公开(公告)号：EP0303987A2

公开(公告)日：1989-02-22

申请号：EP88113133.8

申请日：1988-08-12

Applicant: ATOCHEM NORTH AMERICA, INC.

Inventor： MacLeay, Ronald Edward ,  Kazmierczak, Robert Thaddeus

IPC: C08F8/30

CPC classification number: C08F8/30 ,  C08F22/00

Abstract: There are provided polymer bound hindered amine light stabilizers with recurring units selected from
or both in which the units occur, e.g., in the polymer backbone and wherein R¹ and R² are, e.g., hydrogen or alkyl of 1 to 6 carbons, x is an integer of 0 or 1, and G has the structure
wherein X is, e.g., -Z-C(=O)-R⁹-C(=O)-N(R⁸)- where Z is, e.g., -N(R¹⁰)-, R⁹ is, e.g., a direct bond and R⁴, R⁵, R⁶, R⁸ and R¹⁰ are, e.g., hydrogen. They are prepared by reacting hindered amine light stabilizers containing reactive hydrazide functionalities with anhydride containing polymers or copolymers. The reactions may be carried out in an inert solvent or in a melt blending step. The polymer bound hindered amine light stabilizers are useful alone or may also be used to stabilize other polymers, copolymers or polymer blends against the deleterious effects of heat and/or light.

Abstract translation: 提供了聚合物结合的受阻胺光稳定剂，其具有选自的重复单元或其中单元出现的二者，例如在聚合物主链中，并且其中R 1和R 2是例如氢或烷基 1至6个碳，x为0或1的整数，G具有结构，其中X为例如-ZC（= O）-R 9 -C（= O）-N（R' 8）） - 其中Z为例如-N（R 1） - ，R 9为例如直接键合，R 4，R 5，R 6， R 8和R 1是例如氢。 它们通过将含有反应性酰肼官能团的受阻胺光稳定剂与含酸酐的聚合物或共聚物反应来制备。 反应可以在惰性溶剂中或在熔融共混步骤中进行。 聚合物结合的受阻胺光稳定剂可单独使用或也可用于稳定其它聚合物，共聚物或聚合物共混物以抵抗热和/或光的有害影响。

公开(公告)号：EP0303986A2

公开(公告)日：1989-02-22

申请号：EP88113131.2

申请日：1988-08-12

Applicant: ATOCHEM NORTH AMERICA, INC.

Inventor： MacLeay, Ronald Edward ,  Myers, Terry Ned

IPC: C08F8/30 ,  C08F8/34

CPC classification number: C08F8/30 ,  C08F8/34

Abstract: These are provided polymer bound stabilizers with recurring units selected from the formulas
or both wherein the units occur, e.g., in the polymer back­bone, x is 0 or 1, R¹ and R² are, e.g., hydrogen, and each - -

is the residue of a primary amino or hydrazido substituted stabilizer group selected from (a) hindered phenols, (b) hindered amine light stabilizers, (c) 2-hydroxybenzophenones, (d) 2-(2-hydroxyphenyl)-2H-benzotriazoles, (e) secondary aromatic amines, (f) benzothiazoles or benzimidazoles, (g) aryl salicylates, (h) salicylic acid derivatives (i) oxamide derivatives and (j) dialkyl sulfides, with the proviso that at least two different groups from (a) through (j) are attahced to the polymer. The polymeric stabilizers are prepared by the reaction of primary amino or hydrazido substituted stabilizers with some or all of the anhydride groups of the polymer or copolymer. They are not lost from the polymer by volatilization, migration or extraction, even at high temperature and may be used as concentrates to stabilize other polymers.

Abstract translation: 这些提供了聚合物结合稳定剂，其具有选自式CHEM的重复单元或其中单元出现的二者，例如在聚合物主链中，x为0或1，R 1和R 2为例如氢 ，（a）受阻酚，（b）受阻胺光稳定剂，（c）2-羟基二苯甲酮，（d）2-（2-羟基苯基） ）（2-） - 苯并三唑，（e）仲芳族胺，（f）苯并噻唑或苯并咪唑，（g）水杨酸芳基酯，（h）水杨酸衍生物（i）草酰胺衍生物和（j）二烷基硫化物，条件是至少 （a）至（j）中的两个不同的基团均聚合到聚合物上。 聚合物稳定剂通过伯氨基或肼取代的稳定剂与聚合物或共聚物的一些或全部酸酐基团的反应来制备。 即使在高温下，它们也不会通过挥发，迁移或萃取而从聚合物中流失，并可用作浓缩物以稳定其它聚合物。

公开(公告)号：EP0303283A2

公开(公告)日：1989-02-15

申请号：EP88113138.7

申请日：1988-08-12

Applicant: ATOCHEM NORTH AMERICA, INC.

Inventor： Myers, Terry Ned

IPC: C07C243/24 ,  C07C241/00 ,  C07C311/49 ,  C07C251/74 ,  C07C251/86 ,  C07C249/16 ,  C07C281/06 ,  C08K5/16 ,  C08K5/24

CPC classification number: C07D209/48 ,  C07C243/00 ,  C07C243/34 ,  C07C243/38 ,  C07C251/72 ,  C07D209/76 ,  C07D211/74 ,  C07D217/24 ,  C07D221/14 ,  C07D265/33 ,  C07D279/12 ,  C08K5/25

Abstract: This invention relates to a compound having the formula:
wherein
R¹, R², R³ and R⁴ are, e.g., alkyl of 1 to 10 carbons or hydroxy,
X is, e.g., -O- or -S-,
R⁵ is, e.g., alkylene of 1 to 10 carbons or alkenylene of 2 to 10 carbons,
Y is, e.g., -C(=O)- or -S(=O)₂-,
R⁶ is, e.g., hydrogen or alkyl of 1 to 10 carbons,

R¹² is, e.g., alkylene of 2 to 5 carbons or alkenylene of 2 to 3 carbons and
n is 1 or 2,
which compound incorporates both o-hydroxybenzophenone and hydrazide functional groups. Such compounds are useful as ultraviolet light absorbers and heat stabilizers for plastics.

Abstract translation: 本发明涉及具有下式的化合物：其中R 1，R 2，R 3和R 4是例如1至10个碳原子的烷基或羟基，X是例如 ，-O-或-S-，R 5例如为1至10个碳的亚烷基或2至10个碳的亚烯基，Y为例如-C（= O） - 或-S（= O） 2-，R 6是例如氢或1至10个碳的烷基，CH 2 R 2是例如2至5个碳的亚烷基或2至3个碳的亚烯基，n是 1或2，该化合物包含邻羟基二苯甲酮和酰肼官能团。 这些化合物可用作塑料的紫外光吸收剂和热稳定剂。

公开(公告)号：EP0303279A2

公开(公告)日：1989-02-15

申请号：EP88113132.0

申请日：1988-08-12

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： MacLeay, Ronald Edward ,  Kazmierczak, Robert Thaddeus

IPC: C07D211/58 ,  C08K5/34

CPC classification number: C08K5/3435 ,  C07D211/58

Abstract: There are provided reactive hindered amine light stabilizers of the formula
wherein

R is e.g., hydrogen, hydroxyl or alkyl of 1 to 20 carbons;
R 1 is, hydrogen or lower alkyl of 1 to 4 carbons;
R 2 is, e.g., hydrogen or alkyl of 1 to 20 carbons;
R 3 is, e.g., a direct bond or an alkylene or branched alkylene diradical of 1 to 14 carbons; and
R 4 is, e.g., hydrogen or a primary or secondary alkyl group of 1 to 8 carbons, containing a light stabilizing group, a heat stabilizing group, and a reactive hydrazide functionality in the same molecule. The reactive stabilizers are prepared by reacting 4-amino-2,2,6,6-tetraalkylpiperidines with diesters (or mono ester acid chlorides) of dicarboxylic acids followed by hydrazinolysis of the ester group of the intermediate mono ester-amide. The compounds are useful for introducing permanent heat and light stability to coreactive polymers or copolymers.

Abstract translation: 提供式CHEM的反应性受阻胺光稳定剂，其中R为例如氢，羟基或1-20个碳的烷基; R 1是氢或1至4个碳的低级烷基; R 2是例如氢或1至20个碳的烷基; R 3是例如直接键或1至14个碳的亚烷基或支链亚烷基二碱基; 并且R 4是例如在相同分子中含有光稳定基团，热稳定基团和反应性酰肼官能团的氢或1至8个碳原子或仲烷基。 反应性稳定剂通过4-氨基-2,2,6,6-四烷基哌啶与二羧酸的二酯（或单酯酰氯）反应，然后通过中间体单酯 - 酰胺的酯基进行肼解来制备。 该化合物可用于将热稳定性和光稳定性引入聚合物或共聚物。

公开(公告)号：EP0289951A2

公开(公告)日：1988-11-09

申请号：EP88106906.6

申请日：1988-04-29

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Carroll, Glenn Thomas ,  Lindstrom, Michael Jeffrey

IPC: C01B17/02 ,  E21B37/06 ,  C07C149/12

CPC classification number: C09K8/532 ,  C01B17/02 ,  C07C321/00 ,  C07C323/00

Abstract: A composition, useful for dissolving sulfur, comprising a disulfide, polysulfide and mixtures thereof containing a catalytic amount of a mixture of a basic nitrogen-containing compound and an alcoholic or aqueous solution of an alkali hydroxide, alkoxide, or carbonate and methods for using the composition to prevent sulfur-plugging in a system, are disclosed.

Abstract translation: 用于溶解硫的组合物，其包含二硫化物，多硫化物及其混合物，其含有催化量的碱性含氮化合物和碱金属氢氧化物，醇盐或碳酸盐的醇或水溶液的混合物，以及使用 公开了防止系统中的硫塞的组合物。

公开(公告)号：EP0273090A1

公开(公告)日：1988-07-06

申请号：EP87100025.3

申请日：1987-01-02

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Kamath, Vasanth R.

IPC: C08F2/06

CPC classification number: C08F2/06

Abstract: A process is provided for the free radical polymerization of monomers derived from substituted or unsubstituted acrylic acid/methacrylic acid and esters thereof for the production of a polymer having a narrow molecular weight distribution and an average molecular weight of less than 4000. These polymers are produced by the solution polymerizing of said monomers wherein 20-40% by weight of the monomer composition is hydroxyalkyl acrylate or methacrylate in the presence of a solvent system suitable for high solids coating applications and in the presence of an initiating amount of a tertiary alkyl hydroperoxide and/or its derivatives having at least 5 carbons wherein the initiator and monomers, alone or in combination, are added continuously at a programmed rate wherein the rate of addition corresponds approximately to the rate of decomposition of said monomer and initiator. These polymers are used for high solids coating applications.

Abstract translation: 提供了用于自由基聚合衍生自取代或未取代的丙烯酸/甲基丙烯酸及其酯的单体的方法，用于生产具有窄分子量分布和小于4000的平均分子量的聚合物。制备这些聚合物 通过所述单体的溶液聚合，其中20-40重量％的单体组合物是丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯，在适用于高固体涂料应用的溶剂体系存在下和在引发量的叔烷基氢过氧化物的存在下，和 /或其衍生物具有至少5个碳，其中单独或组合的引发剂和单体以编程速率连续加入，其中加入速率大致对应于所述单体和引发剂的分解速率。 这些聚合物用于高固体涂料应用。

公开(公告)号：EP0259537A2

公开(公告)日：1988-03-16

申请号：EP87102632.4

申请日：1987-02-25

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Kamath, Vasanth R. ,  Palys, Leonard H.

IPC: C08F283/00 ,  C08F4/38 ,  C08F6/10 ,  C08G18/63

CPC classification number: C08F283/00 ,  C08F6/006 ,  C08G18/63

Abstract: An improved process is provided for preparing stable low viscosity polymer-polyols containing less than about 100 ppm residual monomers by using a monoperoxycarbonate initiator in combination with at least one initiator selected from diperoxyketals and peroxyesters, as chaser catalysts, at or near the end of the polymerization. The polymer-polyols prepared by the instant invention can be used to prepare high resiliency (load bearing) polyurethane foams.

Abstract translation: 提供了一种改进的方法，用于通过使用单过氧碳酸酯引发剂与至少一种选自二过氧缩酮和过氧酯的引发剂组合作为催化剂催化剂来制备含有少于约100ppm残留单体的稳定的低粘度聚合物 - 多元醇， 聚合。 本发明制备的聚合物 - 多元醇可用于制备高弹性（负荷）聚氨酯泡沫。

公开(公告)号：EP0247393A1

公开(公告)日：1987-12-02

申请号：EP87106494.5

申请日：1987-05-05

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Nevers, Ashley D.

IPC: C23F11/16 ,  C23F11/14 ,  C10G5/00 ,  C10L1/24 ,  C10L1/22

CPC classification number: C10L3/006 ,  F17C13/12 ,  F17C2203/0639 ,  F17C2221/035 ,  F17C2223/0153 ,  F17C2223/033 ,  F17C2227/044

Abstract: A process for preventing odor-fading of liquefied petroleum gas odorized with organosulfur compounds wherein the gas is stored in containers having new or recently cleaned interior surfaces, such surfaces having been pretreated with benzotriazole, tolyl triazole, mercapto­benzothiazole, benzothiazyl disulfide or mixtures thereof.

Abstract translation: 用于防止用有机硫化合物气化的液化石油气的气味褪色的方法，其中气体储存在具有新的或最近清洁的内表面的容器中，这些表面已用苯并三唑，甲苯基三唑，巯基苯并噻唑，苯并噻唑基二硫化物或其混合物预处理。

公开(公告)号：EP0219757A1

公开(公告)日：1987-04-29

申请号：EP86113840.2

申请日：1986-10-06

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Wijn, Jan A. ,  Kool, Pieter

IPC: C02F1/58 ,  C02F1/20

CPC classification number: C02F1/66 ,  C02F2101/32 ,  Y10S210/908 ,  Y10S210/916

Abstract: Waste water from the preparation of salts of dithiocarbamic acid is detoxified by acidifying the waste water to promote hydrolytic decomposition of organosulfur compounds, passing an inert gas through the acidified water to aid in expelling decomposition gases thereby increasing the decomposition rate, and optionally, adjusting the pH of the resulting solution toward neutral.

公开(公告)号：EP0200923A2

公开(公告)日：1986-11-12

申请号：EP86104554.0

申请日：1986-04-03

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Gardner, David Milton ,  Mc Elligott, Paul Joseph ,  Clark, Roger Thomas

IPC: C07C209/60

CPC classification number: C07C209/60

Abstract: The process for preparing aliphatic and aromatic amines by reacting an olefin with either ammonia, a primary amine, or a secondary amine at elevated temperature in the presence of an ammonium halide catalyst, preferably a catalyst-promoter combination, is disclosed herein.

Abstract translation: 本文公开了在卤化铵催化剂，优选催化剂 - 促进剂组合的存在下，在升高的温度下使烯烃与氨，伯胺或仲胺反应制备脂族和芳族胺的方法。