公开(公告)号：MX9803864A

公开(公告)日：1998-09-30

申请号：MX9803864

申请日：1998-05-15

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  FISCHER ROLF ,  HARDER WOLFGANG

IPC: C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  B01J25/02 ,  C07C255/24

Abstract: Un proceso para la coproduccion de 6-aminocapronitrilo (ACN) y hexametilendiamina (HMD) mediante el tratamiento de adiponitrilo (ADN) con hidrogeno en presencia de un catalizador que contiene níquel a temperaturas no inferiores a la temperatura ambiente y presion parcial de hidrogeno elevada, en presencia o ausencia de solvente, el cual comprende, después que la conversion basada en ADN y/o la selectividad basada en ACN ha descendido abajo de un valor definido. (a) interrumpir el tratamiento del ADN con hidrogeno deteniendo la alimentacion de ADN y del solvente, si se utiliza, (b) tratar el catalizador de 150 a 400 degree C con hidrogeno utilizando una presion de hidrogeno dentro del rango de 0.1 a 30 MPa y un tiempo de tratamiento dentro del rango de 2 a 48 h, y (c) después continuar la hidrogenacion de ADN con el catalizador tratado de la etapa (b).

公开(公告)号：CZ9801845A3

公开(公告)日：1998-09-16

申请号：CZ184598

申请日：1997-04-04

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  FISCHER ROLF ,  HARDER WOLFGANG

IPC: B01J25/02 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

CPC classification number: C07C209/48 ,  C07C253/30 ,  Y02P20/584

公开(公告)号：CA2280889A1

公开(公告)日：1998-08-13

申请号：CA2280889

申请日：1998-01-30

Applicant: BASF AG

Inventor： VOIT GUIDO ,  REHFINGER ALWIN ,  FISCHER ROLF ,  LUYKEN HERMANN ,  BASSLER PETER

IPC: C07C209/84 ,  C07C209/86 ,  C07C211/12

Abstract: The invention relates to a method for obtaining hexamethylene diamine (I) from a mixture (II) containing (I) hexamethylene diamine, (III) hexamethylenimine, (IV) a compound selected from the group consisting of 2-aminomethyl cyclopentylamine and 1,2-diaminocyclohexane, (V) an imine, and (VI) adipodinitrile and 6-aminocaproic acid nitrile. According to said method, (a) a mixture (II) is subjected to distillation, yielding (a1) a low-boiling fraction which essentially contains (III), (a2) a medium-boiling fraction (VII) containing (I), (IV) and (V), and (a3) a high-boiling fraction containing (V) and (VI); (b) a mixture (VII) is subjected to distillation, yielding (b1) an overhead which essentially contains (IV) and (b2) a mixture (VIII) containing (I) and (V) as bottom residue; and (c) a mixture (VIII) is subjected to distillation, yielding (c1) (I) as overhead and (c2) a bottom residue which contains the essential part of (V).

公开(公告)号：SK56097A3

公开(公告)日：1998-07-08

申请号：SK56097

申请日：1995-11-03

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  AUMULLER ALEXANDER ,  TRAUTH HUBERT ,  VOIT GUIDO ,  SPERLING KARIN ,  KRAUSE ALFRED

IPC: C07D211/14 ,  C07B63/04 ,  C07C253/30 ,  C07C255/19 ,  C07C255/23 ,  C07C255/30 ,  C07C255/41 ,  C07C255/42 ,  C07D211/46 ,  C08K5/315 ,  C08K5/3435 ,  C09D7/12 ,  C09K3/00 ,  C09K15/16 ,  C09K15/20

Abstract: 2-Cyanoacrylic esters (I) of alpha , omega -bis(4-hydroxy-2,2,6,6-tetramethylpiperid-1-yl)alkanes or (cyclo)aliphatic polyols of the given formula (I) are new. R , R = the radical of an iso- or heterocyclic ring system with at least one iso- or heteroaromatic ring and ≥ 1 of R and R is not H, n = 2-10, if n = 2, X = a gp. of formula (II), m = 2-8; if n = 3-10, X = the radical of an n-hydric 3-20C (cyclo)aliphatic polyol, opt. with 1 or 2 heteroatoms in the cycloaliphatic gp. and up to 8 non-adjacent O or S atoms or -NH- or 1-4C alkylimino gps. in the aliphatic chain. Also claimed are various materials stabilised against the action of light, O2 and heat with (I).

公开(公告)号：CA2265488A1

公开(公告)日：1998-03-19

申请号：CA2265488

申请日：1997-08-21

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  LUYKEN HERMANN ,  FLICK KLEMENS ,  VOIT GUIDO ,  BASSLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention concerns a process for simultaneously preparing 6aminocapronitrile and hexamethylene diamine proceeding from a mixture which contains a phosphorated compound and substantially adipodinitrile and is obtained by reacting butadiene with hydrocyanic acid in the presence of a catalyst containing a phosphorated compound. The process is characterized in that: (1) the portion by weight of a phosphorated compound, calculated as phosphorus, in the mixture is reduced; (2) the resultant mixture is partially hydrogenated in the presence of a catalyst in order to form an alpha-, omega aminonitrile; and (3) 6-aminocapronitrile and hexamethylene diamine are separated from the mixture.

公开(公告)号：CA2265436A1

公开(公告)日：1998-03-19

申请号：CA2265436

申请日：1997-08-28

Applicant: BASF AG

Inventor： BASSLER PETER ,  RUST HARALD ,  FISCHER ROLF ,  VOIT GUIDO ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  MERGER MARTIN

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

Abstract: Process for the separation of 2-aminomethylcyclopentylamine from a mixture containing hexamethyldiamine and 2-aminomethylcyclopentylamine, characterized by the fact that the separation is carried out by means of distillation at a pressure of 1-300 mbars.

公开(公告)号：CA2260805A1

公开(公告)日：1998-01-29

申请号：CA2260805

申请日：1997-07-07

Applicant: BASF AG

Inventor： ACHHAMMER GUENTHER ,  FISCHER ROLF ,  RITZ JOSEF ,  FUCHS EBERHARD ,  VOIT GUIDO

IPC: C07C231/06 ,  C07C237/06 ,  C07C253/00 ,  C07C255/24 ,  C07D201/08 ,  C07D201/12 ,  C07D201/16 ,  C07D223/10

Abstract: The invention concerns the preparation of caprolactam by cyclizing 6aminocapronitrile in the presence of water at high temperature and optionally of a catalyst and a solvent by: a) separating from the reaction yield ("reaction yield I") of the cyclizing process caprolactam and all the components boiling higher than caprolactam ("high boilers"); b) treating the high boilers from step a) with phosphoric acid and/or polyphosphoric acid at a temperature ranging from 200 to 350 ~C, obtaining reaction yield II; and c) separating the caprolactam resulting from reaction yield II of step b) and optionally 6-aminocapronitrile from unreacted "high boilers" and the acid used.

公开(公告)号：CA2304848C

公开(公告)日：2008-07-15

申请号：CA2304848

申请日：1998-09-08

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF HARTMUTH ,  MERGER MARTIN ,  VOIT GUIDO ,  ANSMANN ANDREAS ,  FLICK KLEMENS

IPC: B01J23/78 ,  C07C253/30 ,  B01J23/745 ,  C07B61/00 ,  C07C255/24 ,  C07C255/26

Abstract: The invention relates to a method for producing aliphatic alpha, omega-amino nitriles in the presence of a catalyst composed of (a) iron or an iron based compound or a mixture thereof, (b) 0.01 to 5 wt. % in relation to (a) a promotor based on 2, 3, 4, or 5 elements selected from the group comprising aluminum, silicium, zirconium, titanium and vanadium and (c) 0 to 0.5 wt. % in relation to (a) a compound based on an alkaline metal or alkaline-earth metal. The inventive method is characterized in that the applied aliphatic alpha, omega-amino dinitrile contains 1.0 wt. ppm or more phosphor. Catalysts are obtainable through the reduction and optional successive passivation of a magnetite, whereby the catalysts have a BET surface of 3 to 10 m2/g, a total pore volume of 0.05 to 0.2 ml/g, an average pore diameter of 0.03 to 0.1 mm and a pore volume portion in the range of 0.01 to 0.1 mm of 50 to 70 %.

公开(公告)号：ES2171980T5

公开(公告)日：2006-04-16

申请号：ES97935513

申请日：1997-07-07

Applicant: BASF AG

Inventor： RITZ JOSEF ,  ACHHAMMER GUNTHER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  VOIT GUIDO

IPC: C07C231/06 ,  C07C237/06 ,  C07C253/00 ,  C07C255/24 ,  C07D201/08 ,  C07D201/12 ,  C07D201/16

Abstract: OBTENCION DE CAPROLACTAMA MEDIANTE LA CICLACION DE 6 AMINOCAPRONITRILO EN PRESENCIA DE AGUA Y A ELEVADA TEMPERATURA Y OPCIONALMENTE DE UN CATALIZADOR, ASI COMO DE UN DISOLVENTE, MEDIANTE A) SE SEPARA DEL PRODUCTO DE LA REACCION ("PRODUCTO DE LA REACCION") DE LA CICLACION DE LA CAPROLACTAMA ASI COMO TODOS LOS COMPONENTES QUE LLEGUEN POR ENCIMA DE LA CAPROLACTAMA ("COMPONENTES DE ELEVADO PUNTO DE EBULLICION"); B) LOS COMPONENTES CON ELEVADO PUNTO DE EBULLICION DE LA ETAPA A) SE TRATAN CON ACIDO FOSFORICO Y/O ACIDO POLIFOSFORICO A UNA TEMPERATURA DE 200 A 350 °C, OBTENIENDO EL PRODUCTO DE LA REACCION II; Y C) SEPARAR LA CAPROLACTAMA QUE RESULTA DEL PRODUCTO DE LA REACCION II DE LA ETAPA B); Y OPCIONALMENTE SEPARAR 6 - AMINOCAPRONITRILO DE LOS COMPUESTOS DE ELEVADO PUNTO DE EBULLICION QUE NO HAN REACCIONADO Y EL ACIDO UTILIZADO.

公开(公告)号：CA2265436C

公开(公告)日：2006-03-28

申请号：CA2265436

申请日：1997-08-28

Applicant: BASF AG

Inventor： RUST HARALD ,  MERGER MARTIN ,  BASSLER PETER ,  FISCHER ROLF ,  VOIT GUIDO ,  REHFINGER ALWIN ,  LUYKEN HERMANN

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

Abstract: Process for the separation of 2-aminomethylcyclopentylamine from a mixture containing hexamethyldiamine and 2-aminomethylcyclopentylamine, characterized by the fact that the separation is carried out by means of distillation at a pressure of 1-300 mbars.