公开(公告)号：HU181951B

公开(公告)日：1983-11-28

申请号：HUSA002687

申请日：1974-09-03

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  MILLER ARTHUR F ,  SHAW WILFRID G

IPC: C07C27/14 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  B01J27/198 ,  B01J27/199 ,  C07B35/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/31

Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.

公开(公告)号：CA1151635A

公开(公告)日：1983-08-09

申请号：CA365087

申请日：1980-11-20

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  BRAZDIL JAMES F ,  RATKA FRANCES I

IPC: B01J23/54 ,  B01J23/00 ,  B01J23/888 ,  B01J27/02 ,  B01J27/057 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/00 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C51/00 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/70 ,  C07C27/12 ,  C07C120/14

Abstract: Certain multiply promoted Sn-Sb oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxydehydrogenation of olefins to diolefins.

公开(公告)号：RO70128A

公开(公告)日：1982-10-11

申请号：RO8290875

申请日：1975-07-21

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  HARDMAN HARLEY F

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/881 ,  B01J23/887 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J27/192 ,  C07B31/00 ,  C07B33/00 ,  C07B35/04 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/12 ,  C07C27/00 ,  C07C27/14 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08 ,  C07C5/42

公开(公告)号：RO77761A

公开(公告)日：1981-11-24

申请号：RO9481478

申请日：1978-07-27

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  FRIEDRICH MARIA S ,  SURESH DEV O ,  ORNDOFF DAVID A

IPC: B01J23/28 ,  B01J23/88 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J23/00

公开(公告)号：CS203197B2

公开(公告)日：1981-02-27

申请号：CS496978

申请日：1978-07-26

Applicant: STANDARD OIL CO OHIO

Inventor： GUTTMANN ANDREW T ,  GRASSELLI ROBERT K

IPC: B01J23/16 ,  B01J23/85 ,  C07C47/21

公开(公告)号：RO75590A

公开(公告)日：1981-01-30

申请号：RO9048177

申请日：1977-05-26

Applicant: STANDARD OIL CO OHIO

Inventor： MILLER ARTHUR F ,  ZAGATA ROBERT J ,  GRASSELLI ROBERT K

IPC: B01J23/00 ,  C07B61/00 ,  C07C67/39 ,  C07C69/54

Abstract: The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.

公开(公告)号：CS199528B2

公开(公告)日：1980-07-31

申请号：CS279578

申请日：1978-05-02

Applicant: STANDARD OIL CO OHIO

Inventor： BARTEK JOSEPH P ,  GRASSELLI ROBERT K

IPC: B01J23/00 ,  B01J27/186 ,  B01J27/192 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C15/44 ,  C07C15/46 ,  C07C15/58 ,  C07C67/00 ,  C07D213/06 ,  C07D213/127 ,  C07D213/16 ,  C07B3/00

公开(公告)号：CA1075709A

公开(公告)日：1980-04-15

申请号：CA231660

申请日：1975-07-16

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  HARDMAN HARLEY F

IPC: B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/02 ,  B01J27/192 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C47/20 ,  C07C57/04

Abstract: The present invention is a process for the oxidation of olefins to unsaturated aldehydes and acids using a catalyst containing iron, bismuth, molybdenum plus at least one of nickel, cobalt, magnesium, zinc, cadmium or calcium and according to the invention, an element selected from cerium, thorium, niobium, praseodymium, yttrium, zirconium, ruthenium, gallium, indium, copper, lanthanum, or antimony. These catalysts may also contain certain elements that further enhance the desirability of the oxidation process.

公开(公告)号：CA1075669A

公开(公告)日：1980-04-15

申请号：CA242831

申请日：1975-12-30

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D

IPC: B01J23/02 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  C07B61/00 ,  C07C255/08 ,  B01J23/00

Abstract: OXIDATION CATALYSTS The invention is an oxidation catalyst which contains at least a Group IIA or Group IIB element or manganese plus as required elements, chromium, bismuth and molybdenum. The catalysts can optionally contain a number of other elements and are useful for various oxidation reactions, especially the ammoxidation of propylene or isobutylene to obtain acrylonitrile or methacrylonitrile, the oxidation of propylene or isobutylene to obtain acrolein or methacrolein and the oxidative dehydrogenation of olefins containing 4 or 5 carbon atoms to obtain the corresponding diolefin.

公开(公告)号：CA1065270A

公开(公告)日：1979-10-30

申请号：CA235817

申请日：1975-09-18

Applicant: STANDARD OIL CO OHIO

Inventor： BARTEK JOSEPH P ,  CROSBIE LAWRENCE P ,  GRASSELLI ROBERT K

IPC: C10G35/06 ,  B01J21/04 ,  B01J23/40 ,  B01J23/52 ,  B01J23/56 ,  B01J23/64 ,  B01J23/70 ,  B01J29/18 ,  B01J35/08 ,  C10G35/09 ,  C10G35/04

Abstract: SHAPED CATALYST FOR NAPHTHA REFORMING The present invention is the use of amphora shaped catalysts in the known process of naphtha reforming. Catalysts employed in naphtha reforming have been found to be unexpectedly superior to other commercial catalyst forms when placed in the amphora shape, which is a substantially spherical outer surface with a void center having a cavity in the external surface communicating with the void center.