New 4-azo- and 4-hydrazino-pyrimidine compounds

    公开(公告)号:DE19650378A1

    公开(公告)日:1998-06-10

    申请号:DE19650378

    申请日:1996-12-05

    Applicant: BASF AG

    Abstract: Pyrimidyl compounds of formula (I) are new. R = N(R4)NR5R6, N=NR6 or N(R6)NHR4; R1 = H, halo, alkyl or 3-8C cycloalkyl; R2, R3 = halo, CN, 1-8C alkyl, haloalkyl, 1-8C alkoxy, alkylthio, alkylthioalkyl, haloalkoxy, alkoxyalkyl, alkoxycarbonyl, alkoxycarbonylalkyl, 3-8C cycloalkyl or 3-8C halocycloalkyl; or CR2R3 = Z; Z = 4-8 membered ring which may contain one or two O, S, NH or N-alkyl (optionally with C atoms mono- or di-substituted by halo, CN, alkyl, alkoxyalkyl, haloalkyl, alkoxy, 1-4C haloalkoxy, alkylthio, alkoxycarbonyl, aryl or aryloxy); R4 = H, alkyl, formyl, alkylcarbonyl or alkoxycarbonyl; R5 = H, formyl, 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 1-8C alkylcarbonyl, 3-7C cycloalkyl or 5-7C cycloalkenyl (all partially or fully halogenated), aryl or heteroaryl (both optionally substituted by 1-3 NO2, halo, CN, alkyl, haloalkyl, alkoxy, haloalkoxy, 1-4C alkoxyalkyl, alkylthio, alkylamino, dialkylamino, alkylsulphonyl, alkylsulphonyloxy, alkylsulphoxy, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, aryl or aryloxy; R6 = 1-8C alkyl, 2-8C alkenyl or 2-8C alkynyl (all partially or fully halogenated and/or substituted by 1-3 CN, alkoxy, haloalkoxy, alkylthio or Cyc), or 3-7C cycloalkyl or cycloalkenyl, (both partially or fully halogenated and optionally substituted by 1-3 CN, alkoxy, haloalkoxy, alkylthio, Cyc), Z, or aryl or heteroaryl, (both optionally substituted by 1-3 halo, CN, alkyl (optionally substituted by Ar'), 1-4C alkoxyalkyl, haloalkyl, alkoxy (optionally substituted by Ar'), haloalkoxy, alkylthio, Ar', OAr', 3-7C cycloalkyl optionally substituted by 1-3 Rc), alkylamino, dialkylamino, alkylsulphonyl, alkylsulphonyloxy, haloalkylsulphonyl, alkylsulphoxy, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl or cyanoalkyl); Ar' = aryl or heteroaryl (both optionally substituted by 1-3 Rc); Cyc = 3-7C cycloalkyl, 5-7C cycloalkenyl, aryl, aryloxy or heteroaryl (all optionally substituted by 1-3 Rc); Rc = halo, CN, alkyl, 1-4C alkoxyalkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, aryl, aryloxy or heteroaryl; alkyl, alkoxy have 1-4C unless specified otherwise. The use of a compound (Ic) is also claimed.

    DERIVATIVE OF CARBAMOYLCARBOXYLIC ACID AMIDE, PROCESS OF ITS PREPARATION AND THE USE THEREOF

    公开(公告)号:CZ64097A3

    公开(公告)日:1998-02-18

    申请号:CZ64097

    申请日:1995-08-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03303 Sec. 371 Date Mar. 3, 1997 Sec. 102(e) Date Mar. 3, 1997 PCT Filed Aug. 19, 1995 PCT Pub. No. WO96/07638 PCT Pub. Date Mar. 14, 1996Carbamoylcarboxamides of the general formula I (I) and their salts (R1 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl or an unsubstituted or substituted nonaromatic carbo- or heterocycle; R2 is H or unhalogenated or halogenated alkyl or cycloalkyl; R3 is unsubstituted or substituted alkyl, cycloalkyl or phenylalkyl; R4 is H or one of the radicals R3 or R3 and R4, together with the C atom to which they are bonded, are an unsubstituted or substituted carbo- or heterocycle; R5 independently of these is one of the radicals R2; X independently of one another is hydrogen, unsubstituted or substituted alkyl and/or alkenyl; Y independently of one another and of these is one of the radicals X; p,q independently of one another are 0, 1 or 2; R6 is halogen, cyano, nitro or unsubstituted or substituted alkyl, alkoxy, alkylthio or an unsubstituted or substituted phenyl group bonded via oxygen or sulfur; r is 0, 1, 2 or 3), and compositions containing them, processes for preparation, and the use of the compounds I and the compositions are described.

    Oximethers and fungicides containing them.

    公开(公告)号:GR3023966T3

    公开(公告)日:1997-10-31

    申请号:GR970401617

    申请日:1997-07-01

    Applicant: BASF AG

    Abstract: alpha -Imino oxime cpds, described as oxime ethers, of formula (I) are new: R = CR2R3R4 or opt. substd. 3-8C cycloalkyl, 2-8C alkenyl, 2-8C alkynyl, phenyl or heteroaryl; R1 = H or 1-8C alkyl; R2 = H, 1-8C alkyl, aralkyl, heteroarylalkyl, alkoxyalkyl, aryloxyalkyl, aryl or heteroaryl; R3 = H, Me, CN, COOH or 2-9C alkoxycarbonyl; R4 = a gp. as defined for R2; or CR2R3 is a 5- to 8-membered lactone ring or CR2R4 is a 3-8C cycloalkane ring; R5 = H, 1-8C alkyl, aralkyl, 3-6C cycloalkyl, OH, 1-4C alkoxy, NH2, 1-4C alkylamino or dialkylamino; Y = a gp. stated to be an opt. substd. 1-8C alkyl, opt. substd. 2-8C alkenyl, 2-8C alkynyl, O, S(O)m (m = 0-2), N substd. by opt. substd. 1-8C alkyl, oxycarbonyl, carbonyloxy, oxycarbonyl (1-8C) alkyl, carbonyloxy (1-8C) alkyl, 2-8C oxyalkyloxy, 2-8C oxyalkenyl, 1-8C alkoxy, 1-4C oxyalkyl, 1-8C thioalkyl, azo, opt. 1-8C alkyl-substd. -carbonylamino, -aminocarbonyl or -aminocarbonyloxy, oxyimino or opt. substd. imino oxyalkyl; Z = (a) 1-18C alkyl, 2-18C alkenyl, 3-18C alkynyl, aryl, aryl (1-10C) alkyl, aryl (2-10C) alkenyl, aryloxy (1-10C) alkyl, (1-4C) alkoxy (1-10C) alkyl, 1-10C haloalkyl, 2-5C alkoxycarbonyl or heteroaryl; (b) aryloxy, aryloxy (1-10C) alkoxy, aryl (1-10C) alkoxy, 1-10C alkoxy or heteroaryloxy when Y is not oxyalkyl, oxyalkyloxy, thialkyl (sic), -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy, O or S; or (c) 1-18C alkylthio or arylthio when Y is not oxyalkyl, oxyalkyloxy, -O-N=C- (sic), -N=N-, oxycarbonyl, oxycarbonyloxy or O, and Z is opt. substd. by halogen, CN, NO2, 1-4C alkyl, 2-4C alkenyl, 1-4C alkoxy, 1-4C haloalkyl, (1-4C) alkoxy (1-4C) alkyl, di(1-4C) alkoxy (1-4C) alkyl, opt. substd. 1-10C alkoxyimino, opt. substd. 2-10C alkenyloxyimino, opt. substd. aralkoxyimino, opt. substd. 2-10C alkanoyl, opt. substd. formyl, 2-4C haloalkenyl, 2-5C alkoxycarbonyl, opt. substd. phenyl, or opt. substd. 5-membered heterocyclyl which contains 1-4 heteroatoms (N, O and/or S) and is opt. fused with an opt. substd. aromatic or heteroaromatic ring; X = H, halogen, NO2 and/or opt. substd. 1-4C alkyl, 1-4C alkoxy and/or 1-4C haloalkyl; m = 1-4.

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