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公开(公告)号：JPH04225054A
公开(公告)日：1992-08-14
申请号：JP40850190
申请日：1990-12-27
Applicant: TORAY INDUSTRIES
Inventor： YAMANAKA TORU , OKAMOTO MASARU , INOUE SHUNEI
IPC: C08L59/00 , C08K3/24 , C08L25/18 , C08L67/00 , C08L69/00 , C08L71/10 , C08L71/12 , C08L77/00 , C08L81/04 , C08L81/06 , C08L87/00
Abstract: PURPOSE:To obtain the subject composition, excellent in mechanical characteristics and retention stability by including a specific liquid crystal polyester, a specified polybrominated styrene, a thermoplastic resin such as a polyamide, a filler and an antimony compound in a prescribed proportion. CONSTITUTION:The objective composition is obtained by including (C) 0-200 pts.wt. filler, (D) 0.5-60 pts.wt. compound expressed by formula VII and (E) 0-30 pts.wt. antimony compound in 100 pts.wt. resin composition composed of (A) 1-99wt.% thermotropic liquid crystal polyester, composed of structural units expressed by formulas I, II, III or IV (R1 is formula V, etc.; R2 is formula VI, etc.) and having 150-280 deg.C deflection temperature under load and (B) 99-1wt.% one or more thermoplastic resins of polyamides, polyoxymethylenes, polycarbonates, polyarylene oxides, semi-aromatic polyesters, polyarylene sulfides, polysulfones, polyether sulfones, amorphous polyarylates and polyether ketones.
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公开(公告)号：JPH04202558A
公开(公告)日：1992-07-23
申请号：JP33972790
申请日：1990-11-30
Applicant: TORAY INDUSTRIES
Inventor： OKAMOTO MASARU , KITAJIMA NORIO , INOUE SHUNEI
Abstract: PURPOSE:To obtain a liquid crystal polymer resin composition having excellent heat-resistance, moldability and mechanical strength and exhibiting small mechanical anisotropy and deformation by compounding a specific amount of specific mica powder to a liquid crystalline polyester (amide). CONSTITUTION:The objective composition is produced by compounding (A) 100 pts.wt. of a liquid crystalline polyester resin and/or liquid crystalline polyester amide resin forming an anisotropic molten phase and composed of the structural units of formula I, formula II and formula IV or the structural units of formula I, formula II, formula III and formula IV [R1 is group of formula V, etc.; R2 is group of formula VI; the structural unit IV is equimolar to the structural units (II+III)] with (B) 1-200 pts.wt. (preferably 5-150 pts.wt.) of mica having a bulk density of 0.18-0.23, an average particle diameter of 10-15mum and a heating loss of
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公开(公告)号：JPH0481453A
公开(公告)日：1992-03-16
申请号：JP19653690
申请日：1990-07-25
Applicant: TORAY INDUSTRIES
Inventor： ICHIKAWA YASUNORI , OKAMOTO MASARU , KITAJIMA NORIO
Abstract: PURPOSE:To obtain the subject resin composition having excellent moldability and heat-resistance and suitable for gear by compounding a specific amount of a filler to a specific liquid crystal polyester. CONSTITUTION:The objective composition is produced by compounding (A) 100 pts.wt. of a liquid crystal polyester moldable by melt-molding and composed of the structural units of formula I, formula II, formula III and formula IV (R1 is group of formula V, formula VI, etc.; R2 is group of formula V, formula VI, formula VII, etc.) wherein the amount of I is 40-90mol% based on I+II+III and the molar ratio of II/III is 9/l to 1/9 and (B) 5-200 pts.wt. (preferably 25-100 pts.wt.) of a filler (e.g. glass fiber).
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公开(公告)号：JPH0481452A
公开(公告)日：1992-03-16
申请号：JP19653590
申请日：1990-07-25
Applicant: TORAY INDUSTRIES
Inventor： ICHIKAWA YASUNORI , OKAMOTO MASARU , KITAJIMA NORIO
Abstract: PURPOSE:To obtain the subject resin composition having excellent moldability and heat-resistance and suitable for gear for precision part by compounding a specific amount of a filler to a specific liquid crystal polyester. CONSTITUTION:The objective composition is produced by compounding (A) 100 pts.wt. of a liquid crystal polyester moldable by melt-molding and composed of the structural units of formula I, formula II, formula III and formula TV (R1 is group of formula V, etc. ; R2 is group of formula VI, etc.) wherein the amount of I+II is 75-95mol% based on I+II+III, that of III is 25-5mol% based on I+II+III and the molar ratio of I/II is 75/25 to 95/5, (B) 5-200 pts.wt. (preferably 25-100 pts. wt.) of a filler (e.g. glass fiber) and, as necessary, (C) 0.2-30 pts.wt. (preferably 0.5-20 pts.wt.) of an organic flame-retardant (organic bromine compound and/or organic phosphorus compound).
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公开(公告)号：JPH03220257A
公开(公告)日：1991-09-27
申请号：JP29859490
申请日：1990-11-02
Applicant: TORAY INDUSTRIES
Inventor： ICHIKAWA YASUNORI , INOUE SHUNEI , OKAMOTO MASARU
Abstract: PURPOSE:To prepare the title compsn. which is anisotropic and excellent in the heat resistance, moldability, and high-temp. mechanical properties by compounding a glass fiber having a specific diameter into a melt-moldable liq. crystal polyester resin comprising specific structural units. CONSTITUTION:5-200 pts.wt. glass fiber having a mean diameter of 3-9mum is compounded into 100 pts.wt. melt-moldable liq. crystal polyester resin which comprises structural units I, II, III, and IV shown by formula I, II, III, and IV, respectively (wherein R1 is a group of formula V, etc.; R2 is a group of formula VI, etc.; and X is H or Cl) in ratios of (I+II)/(I+I+III), (III)/(I+II+III), and (I)/(II) of 75-95mol%, 25-5mol%, and (75:25)-(95:5) (by mole), respectively.
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Patent Agency Ranking
公开(公告)号：JPH03182547A
公开(公告)日：1991-08-08
申请号：JP32338089
申请日：1989-12-12
Applicant: TORAY INDUSTRIES
Inventor： INOUE SHUNEI , OKAMOTO MASARU , ICHIKAWA YASUNORI
IPC: C08L67/00 , C08L67/02 , C08L67/03 , C08L101/00 , C08L101/04
Abstract: PURPOSE:To prepare the title compsn. giving a molded article excellent in the flame retardance, heat resistance, mechanical properties, and appearance by dispersing a specified amt. of a polymeric flame retardant in a liq. crystalline polyester in such a way that the dispersed retardant particle has a specified diameter. CONSTITUTION:0.2-30 pts.wt. polymeric the flame retardant (e.g. a brominated polystyrene) is dispersed in 100 pts.wt. liq. crystal polyester [e.g. a compd. of the formula wherein (k/l/m/n=75/10/15/25)], in such a way that the dispersed retardant particle has a mean diameter of 2.5mu or lower.
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公开(公告)号：JPH03153279A
公开(公告)日：1991-07-01
申请号：JP29293489
申请日：1989-11-10
Applicant: TORAY INDUSTRIES
Inventor： YAMANAKA TORU , INOUE SHUNEI , OKAMOTO MASARU
IPC: G03G15/14
Abstract: PURPOSE:To improve the heat resistance, the toughness of the knife edge, and the adhesive strength to fluororesin paint by using fusion-moldable liquid crystal polyester which consists of four specific structure units so that the ratio of the 1st structure unit to the sum of the 1st - 3rd structure units and the mole ratio of the 2nd and 3rd structure units are specified. CONSTITUTION:The fusion-moldable liquid crystal polyester which consists of the structure units shown by formulas I - IV so that the structure unit shown by the formula I has a 40 - 90% mole ratio to the sum of the structure units shown by the formulas I - III and the mole ratio of the structure units shown by the formulas II and III is 9/1 - 1/9. In the formula III, R1 is the group of the formula V and in the formula IV, R2 is >=2 kinds selected from the formulas VI and VII. In the formula VI, X is a hydrogen atom or chlorine atom. Consequently, the separating claw is obtained which has the superior heat resistance, low water absorptivity, superior paper discharging ability, and adhesive strength of fluororesin paint while its knife edge is hard to deform even at high temperature and high humidity.
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公开(公告)号：JPH03103462A
公开(公告)日：1991-04-30
申请号：JP21780789
申请日：1989-08-24
Applicant: TORAY INDUSTRIES
Inventor： OKAMOTO MASARU , ICHIKAWA YASUNORI , INOUE SHUNEI , YAMANAKA TORU
Abstract: PURPOSE:To obtain the title composition having excellent heat resistance, mechanical properties, appearance of molded article and flame retardance of thin molded article by blending a liquid crystal polyester having a specific structural unit with an organic bromine compound. CONSTITUTION:(A) 100 pts.wt. liquid crystal polyester comprising structural units shown by formula I, formula II, formula III and formula IV (R1 is biphenylene, phenylene, etc.; R2 is phenylene, biphenylene, etc.), molar ratio of structural units shown by formula I + formula II to structural units shown by formula I + formula II + formula III of 77-95mol%, molar ratio of structural unit shown by formula III to structural units shown by formula I + formula II + formula III of 23-5mol%, molar ratio of structural unit shown by formula I/structural unit shown by formula II of (75/25)-(95/5) is blended with (B) 0.5-30 pts.wt. organic bromine compound to give the objective composition.
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公开(公告)号：JPH0395261A
公开(公告)日：1991-04-19
申请号：JP23261289
申请日：1989-09-07
Applicant: TORAY INDUSTRIES
Inventor： YAMANAKA TORU , OKAMOTO MASARU , INOUE SHUNEI
IPC: C08K3/10 , C08G63/60 , C08K3/00 , C08K5/00 , C08K5/02 , C08L59/00 , C08L67/00 , C08L67/03 , C08L69/00 , C08L71/08 , C08L71/10 , C08L77/00 , C08L81/02
Abstract: PURPOSE:To obtain a resin composition which can form a molded product excellent in heat resistance, mechanical properties and appearance by blending a thermotropic liquid crystal polyester comprising specific structural units with a thermoplastic resin. CONSTITUTION:The title resin composition comprises 1-99wt.% thermotropic liquid crystal polyester comprising structural units of formulae I-IV and having a heat deformation temperature of 150-280 deg.C and 99-1wt.% one or more thermoplastic resins selected from the group consisting of polyamides, polyoxymethylenes, polycarbonates, polyarylene oxides, semi-aromatic polyesters, polyarylene sulfides, polysulfones, polyether sulfones, amorphous polyarylates and polyether ether ketones. In formulae I-IV, X is one or more groups selected from the group consisting of formulae V, VI, etc.; the carbonyl groups in the structural units of formulae II and III are in the para- and meta-positions relative to each other, 65mol% or more of which is in the para-position; and the amount of the structural unit of formula IV is substantially equivalent to the total amount of the structural units of formulae II and III by mole.
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公开(公告)号：JPH0347861A
公开(公告)日：1991-02-28
申请号：JP28820289
申请日：1989-11-06
Applicant: TORAY INDUSTRIES
Inventor： YAMANAKA TORU , INOUE SHUNEI , TSUNASHIMA KENJI , OKAMOTO MASARU
IPC: C08L59/00 , C08L67/00 , C08L67/03 , C08L69/00 , C08L71/10 , C08L77/00 , C08L81/00 , C08L81/02 , C08L81/06 , C08L101/00
Abstract: PURPOSE:To obtain a thermoplastic resin composition excellent in heat resistance, mechanical properties and fluidity by blending a thermotropic liquid crystal polyester having a specific heat distortion temperature with a thermoplastic resin having a specified heat distortion temperature in a specific amount. CONSTITUTION:A thermoplastic resin composition obtained by blending (A) 0.1-99wt.%, preferably 5-95wt.% thermotropic liquid polyester, having structural units composed of formulas I and II (R1 is formula III, etc.) and formula IV (R2 is formula V, etc.) or formulas I, II, VI and having
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