公开(公告)号：TR9801153T2

公开(公告)日：1998-10-21

申请号：TR9801153

申请日：1996-12-11

Applicant: BASF AG

Inventor： ACHHAMMER GUNTHER ,  BASSLER PETER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  LUYKEN HERMANN ,  SCHNURR WERNER ,  VOIT GUIDO ,  HILPRECHT LUTZ

IPC: C07C209/48 ,  C07C209/86 ,  C07C211/12 ,  C07D201/08

CPC classification number: C07D201/08 ,  C07C209/48 ,  Y02P20/52

公开(公告)号：TR199801153T2

公开(公告)日：1998-10-21

申请号：TR9801153

申请日：1996-12-11

Applicant: BASF AG

Inventor： ACHHAMMER GUNTHER ,  BASSLER PETER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  LUYKEN HERMANN ,  SCHNURR WERNER ,  VOIT GUIDO ,  HILPRECHT LUTZ

IPC: C07C209/48 ,  C07C209/86 ,  C07C211/12 ,  C07D201/08

Abstract: PCT No. PCT/EP96/05521 Sec. 371 Date Jun. 16, 1998 Sec. 102(e) Date Jun. 16, 1998 PCT Filed Dec. 11, 1996 PCT Pub. No. WO97/23454 PCT Pub. Date Jul. 3, 1997Caprolactam and hexamethylenediamine are prepared simultaneously starting from adiponitrile.

公开(公告)号：BG102038A

公开(公告)日：1998-08-31

申请号：BG10203897

申请日：1997-11-12

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  FISCHER ROLF

IPC: C07D201/08 ,  C07D223/12

Abstract: The method occurs by reaction between 6-aminocapronitrile andwater in the presence of a catalyst, making use of an initialmixture of 6-aminocapronitrile and tetrahydroazepine derivativewith the formulaThe reaction occurs in liquid phase in the presence ofheterogeneous catalysts. The invention also relates to a methodfor the preparation of tetrahydroazepine derivative with theabove-mentioned formula and to its use for the preparation ofcaprolactam and polycaprolactam.8 claims

公开(公告)号：AU4552297A

公开(公告)日：1998-04-02

申请号：AU4552297

申请日：1997-08-21

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  FISCHER ROLF ,  EBEL KLAUS ,  SCHNURR WERNER ,  VOIT GUIDO

IPC: B01J23/75 ,  B01J23/74 ,  B01J23/76 ,  B01J25/00 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24 ,  C07C255/25

Abstract: PCT No. PCT/EP97/04547 Sec. 371 Date Jan. 7, 1999 Sec. 102(e) Date Jan. 7, 1999 PCT Filed Aug. 21, 1997 PCT Pub. No. WO98/11058 PCT Pub. Date Mar. 19, 1998A catalyst suitable for preparing aliphatic alpha, omega-aminonitriles by partial hydrogenation of aliphatic dinitriles comprises (a) metallic cobalt, a cobalt compound or a mixture thereof, the proportion of metallic cobalt based on (a) being from 20 to 100% by weight, (b) from 10 to 70% by weight, based on (a), of metallic iron, iron oxide, a further iron compound or a mixture thereof, the proportion of iron oxide based on (b) being from 20 to 100% by weight, (c) from 0 to 1% by weight, based on (a), of a compound based on an alkali metal, an alkaline earth metal or zinc.

公开(公告)号：HUT77021A

公开(公告)日：1998-03-02

申请号：HU9702137

申请日：1995-12-16

Applicant: BASF AG

Inventor： EBEL KLAUS ,  FISCHER ROLF ,  FLICK KLEMENS ,  HARDER WOLFGANG ,  MELDER JOHANN-PETER ,  REHFINGER ALWIN ,  SCHNURR WERNER ,  WITZEL TOM

IPC: B01J23/76 ,  B01J23/889 ,  B01J23/89 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24

Abstract: Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process which comprises using a catalyst which (a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and (b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and (c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal. with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or rhodium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.

公开(公告)号：TR199701387T1

公开(公告)日：1998-02-21

申请号：TR9701387

申请日：1996-05-07

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  FISCHER ROLF

IPC: C07D201/08 ,  C07D223/12

Abstract: A process for preparing caprolactam by reacting 6-aminocapronitrile with water in the presence of catalysts comprises using a starting mixture of 6-aminocapronitrile and the tetrahydroazepine derivative of the formulaand conducting the reaction in liquid phase in the presence of a heterogeneous catalyst. Also describes a process for preparing said tetrahydroazepine derivative I and its use for preparing caprolactam and polycaprolactam.

公开(公告)号：AU4378297A

公开(公告)日：1998-02-20

申请号：AU4378297

申请日：1997-07-29

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

Abstract: A process for preparing an NH2-containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.

公开(公告)号：ID17973A

公开(公告)日：1998-02-12

申请号：ID972677

申请日：1997-07-31

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

Abstract: A process for preparing an NH2-containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.

公开(公告)号：CA2261817A1

公开(公告)日：1998-02-12

申请号：CA2261817

申请日：1997-07-23

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  FISCHER ROLF

IPC: B01J23/44 ,  B01J23/46 ,  B01J23/75 ,  C07B61/00 ,  C07C209/48 ,  C07C209/60 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention concerns a process for preparing 6-aminocapronitrile or 6aminocapronitrile-hexamethylene diamine mixtures by: a) reacting 5formylvaleronitrile with ammonia and hydrogen in the presence of hydrogenation catalysts selected from the group comprising metals or metal compounds of rhenium, copper and elements of the eight subgroups, a hydrogenation discharge product being obtained; and b) extracting from the hydrogenation discharge product 6-aminocapronitrile and optionally hexamethylene diamine, provided that the hydrogenation catalyst does not contain copper, nickel or copper and nickel as its only components.

公开(公告)号：CA2259941A1

公开(公告)日：1998-02-12

申请号：CA2259941

申请日：1997-07-23

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  PACIELLO ROCCO ,  R PER MICHAEL ,  FISCHER ROLF

IPC: C07C253/30 ,  C07C255/24

Abstract: Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst from the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6aminocapronitrile and if necessary hexamethylene diamine.