公开(公告)号：US4323381A

公开(公告)日：1982-04-06

申请号：US169638

申请日：1980-07-17

Applicant: Iwao Matsuyama ,  Kenzo Susa ,  Tsuneo Suganuma ,  Shin Satoh ,  Toshio Katsuyama ,  Hidehito Obayashi

Inventor： Iwao Matsuyama ,  Kenzo Susa ,  Tsuneo Suganuma ,  Shin Satoh ,  Toshio Katsuyama ,  Hidehito Obayashi

IPC: C03B8/02 ,  C03B37/014 ,  C03B37/016 ,  G02B6/00 ,  C03B5/16

CPC classification number: C03B37/016 ,  C03B2201/10 ,  Y10S65/901

Abstract: A process for producing a mother rod useful for the production of an optical fiber which comprises hydrolyzing a silicon alkoxide to prepare a gel of a desired shape, and drying and sintering the gel to produce a block made of a silica glass. The process has the advantages that it is well adapted for mass-production, that a glass made of a B.sub.2 O.sub.3 --SiO.sub.2 system may be produced thereby and that a glass block of arbitrary shape may be readily produced.

Abstract translation: 一种制造用于生产光纤的母棒的方法，包括水解硅醇盐以制备所需形状的凝胶，以及干燥和烧结凝胶以制备由石英玻璃制成的块。 该方法的优点是适于批量生产，因此可以生产由B2O3-SiO2体系制成的玻璃，并且可以容易地生产任意形状的玻璃块。

公开(公告)号：US4295869A

公开(公告)日：1981-10-20

申请号：US10644

申请日：1979-02-08

Applicant: Satoshi Shiraishi ,  Kunio Fujiwara ,  Shiro Kurosaki

Inventor： Satoshi Shiraishi ,  Kunio Fujiwara ,  Shiro Kurosaki

IPC: B29D11/00 ,  C03B23/207 ,  C03B37/012 ,  C03B37/014 ,  C03B37/018 ,  C03B37/027 ,  C03C13/04 ,  G02B6/02 ,  C03C25/02

CPC classification number: C03C13/045 ,  B29D11/00663 ,  C03B23/207 ,  C03B37/01211 ,  C03B37/01413 ,  C03B37/01446 ,  C03B37/01807 ,  C03B37/027 ,  G02B6/02 ,  G02B6/03611 ,  G02B6/03627 ,  C03B2201/02 ,  C03B2201/08 ,  C03B2201/10 ,  C03B2201/12 ,  C03B2203/16 ,  C03B2203/22 ,  Y10S65/16

Abstract: A process for producing an optical transmission fiber is provided which comprises feeding highly pure halides, hydrides or organic compounds of Si and B by way of carrier gas on the outer surface of a fused silica rod or a fused silica pipe, or inner surface of a fused silica pipe, oxidizing them and depositing the products to form a pure fused silica layer or a doped fused silica layer containing B.sub.2 O.sub.3, melting the pipe and the deposited layer followed by a spinning. The SiO.sub.2 layer can alternatively contain fluorine instead of B.sub.2 O.sub.3. A further SiO.sub.2 layer can be deposited thereon to improve the spinning processability and lower the index of refraction of the B.sub.2 O.sub.3 containing layer.

Abstract translation: 提供了一种制造光传输纤维的方法，其包括在熔融石英棒或熔融石英管的外表面上通过载气将高纯度卤化物，氢化物或Si和B的有机化合物进料，或 熔融石英管，氧化它们并沉积产物以形成纯熔融石英层或含有B2O3的掺杂熔融石英层，熔化管和沉积层，随后进行纺丝。 SiO 2层可以替代地含有氟代替B2O3。 可以在其上沉积另外的SiO 2层以改善纺丝加工性能并降低含B2O3的层的折射率。

公开(公告)号：US4265649A

公开(公告)日：1981-05-05

申请号：US110774

申请日：1980-01-09

Applicant: Claude Achener

Inventor： Claude Achener

IPC: C03B37/014 ,  C03B8/00 ,  C03B19/01 ,  C03B20/00 ,  C03B37/012 ,  G02B6/00 ,  C03C25/02

CPC classification number: C03B37/01291 ,  C03B19/01 ,  C03B2201/02 ,  C03B2201/10 ,  C03B2203/26

Abstract: The invention provides a method for preparing a preform for producing by drawing an optical waveguide comprising a core region and a sheath region whose refractive index varies in the radial direction, so that the index of the former is greater than those of the second. The method consists in starting from a bar of a first composition for forming the core region and in forming, by means of a plasma torch, on its surface, a deposit of a plurality of layers whose composition varies in the radial direction, is characterized in that glass powder is fed to said torch transversely to the jet of said torch; in that said bar is drawn after each layer is deposited to bring its diameter to a value close or equal to the initial diameter; and in that the chemical composition of the glass powder is changed after each layer is deposited. The preform obtained by the present method makes it possible to produce by drawing optical waveguides for applications in the field of information transmission.

Abstract translation: 本发明提供一种制备用于制造预制棒的方法，该预成型件通过拉伸包括芯区域和折射率在径向方向变化的鞘区域的光波导制造，使得前者的折射率大于第二光导体的折射率。 该方法包括从用于形成芯区域的第一组合物的棒开始，并且通过等离子体焰炬在其表面上形成其组成在径向方向上变化的多个层的沉积，其特征在于 该玻璃粉末横向于所述割炬的射流被供给到所述割炬; 因为在每层沉积之后，所述棒被拉伸以使其直径达到接近或等于初始直径的值; 并且在每层沉积后，玻璃粉末的化学成分发生变化。 通过本方法获得的预制件使得可以通过绘制用于信息传输领域的光波导来制造。

公开(公告)号：US4230744A

公开(公告)日：1980-10-28

申请号：US13281

申请日：1979-02-21

Applicant: Michael G. Blankenship

Inventor： Michael G. Blankenship

IPC: C03B37/014 ,  C03B37/018 ,  G02B5/14 ,  G02B1/10

CPC classification number: C03B37/01807 ,  C03B37/01413 ,  C03B2201/10 ,  C03B2201/31 ,  C03B2207/81 ,  C03B2207/85 ,  C03B2207/87

Abstract: A system for delivering a siliceous matrix material and selected dopants to an oxidizing reaction flame or the like. Each constituent is maintained in liquified form and transferred by means of an individually controlled metering pump to a nebulizing stage then passed to a burner or the like from which the materials are converted into appropriate soots. The soots are then applied to a starting member which is subsequently subjected to heat to fuse it into a drawing blank.

Abstract translation: 用于将硅质基体材料和所选掺杂剂输送到氧化反应火焰等的系统。 每个组分保持液化形式，并通过单独控制的计量泵转移到雾化阶段，然后传送到燃烧器等，材料从该燃烧器等转化为适当的烟灰。 然后将烟炱施加到起始构件，其随后经受加热以将其熔合成拉丝坯。

公开(公告)号：US4181403A

公开(公告)日：1980-01-01

申请号：US755588

申请日：1976-12-30

Applicant: Pedro B. Macedo ,  Robert K. Mohr ,  Prabhat K. Gupta

Inventor： Pedro B. Macedo ,  Robert K. Mohr ,  Prabhat K. Gupta

IPC: C03B37/012 ,  C03B37/014 ,  C03B37/018 ,  C03C13/04 ,  C03C23/00 ,  G02B6/02 ,  G02B6/028 ,  G02B6/036 ,  G02B5/14 ,  C03C3/04 ,  C03C25/02

CPC classification number: G02B6/03694 ,  C03B37/012 ,  C03B37/01274 ,  C03B37/01413 ,  C03B37/01807 ,  C03C13/045 ,  C03C13/046 ,  C03C23/0095 ,  G02B6/02 ,  G02B6/0281 ,  C03B2201/10 ,  C03B2201/50 ,  C03B2203/22 ,  C03B2203/224

Abstract: A glass dielectric fiber waveguide with a composition profile varying radially from the center to the surface, the composition profile causing a surface layer which is in compression, said composition profile being caused by (a) at least one dopant used substantially to create a stress profile wherein the surface is in compression, and (b) at least one dopant used substantially for the purpose of creating an index of refraction profile.

Abstract translation: 具有从中心到表面径向变化的组成轮廓的玻璃介电纤维波导，所述组成轮廓导致处于压缩的表面层，所述组成轮廓由（a）至少一种掺杂剂用于基本上产生应力分布 其中所述表面处于压缩状态，和（b）基本上为了产生折射率分布的目的而使用的至少一种掺杂剂。

公开(公告)号：US4173305A

公开(公告)日：1979-11-06

申请号：US885215

申请日：1978-03-10

Applicant: Michael G. Blankenship

Inventor： Michael G. Blankenship

IPC: C03B37/014 ,  C23C16/453 ,  B05B1/24

CPC classification number: C03B37/01413 ,  C23C16/453 ,  C03B2201/10 ,  C03B2201/31 ,  C03B2207/34 ,  C03B2207/81 ,  C03B2207/85 ,  C03B2207/87

Abstract: A system for delivering a siliceous matrix material and selected dopants to an oxidizing reaction flame or the like. Each constituent is maintained in liquified form and transferred by means of an individually controlled metering pump to a nebulizing stage then passed to a burner or the like from which the materials are converted into appropriate soots. The soots are then applied to a starting member which is subsequently subjected to heat to fuse it into a drawing blank.

Abstract translation: 用于将硅质基体材料和所选掺杂剂输送到氧化反应火焰等的系统。 每个组分保持液化形式，并通过单独控制的计量泵转移到雾化阶段，然后传送到燃烧器等，材料从该燃烧器等转化为适当的烟灰。 然后将烟炱施加到起始构件，其随后经受加热以将其熔合成拉丝坯。

公开(公告)号：US4157906A

公开(公告)日：1979-06-12

申请号：US879154

申请日：1978-02-21

Applicant: Alan C. Bailey

Inventor： Alan C. Bailey

IPC: C03B37/018 ,  C03B8/00 ,  C03B20/00 ,  C03B37/014 ,  C03B37/027 ,  G02B6/00 ,  C03B37/00

CPC classification number: C03B37/027 ,  C03B37/01446 ,  C03B37/01486 ,  C03B37/02736 ,  C03B2201/06 ,  C03B2201/10 ,  C03B2201/28 ,  C03B2201/31 ,  C03B2201/32 ,  C03B2201/34 ,  C03B2201/40 ,  C03B2201/42 ,  Y10S65/90

Abstract: A method of making glass optical waveguides by the flame hydrolysis technique. Particles of glass soot produced by flame hydrolysis are deposited on the outside surface of a mandrel to form a porous preform. The soot particles closer to the mandrel have a refractive index greater than that of the soot disposed toward the outer surface of the preform. The mandrel is removed and the resultant hollow soot preform is supported in a draw furnace through which a helium-rich gas flows. The preform is heated to a temperature sufficient to cause said soot to consolidate and simultaneously permit an optical waveguide filament to be drawn therefrom.

Abstract translation: 通过火焰水解技术制造玻璃光波导的方法。 通过火焰水解产生的玻璃烟炱颗粒沉积在心轴的外表面上以形成多孔预制件。 靠近心轴的烟灰颗粒的折射率大于朝向预成型体的外表面设置的烟灰的折射率。 将心轴移除，并将得到的空心烟炱预制件支撑在富氦气流经的拉制炉中。 将预成型件加热到足以使所述烟灰固结并同时允许从其中拉出光波导细丝的温度。

公开(公告)号：US4002512A

公开(公告)日：1977-01-11

申请号：US568215

申请日：1975-04-14

Applicant: Mahn-Jick Lim

Inventor： Mahn-Jick Lim

IPC: C03B19/14 ,  C03B37/014 ,  C03B37/018 ,  C23C16/40 ,  G02B6/132 ,  H01L21/316 ,  H01L21/18

CPC classification number: H01L21/02126 ,  C03B19/1415 ,  C03B37/01413 ,  C03B37/01807 ,  C23C16/402 ,  G02B6/132 ,  H01L21/02129 ,  H01L21/02142 ,  H01L21/02164 ,  H01L21/022 ,  H01L21/02211 ,  H01L21/02271 ,  H01L21/31608 ,  C03B2201/02 ,  C03B2201/10 ,  C03B2201/30 ,  C03B2201/31 ,  C03B2201/32 ,  C03B2201/34 ,  C03B2201/42 ,  C03B2207/36

Abstract: A method of depositing a layer comprising SiO.sub.2 on a surface of a substrate at a rate which is temperature independent is disclosed. The method includes combining dichlorosilane (SiH.sub.2 Cl.sub.2) with an oxidizing gas, such as O.sub.2, CO.sub.2, N.sub.2 O, H.sub.2 O, to form SiO.sub.2.

Abstract translation: 公开了一种以温度无关的速率在衬底的表面上沉积包含SiO 2的层的方法。 该方法包括将二氯硅烷（SiH 2 Cl 2）与氧化气体如O 2，CO 2，N 2 O，H 2 O组合以形成SiO 2。

公开(公告)号：US3938974A

公开(公告)日：1976-02-17

申请号：US462481

申请日：1974-04-22

Applicant: Pedro B. Macedo ,  Theodore A. Litovitz

Inventor： Pedro B. Macedo ,  Theodore A. Litovitz

IPC: C03B37/016 ,  C03C13/00 ,  C03C13/04 ,  C03C15/00 ,  C03C21/00 ,  C03C23/00 ,  G02B6/02 ,  G02B6/028 ,  C03C17/02 ,  G02B5/14

CPC classification number: C03B37/016 ,  C03C13/005 ,  C03C13/045 ,  C03C15/00 ,  C03C21/00 ,  C03C23/0095 ,  C03B2201/10 ,  C03B2201/30 ,  C03B2201/32 ,  C03B2201/34 ,  C03B2201/50 ,  C03B2201/54 ,  G02B6/0281

Abstract: Procedures are disclosed for producing both core-cladding optical fibers and self-focusing optical fibers from porous germinate and/or silicate glasses obtained after phase separation and removal of the soluble phase. A glass which is separable into at least two phases one of which is soluble, is heated to cause phase separation. The soluble phase is leached out removing undesired impurities. The pores are collapsed and this glass is used to produce cores and/or cladding layers, or self focusing fibers. According to one aspect of the invention, preforms of the porous glass have their interconnected pores stuffed with a dopant. In the production of core-cladding optical fibers, the dopant modifies the index of refraction of the core and/or cladding so that the index of refraction of the core is greater than that of the cladding. The control of this index of refraction can be accomplished by addition of non silicate network formers such as GeO.sub.2 to the original melt before phase separation. These network formers will stay in the insoluble phase. In producing self-focusing fibers, the dopant may be non-uniformly deposited in order to produce a radial gradient in the index of refraction, or sodium or potassium ions may be ion exchanged into the glass for a portion of a dopant containing lithium or thallium to produce such an index of refraction gradient.

Abstract translation: 公开了用于在相分离和去除可溶相之后获得的多孔发芽体和/或硅酸盐玻璃中生产芯包层光纤和自聚焦光纤的方法。 可分离成至少两相的玻璃是可溶的，被加热以引起相分离。 浸出溶出相去除不需要的杂质。 孔被折叠，并且该玻璃用于生产芯和/或包层或自聚焦纤维。 根据本发明的一个方面，多孔玻璃的预制件具有填充有掺杂剂的互连孔。 在芯包层光纤的生产中，掺杂剂改变了芯和/或包层的折射率，使得芯的折射率大于包层的折射率。 该折射率的控制可以通过在相分离之前向原始熔体中添加诸如GeO 2的非硅酸盐网络形成剂来实现。 这些网络成员将保持在不溶性阶段。 在生产自聚焦纤维时，可以不均匀地沉积掺杂剂以产生折射率的径向梯度，或者钠或钾离子可以离子交换到玻璃中，用于含有锂或铊的掺杂剂的一部分 以产生这样的折射率梯度。

公开(公告)号：US3859073A

公开(公告)日：1975-01-07

申请号：US40791873

申请日：1973-10-19

Applicant: CORNING GLASS WORKS

Inventor： SCHULTZ PETER C

IPC: C03B8/04 ,  C03B37/014 ,  C03B37/018 ,  C03C3/06 ,  C03C13/04 ,  C03C23/00 ,  C04B41/86 ,  G02B6/00 ,  C03C25/02

CPC classification number: C03B37/01433 ,  C03B2201/10 ,  C03B2201/28 ,  C03B2201/30 ,  C03B2201/31 ,  C03B2201/34 ,  C03B2201/36 ,  C03B2201/40 ,  C03B2201/42 ,  C03C3/06 ,  C03C23/0095 ,  C03C2201/34 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2203/44 ,  C03C2203/50

Abstract: A method of incorporating an additive or dopant oxide in a glass body produced by the flame hydrolysis technique. Particles of the primary glass former are produced by flame hydrolysis and deposited to form a porous body which is impregnated, in part at least, with a dopant which may be dissolved or suspended in a vehicle. The body is then thermally consolidated with the dopant dispersed therein.

Abstract translation: 通过火焰水解技术在玻璃体中掺入添加剂或掺杂剂氧化物的方法。 初级玻璃形成器的颗粒通过火焰水解产生并沉积以形成多孔体，该多孔体部分至少浸渍有可溶解或悬浮在载体中的掺杂剂。 然后将体与其中分散的掺杂剂热固化。