公开(公告)号：BRPI0416021A

公开(公告)日：2007-01-02

申请号：BRPI0416021

申请日：2004-10-28

Applicant: BASF AG

Inventor： HADERLEIN GERD ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SCHOFER HEINZ ,  SIEGEL WOLFGANG

IPC: B01J31/18 ,  C01G53/08 ,  C07F15/04 ,  C01G53/00 ,  B01J31/16

Abstract: A process is described for preparing a nickel(0)-phosphorus ligand complex containing at least one nickel(0)central atom and at least one phosphorus ligand, which comprises reducing a nickel(II) halide dried by azeotropic distillation in the presence of at least one phosphorus ligand.

公开(公告)号：DE502004001216D1

公开(公告)日：2006-09-28

申请号：DE502004001216

申请日：2004-04-15

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL PASCALE ,  BASSLER PETER

IPC: C01C3/02 ,  C01C3/04 ,  C07C253/00

Abstract: A process for dewatering hydrocyanic acid by distillation, which includes distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stabilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream including water and, optionally, the involatile stabilizer.

公开(公告)号：DE50207332D1

公开(公告)日：2006-08-03

申请号：DE50207332

申请日：2002-10-04

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL PASCALE ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J31/22 ,  C07F9/48 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07

Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF 3 and n is 1 or 2.

公开(公告)号：DE102004063381A1

公开(公告)日：2006-07-06

申请号：DE102004063381

申请日：2004-12-23

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  AECHTNER TOBIAS ,  PFAB PETER ,  DECKERT PETRA ,  SIEGEL WOLFGANG ,  BASLER PETER

IPC: C07C253/30 ,  B01J31/22 ,  B01J38/00 ,  C07C253/10 ,  C07C253/34 ,  C07C255/07

Abstract: Producing 3-pentenonitrile comprises isomerizing a 2-methyl-3-butenonitrile feed stream in the presence of a dissolved or dispersed catalyst, distilling the product stream to separate an overhead stream (2) from a catalyst-containing bottoms stream, distilling stream (2) to obtain an overhead stream enriched in (Z)-2-methyl-2-butenonitrile and a bottoms stream (5), and distilling stream (5) to produce a bottoms stream containing 3-pentenonitrile and an overhead stream containing 2-methyl-3-butenonitrile.

公开(公告)号：ZA200406664B

公开(公告)日：2006-06-28

申请号：ZA200406664

申请日：2004-08-23

Applicant: BASF AG

Inventor： MASSONNE KLEMENS ,  HALBRITTER KLAUS ,  SIEGEL WOFGANG ,  MAASE MATHIAS ,  NOE RALF ,  BARTSCH MICHAEL ,  STEGMANN VEIT ,  FLORES MIGUEL ,  BECKER MICHEAL ,  HUTTENLOCH OLIVER

IPC: B01D11/04 ,  C07B20060101 ,  C07B63/00 ,  C07C45/50 ,  C07F20060101 ,  C07F9/142 ,  C07F9/145 ,  C07F9/46 ,  C07F9/48 ,  C07F9/52 ,  C07F9/572 ,  C07F9/6503 ,  C07F9/6574 ,  C07F9/6584

公开(公告)号：DE50302903D1

公开(公告)日：2006-05-18

申请号：DE50302903

申请日：2003-07-04

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  SCHEIDEL JENS ,  LUYKEN HERMANN ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD

IPC: C01G9/04 ,  B01D3/36 ,  C07C253/34 ,  F26B5/00 ,  F26B7/00

Abstract: A process for the removal of water from a mixture comprising water and zinc chloride, which comprises adding to said mixture comprising water and zinc chloride an aprotic, polar diluent whose boiling point in the case where an azeotrope is not formed between said diluent and water under the pressure conditions of the distillation mentioned below is higher than the boiling point of water and which is in liquid form at this boiling point of water or which forms an azeotrope or heteroazeotrope with water under the pressure and temperature conditions of the distillation mentioned below, and distilling the mixture comprising water, zinc chloride and the diluent with removal of water or said azeotrope or said heteroazeotrope from this mixture, giving an anhydrous mixture comprising zinc chloride and said diluent.

公开(公告)号：DE102004049339A1

公开(公告)日：2006-04-13

申请号：DE102004049339

申请日：2004-10-08

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  AECHTNER TOBIAS ,  SCHEIDEL JENS ,  LUYKEN HERMANN ,  PFAB PETER ,  SIEGEL WOLFGANG ,  WEISKOPF VERENA

IPC: C07B63/00 ,  C07B63/04

Abstract: A process for purifying phosphorus chelate ligands by extraction, by using polar extractants.

公开(公告)号：BRPI0409290A

公开(公告)日：2006-04-11

申请号：BRPI0409290

申请日：2004-04-16

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ANGEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JEAN ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE

IPC: C07C253/30 ,  C07C255/07

Abstract: A process for isomerizing cis-2-pentenenitrile to trans-3-pentenenitrile in the presence of aluminum oxide as a catalyst, wherein the aluminum oxide has a BET surface area of at least 50 m 2 /g.

公开(公告)号：BRPI0408722A

公开(公告)日：2006-03-07

申请号：BRPI0408722

申请日：2004-03-24

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ANGEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JEAN ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J23/755 ,  B01J31/02 ,  B01J31/14 ,  B01J31/18 ,  C07C253/10 ,  C07C255/04 ,  B01J27/14 ,  B01J27/18

Abstract: A system which is suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds and comprises a) Ni(0) b) a compound which complexes Ni(0) as a ligand and contains trivalent phosphorus, c) a Lewis acid and d) a compound of the formula M Rn where M: Al or Ti R: identical or different monovalent alkoxy radicals, in which case a plurality of alkoxy radicals may be bonded together, and additionally, in the case that M=Al, R may be identical or different monovalent alkyl radicals, in which case a plurality of alkyl radicals may be bonded together or one or more alkyl radicals may be bonded to one or more of the abovementioned alkoxy radicals, n: valency of M, and processes for hydrocyanating an olefinically unsaturated compound in the presence of such a system.

公开(公告)号：BRPI0408200A

公开(公告)日：2006-02-14

申请号：BRPI0408200

申请日：2004-02-24

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  BASSLER PETER

IPC: C07C253/10 ,  C07C253/34 ,  C07C255/04

Abstract: Hydrocyanation of olefinically unsaturated nitriles in the presence of a zero-valent nickel catalyst comprises performing the reaction in the presence of a hydrocarbon that forms a catalyst-rich phase and a catalyst-lean phase. An independent claim is also included for separating adiponitrile from a mixture comprising adiponitrile and a zero-valent nickel catalyst by means of a hydrocarbon with a b. pt. of 90-140[deg]C.