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公开(公告)号:DE69802974T2
公开(公告)日:2002-08-08
申请号:DE69802974
申请日:1998-02-02
Applicant: TORAY INDUSTRIES
Inventor: MAKABE YOSHIKI , KITAJIMA NORIO , INOUE TOSHIHIDE
Abstract: Disclosed are a liquid-crystalline resin composition comprising (A) from 20 to 99 parts by weight of a liquid-crystalline resin and (B) from 1 to 80 parts by weight of aluminium borate whiskers of which the grain size distribution as obtained through laser diffractometry is such that D90/D10 is from 7.5 to 20, and precision moldings of the composition.
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公开(公告)号:CA2228069A1
公开(公告)日:1998-07-31
申请号:CA2228069
申请日:1998-01-28
Applicant: TORAY INDUSTRIES
Inventor: MAKABE YOSHIKI , KITAJIMA NORIO , INOUE TOSHIHIDE
Abstract: Disclosed are a liquid-crystalline resin composition comprising (A) from 20 to 99 parts by weight of a liquid-crystalline resin and (B) from 1 to 80 parts by weight of aluminium borate whiskers of which the grain size distribution as obtained through laser diffractometry is such that D90/D10 is from 7.5 to 20, and precision moldings of the composition.
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公开(公告)号:DE69122433T2
公开(公告)日:1997-02-13
申请号:DE69122433
申请日:1991-06-21
Applicant: TORAY INDUSTRIES
Inventor: INOUE TOSHIHIDE , ICHIKAWA YASUNORI , OKAMOTO MASARU , KITAJIMA NORIO
Abstract: A flame-retardant thermotropic polyester composition comprises 100 parts by weight of thermotropic polyester (A) and 0.5 to 60 parts by weight of poly(bromostyrene) (B) having the following structural units produced from bromostyrene monomer, as the principal structural component thereof, and having a number average molecular weight of 1 x 10 to 30 x 10 ; has excellent flame retardancy, mechanical properties and heat resistance, and the shaped articles molded from the composition has also superior appearance.
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公开(公告)号:DE69122433D1
公开(公告)日:1996-11-07
申请号:DE69122433
申请日:1991-06-21
Applicant: TORAY INDUSTRIES
Inventor: INOUE TOSHIHIDE , ICHIKAWA YASUNORI , OKAMOTO MASARU , KITAJIMA NORIO
Abstract: A flame-retardant thermotropic polyester composition comprises 100 parts by weight of thermotropic polyester (A) and 0.5 to 60 parts by weight of poly(bromostyrene) (B) having the following structural units produced from bromostyrene monomer, as the principal structural component thereof, and having a number average molecular weight of 1 x 10 to 30 x 10 ; has excellent flame retardancy, mechanical properties and heat resistance, and the shaped articles molded from the composition has also superior appearance.
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公开(公告)号:CA2228069C
公开(公告)日:2006-08-01
申请号:CA2228069
申请日:1998-01-28
Applicant: TORAY INDUSTRIES
Inventor: INOUE TOSHIHIDE , MAKABE YOSHIKI , KITAJIMA NORIO
Abstract: Disclosed are a liquid-crystalline resin composition comprising (A) from 20 to 99 parts by weight of a liquid-crystalline resin and (B) from 1 to 80 parts by weight of aluminium borate whiskers of which the grain size distribution as obtained through laser diffractometry is such that D90/D10 is from 7.5 to 20, and precision moldings of the composition.
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公开(公告)号:DE69802974D1
公开(公告)日:2002-01-31
申请号:DE69802974
申请日:1998-02-02
Applicant: TORAY INDUSTRIES
Inventor: MAKABE YOSHIKI , KITAJIMA NORIO , INOUE TOSHIHIDE
Abstract: Disclosed are a liquid-crystalline resin composition comprising (A) from 20 to 99 parts by weight of a liquid-crystalline resin and (B) from 1 to 80 parts by weight of aluminium borate whiskers of which the grain size distribution as obtained through laser diffractometry is such that D90/D10 is from 7.5 to 20, and precision moldings of the composition.
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公开(公告)号:DE69427456T2
公开(公告)日:2001-09-27
申请号:DE69427456
申请日:1994-12-28
Applicant: TORAY INDUSTRIES
Inventor: NAKAMURA KIYOKAZU , KITAJIMA NORIO , INOUE TOSHIHIDE
Abstract: A liquid crystalline polymer contains (A) 100 parts by weight of a liquid crystalline polyester and/or liquid crystal polyesteramide capable of forming an anisotropic melt and (B) 0.01 to 2 parts of an olefinic polymer. The composition is especially suitable for moulding therefrom shaped articles by a moulding process in which at least two flowing molten resin portions of the composition unite to form a weld. Thus, using such a composition it is possible to produce a moulding having such a weld in which the weld has a weld strength retention of 15% to 100%, so that the shaped article has excellent heat stability, mechanical properties, dimensional stability and mold releasability and is suitable for various application uses such as in electrical and electronic devices, accurate machine devices, office related devices and automobile parts.
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公开(公告)号:DE69427456D1
公开(公告)日:2001-07-19
申请号:DE69427456
申请日:1994-12-28
Applicant: TORAY INDUSTRIES
Inventor: NAKAMURA KIYOKAZU , KITAJIMA NORIO , INOUE TOSHIHIDE
Abstract: A liquid crystalline polymer contains (A) 100 parts by weight of a liquid crystalline polyester and/or liquid crystal polyesteramide capable of forming an anisotropic melt and (B) 0.01 to 2 parts of an olefinic polymer. The composition is especially suitable for moulding therefrom shaped articles by a moulding process in which at least two flowing molten resin portions of the composition unite to form a weld. Thus, using such a composition it is possible to produce a moulding having such a weld in which the weld has a weld strength retention of 15% to 100%, so that the shaped article has excellent heat stability, mechanical properties, dimensional stability and mold releasability and is suitable for various application uses such as in electrical and electronic devices, accurate machine devices, office related devices and automobile parts.
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9.
公开(公告)号:JP2002201344A
公开(公告)日:2002-07-19
申请号:JP2001336669
申请日:2001-11-01
Applicant: TORAY INDUSTRIES
Inventor: TACHIKAWA KOJI , KITAJIMA NORIO , MAKABE YOSHIKI
Abstract: PROBLEM TO BE SOLVED: To obtain a liquid crystalline resin composition capable of suppressing discoloration or blistering of a molded product and having improved flame retardance, to provide a method for producing the liquid crystalline resin composition and to obtain the molded product. SOLUTION: This liquid crystalline resin composition comprises (B) a phosphoric acid condensate metal salt assuming alkalinity in an amount of 0.001-5 pts.wt. based on (A) 100 pts.wt. of one or more kinds of liquid crystalline resins comprising a liquid crystal polyester and/or a liquid crystal polyesteramide. The method for producing the liquid crystalline resin composition is characterized by adding (B) the phosphoric acid condensate metal salt assuming the alkalinity during polymerization of (A) one or more kinds of the liquid crystal resins comprising the liquid crystal polyester and/or liquid crystal polyesteramide.
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公开(公告)号:JPH04318058A
公开(公告)日:1992-11-09
申请号:JP8534791
申请日:1991-04-17
Applicant: TORAY INDUSTRIES
Inventor: INOUE SHUNEI , OKAMOTO MASARU , KITAJIMA NORIO
Abstract: PURPOSE:To obtain a liquid crystal polyester resin composition useful for electric and electronic parts, etc., having excellent heat resistance and hydrolysis resistance by blending a liquid crystal polyester to form an anisotropic melt phase with a phosphine compound of a specific structure. CONSTITUTION:(A) 100 pts.wt. liquid crystal polyester to form an anisotropic melt phase, preferably a liquid crystal polyester comprising structural units shown by formula I, formula II, formula III and formula IV (R1 is one or more groups selected from groups shown by formula V, formula VI, etc.; R2 is group selected from groups shown by formula VII, formula VIII, etc.) in molar ratios of formula I + formula II/formula I + formula II + formula III of 60-95mol%, formula III/formula I + formula II + formula III of 40-5mol%, molar ratio of formula I/formula III of 75/25 to 95/5 and formula VI/formula II + formula III of equimolar ratio is blended with (B) 0.001-5 pts.wt., 2,2'-methylenebis(4,6-di-t- butylphenyl)octyl phosphite shown by formula IX, preferably
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