azo dye used in Example 1. The pastes are used to print fabrics (see Division D1).ALSO:An emulsion-thickened print paste consists of a hydrocarbon liquid phase, an aqueous phase and a coloured copolymer which has been prepared from: 10 to 70 parts by weight of an ester of (a) acrylic or methacrylic acid and (b) an aliphatic or cycloaliphatic alcohol having at least six carbon atoms; 1 to 40 parts of a comonomer containing an N-methylol or N-methylol ether group; 1 to 12 parts of a copolymerisable dye; 4 to 15 parts of an alpha, beta-unsaturated mono- or di-carboxylic acid; 0 to 20 parts of an unsaturated polymerisable hydroxy compound; and 0 to 84 parts of one or more other monomers; at least 50% of the free carboxyl groups in the copolymer having been neutralised by ammonia or nitrogenous organic bases. In Example 1 a xylene solution of a copolymer formed from alpha-ethylhexyl acrylate, N-butoxymethyl acrylamide, styrene butanediol monoacrylate, acrylic acid and 2, 4, 5-trichloro-4\sv - (N - ethyl- N -acryloyloxyethyl)-azobenzene which has been neutralised with dimethyl ethanolamine is mixed with water, NM4NO3 and white spirit. Cotton cloth is printed with the resulting paste and heated to yield orange prints. Red or violet prints are obtained when the azo dye is replaced by 4-nitro-4\sv-(N-ethyl-N-acryloyloxyethyl)-azobenzene or 1-amino-2-isopropylcarboxy - 4 - acryloylaminoanthraquinone. In Example 2, N-butoxymethyl methacrylanide and hydroxy - 5 - tertiarybutyl-4\sv-acryloylaminoazobenzene are used in place of p the N-methylol ether and azo dye in Example 1 and the paste is used to print cotton or polypropylene.

    Simultaneous dyeing and finishing of leather and the dyed leather thus obtained
    136.
    发明专利
    Simultaneous dyeing and finishing of leather and the dyed leather thus obtained 未知

    公开(公告)号：GB1063219A

    公开(公告)日：1967-03-30

    申请号：GB4373565

    申请日：1965-10-15

    Applicant: BASF AG

    Inventor： WUERTELE LOTHAR ,  WILHELM HANS ,  SCHUBERT RUDOLF ,  LANGE GUENTER ,  GULBINS KLAUS

    IPC: D06P3/32

    Abstract: Leather is simultaneously dyed and finished by treatment with an aqueous solution or dispersion comprising (I) a polymer having reactive groups X, (II) one or more dyes having reactive groups Y and, optionally (III) a cross-linking component having at least two reactive groups Z per molecule and allowing the components to react at 20 - 120 DEG C in the presence of an acid or alkaline catalyst, where the number of groups Y is less than the number of X and the amount Y + Z being approximately equal to X, the groups X being possibly alkylated N-methylolamide groups and Y and Z being the same or amino or amido groups or vice versa as complementary pairs. Suitable catalysts are ammonium nitrate or ammonium chloride while numbers of suitable compounds (I), (II) and (III) are specified. The components may be applied together or in sequence by brushing, dipping, spreading, spraying or drumming and the subsequent heating may be carried out in drying chambers or hot grain embossing rolls. Examples are given.

    Production of expanded polyamides
    138.
    发明专利
    Production of expanded polyamides 未知

    公开(公告)号：GB1049666A

    公开(公告)日：1966-11-30

    申请号：GB3612663

    申请日：1963-09-13

    Applicant: BASF AG

    Inventor： BAYERLEIN FRIEDRICH ,  WILHELM HANS

    IPC: C08G69/18 ,  C08J9/00

    Abstract: Expanded polyamides are produced by heating a mixture of (A) one or more lactams having seven to fourteen ring members, (B) one or more alkaline catalysts, (C) one or more activators and (D) agents which under the prevailing conditions of polymerization volatilize or decompose with the evolution of gas thereby causing the polymerization product to expand, in the absence of substances containing or forming hydroxyl groups to temperatures above the melting point of the lactam and not more than 200 DEG C. and polymerizing the melt with expansion in the presence of 0.05 to 5% by weight of calcined gypsum with reference to the total weight of the polyamide forming materials. Lactams which are suitable are those of omega-aminocarboxylic acids such as caprolactam, oenantholactam, capryllactam, caprilactam and laurolactam. C-substituted lactams, e.g. 4-isopropylcaprolactam and lactams having chain-branching or cross-linking effects, e.g. alkylene-bis lactams may also be used. Suitable alkaline catalysts are metals such as sodium, potassium and calcium or compounds of these metals such as potassamide, sodium alcoholates and sodium hydroxide, organometallic compounds and especially alkali lactamates. Specified activators are acyl-lactams, monoisocyanates, polyisocyanates, acid derivatives such as carboxylic acid halides, esters or anhydrides, but particularly substituted ureas, thioureas, guanidines and urethanes. Examples of these are hexamethylene-1,6-biscarbamidocapryllactam or phenylcarbamidocaprolactam. Suitable expanding agents are aliphatic and cycloaliphatic hydrocarbons such as hexane, octane and cyclohexane, aromatic hydrocarbons such as benzene and toluene and straight-chain and cyclic ethers such as dibutyl ether and dioxane. Liquids having low boiling points, e.g. pentane may be used under pressure. Solid compounds, such as azoisobutyronitrile, benzene sulphonic acid hydrazide and arylsulphazides may also be used. Dyes, fillers and stabilizers may also be incorporated in the mixture.

    Anionic polymerisation of lactams
    139.
    发明专利
    Anionic polymerisation of lactams 未知

    公开(公告)号：GB1043678A

    公开(公告)日：1966-09-21

    申请号：GB173464

    申请日：1964-01-15

    Applicant: BASF AG

    Inventor： GEHM ROBERT ,  STEINBRUNN GUSTAV ,  JENTZSCH WOLFGANG ,  WILHELM HANS ,  BAYERLEIN FREDERICH ,  SCHICKH OTTO VON

    IPC: C08G69/20

    Abstract: In a process for the anionic polymerization of lactams having 5 to 14 ring members, the polymerization activator used is a compound of the general formula where n is 1 or 2, R1 and R2 are each monovalen hydrocarbon radicals having one to seven carbon atoms or R1 and R2 joined together form a divalent radical, R3 is hydrogen or a hydrocarbon radical having one to eight carbon atoms and R, when n is 1 is an alkyl amine, arylamino or aralkylamino radical having one to fourteen carbon atoms, and, when n is 2 is a divalent radical having the formula -NH-R3-NH- where R4 is a divalent hydrocarbon radical having two to fifteen carbon atoms. Specified lactams are pyrrolidone, piperidone, e -caprolactam, capryllactam, oenanthiclactam, capriclactam, laurolactam, e -ethyl-e -caprolactam, #x-ethyl-#x-oenantholactam and methylenebis-caprolactam. Fillers, e.g. glass fibres, asbestos, graphite, gypsum, chalk, molybdenum sulphide, wood flour and fibres may be incorporated into the polymerization mixture. In Examples (1) to (6), e -caprolactam is polymerized in the presence of sodium caprolactam and: (1) benzimidazole-1-carboxylic anilide; (2) imidazole-1-carboxylic acid N : N1-diphenyl amide; (3) benzimidazole-1-carboxylic acid (N1-methyl) anilide; (4) 2-methylimidazoline-N(1)-carboxylic acid N : N1-diphenyl amide; (5) N : N - hexamethylene - bis - (carbamyldimethyl formamidine) and (6) (a) hexamethylene - bis - (N1 - carbamyl - 2 - methylimidazoli (b) hexamethylene-bis-(N-carbamyltriphenyl formamidine). In Example (7) pyrrolidone is polymerized in the presence of sodium methylate and imidazole-1-carboxylic diphenylamide.

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