절삭특성이 우수한 문화재 복원용 에폭시 퍼티 조성물
    12.
    发明授权
    절삭특성이 우수한 문화재 복원용 에폭시 퍼티 조성물 有权
    环氧油灰组合物具有良好的切割性能,用于恢复文化遗产

    公开(公告)号:KR101488719B1

    公开(公告)日:2015-02-23

    申请号:KR1020130139266

    申请日:2013-11-15

    Inventor: 위광철

    Abstract: 본 발명은 도자기나 토기 등과 같이 파손되기 쉽고, 일단 파손되면 복구가 어려운 문화재의 복원을 위하여 특히 가공특성을 향상시키기 위하여 절삭특성을 향상시켜 문화재 자체에 가해지는 압력을 최소화시켜 가공의 편리성 및 유물의 안정성을 극대화할 수 있는 절삭특성이 우수한 문화재 복원용 에폭시 퍼티 조성물에 관한 것으로서, 주제부와 경화제부로 이루어지며, 상기 주제부가 메인 수지로서 에피클로로히드린을 갖는 수소화 비스페놀 에이 중합체 30 내지 60중량%, 보조 수지로서 3,4-에폭시시클로헥실메틸 3,4-에폭시시클로헥산카르복실레이트 15 내지 30중량%, 반응성 희석제로서 3-에틸-3-옥세탄메탄올 13 내지 30중량%, 말단반응제로서 프로필렌카보네이트 1 내지 3중량%, 커플링제로서 3-글리시독시프로필트리메톡시실란 1 내지 2중량%, 개시제로서 설포늄염 2 내지 4중량%를 포함하여 이루어지는 수지혼합물 및 상기 수지혼합물 100중량부를 기준하여 무기충전제로서 글래스 마이크로벌룬 30 내지 60중량부를 포함하여 이루어지고; 상기 경화제부가 주경화제로서 2,2,4(2,4,4)-트리메틸-1,6-헥산디아민으로 이루어지며, 상기 주경화제 100중량부를 기준하여 무기충전제로서 탈크와 석고의 혼합물 30 내지 50중량부를 포함하여 이루어짐을 특징으로 한다.

    Abstract translation: 本发明涉及一种环氧油灰组合物,具有优异的文化遗产切割性能,能够通过改善切割性能来最大限度地提高文物的稳定性和加工便利性,以恢复文化遗产的文化遗产,如陶器, 陶器等,容易损坏,并且在损坏时难以恢复。 环氧油灰组合物包含主要材料和硬化材料。 主要材料包括由30-60重量%的具有表氯醇作为主要树脂的氢化双酚A聚合物,15-30重量%的作为亚树脂的3,4-环氧环己基甲基3,4-环氧环己烷羧酸酯,13- 30重量%作为反应性稀释剂的3-乙基-3-氧杂环丁烷甲醇,1-3重量%作为终试剂的碳酸亚丙酯1,1-2重量%的作为偶联剂的3-缩水甘油氧基丙基三甲氧基硅烷1和2- 4重量%的锍盐作为引发剂,30-60重量份作为无机填料的玻璃微球,基于100重量份的树脂混合物。 硬化材料包括作为主要硬化材料的2,2,4(2,4,4) - 三甲基-1,6-己二胺和基于100的作为无机填料的滑石和石膏混合物30-50重量份 主要硬化材料的重量份。

    석조문화재 보존을 위한 전처리를 포함한 알콕시실란계 기능성 강화제
    14.
    发明公开
    석조문화재 보존을 위한 전처리를 포함한 알콕시실란계 기능성 강화제 有权
    基于烷基化学的功能综合体,包括对石文化遗产的预处理

    公开(公告)号:KR1020140013532A

    公开(公告)日:2014-02-05

    申请号:KR1020120080899

    申请日:2012-07-25

    CPC classification number: C04B41/4988 C04B2111/00482 C04B2111/20 C09D183/02

    Abstract: The present invention to a functional reinforcing agent for repairing stone cultural heritage which is exfoliated due to natural weathering or an artificial reason. An alkoxysilane based functional reinforcing agent including pre-treatment for preserving stone cultural heritage has a feature of comprising: an alkoxysilane based pre-treating agent which has reactor to react with epoxy group; a functional filler which has epoxy group and is applied on the upper side of the alkoxysilane based pre-treating agent; an alkoxysilane based reinforcing agent which comprises by including alkoxysilane based resin which has epoxy group. Additionally, the present invention has an effect of increasing an interaction between the stone and the functional reinforcing agent; preventing a second damage of the stone which is caused by insufficient interaction between the functional reinforcing agent and the stone and friable property of alkoxysilane based reinforcing agent by treating with the alkoxysilane based reinforcing agent after treating with alkoxysilane based pre-treating agent which has reactive group to stone to increase reinforcing effect, after mixing the functional additive which has an epoxy group which is a reactive group in the alkoxysilane which is a main component of the alkoxysilane based reinforcing agent. The present invention has an effect to of preventing a big damage of stone heritage in which a part of weathered stone is destroyed in case the reinforcing part is destroyed by using a nano cluster filler which has a reactivity and granting a high mechanical stability of the alkoxysilane based reinforcing agent thereby having a less interaction between alkoxysilane based reinforcing agent and stone. [Reference numerals] (AA) An embodiment 11 solution; (BB) A comparative example Wacker OH 100

    Abstract translation: 本发明涉及一种用于修复由于自然风化或人为原因而脱落的石材文化遗产的功能性增强剂。 包括用于保存石材文化遗产的预处理的烷氧基硅烷基官能增强剂具有以下特征:包含:具有与环氧基反应的反应器的烷氧基硅烷基预处理剂; 具有环氧基且用于烷氧基硅烷基预处理剂的上侧的功能填料; 烷氧基硅烷类增强剂,其包含含有具有环氧基的烷氧基硅烷类树脂。 此外,本发明具有增加石材与功能性增强剂之间的相互作用的效果; 通过用烷氧基硅烷类预处理剂处理后,用烷氧基硅烷类增强剂进行处理,防止由功能性增强剂与石料之间的相互作用不足造成的石头的第二次损伤和烷氧基硅烷类增强剂的脆性, 在作为烷氧基硅烷类增强剂的主要成分的烷氧基硅烷中混合具有作为反应性基团的环氧基的官能添加剂之后,增加增强效果。 本发明具有防止石材遗产受到大的破坏的作用,其中一部分风化石被破坏,在加固部分被使用具有反应性并赋予烷氧基硅烷的高机械稳定性的纳米簇填料破坏的情况下 从而具有较少的烷氧基硅烷基增强剂与石料之间的相互作用。 (附图标记)(AA)实施例11的解决方案; (BB)比较例Wacker OH 100

    금속보강재를 이용한 석조문화재의 구조보강처리방법
    16.
    发明公开
    금속보강재를 이용한 석조문화재의 구조보강처리방법 无效
    使用金属加固装置修复石文化遗产

    公开(公告)号:KR1020130081195A

    公开(公告)日:2013-07-16

    申请号:KR1020120127209

    申请日:2012-11-12

    CPC classification number: G01N33/38

    Abstract: PURPOSE: A structural reinforcement processing method for stone cultural properties, which uses a metal reinforcement material, is provided to implement standardized structural reinforcement by reflecting the damaged state of stone cultural properties according to a concentrated load, a surrounding load, the shape of a member, the installation condition of the member, and so forth based on scientific data. CONSTITUTION: A structural reinforcement processing method for stone cultural properties, which uses a metal reinforcement material, is as follows. A test body which has physicochemical properties identical with a stone cultural property is made, and the physicochemical properties are confirmed. The number, position, and length of a metal reinforcement material for a reinforcing work of the stone cultural property are selected according to the confirmed physicochemical properties. An insertion hole for the metal reinforcement material is bored horizontally on the one-forth position from the side center position and the lower part. One hundred parts by weight of an adhesive polymer such as an epoxy resin and an adhesive composition which contains 50300 parts by weight of a filler which is a mixture of one or two kinds selected from a group composed of zirconium, silicate, wollastonite, and talc which are coated in the insertion hole. The metal reinforcement material is inserted into the insertion hole; the erect posture of the metal reinforcement material is maintained; and the adhesive composition is hardened to fix the metal reinforcement material.

    Abstract translation: 目的:提供采用金属加固材料的石材文化特性的结构加固加工方法,以集中载荷,周围载荷,构件形状反映石材文化特性的破坏状态,实施标准化结构加固 ,会员的安装条件等,依据科学数据。 构成:使用金属增强材料的石材文化特性的结构加固加工方法如下。 制作具有与石材文化特性相同的物理化学性质的试验体,确认其物理化学性质。 根据确定的物理化学性质选择用于石材文化特性加固工程的金属增强材料的数量,位置和长度。 用于金属加强材料的插入孔从侧面中心位置和下部在第一位置上水平地钻孔。 100重量份粘合聚合物如环氧树脂和粘合剂组合物,其包含50300重量份作为选自锆,硅酸盐,硅灰石和滑石中的一种或两种的混合物的填料 其被涂覆在插入孔中。 金属加强材料插入插入孔中; 保持金属加固材料的直立姿态; 并且粘合剂组合物被硬化以固定金属增强材料。

    석조문화재 보존을 위한 나노 복합 에폭시 접착제
    19.
    发明公开
    석조문화재 보존을 위한 나노 복합 에폭시 접착제 无效
    用于保护石文化遗产的纳诺复合环氧粘合剂

    公开(公告)号:KR1020100137057A

    公开(公告)日:2010-12-30

    申请号:KR1020090055277

    申请日:2009-06-22

    CPC classification number: C09J11/04 C09J163/00

    Abstract: PURPOSE: A nano composite epoxy adhesive for preservation of stone cultural heritage is provided to prevent secondary damage caused by water condensation by increasing water permeability through nano pores and yellowing caused by ultraviolet rays and moisture by saturated carbon. CONSTITUTION: A nano composite epoxy adhesive for preservation of stone cultural heritage comprises: a mixture of 40~99.99wt% epoxy resin and 0.01~60wt% nano cluster filler with an epoxy group and nano pores; and a room temperature curable hardener in an equivalence ratio of 0.8~1.2. The epoxy resin is hydrogenated bisphenol A type epoxy, hydrogenated bisphenol F type epoxy, biphenol type epoxy, phenol novolac epoxy, and cresol novolac epoxy, which have two or more epoxy groups in molecule.

    Abstract translation: 目的:提供用于保护石材文化遗产的纳米复合环氧树脂粘合剂,以防止水凝结引起的二次损伤,通过增加纳米孔的透水性和紫外线和饱和碳水分引起的泛黄。 构成:用于保护石材文化遗产的纳米复合环氧树脂粘合剂包括:40〜99.99wt%环氧树脂和0.01〜60wt%具有环氧基和纳米孔的纳米簇填料的混合物; 和室温可固化固化剂,当量比为0.8〜1.2。 环氧树脂是分子中具有两个或更多个环氧基团的氢化双酚A型环氧树脂,氢化双酚F型环氧树脂,双酚型环氧树脂,酚醛清漆环氧树脂和甲酚酚醛清漆环氧树脂。

    표면처리제를 이용한 석조물의 개선된 고분자 함침처리 방법
    20.
    发明公开
    표면처리제를 이용한 석조물의 개선된 고분자 함침처리 방법 有权
    通过使用表面处理剂改进聚合物浸渍过程的改进方法

    公开(公告)号:KR1020100107590A

    公开(公告)日:2010-10-06

    申请号:KR1020090025727

    申请日:2009-03-26

    CPC classification number: C04B41/45 C09K3/18

    Abstract: PURPOSE: A polymer impregnation method for a stone structure is provided to easily remove foreign substances or residues from the stone structure when using for a preservation process, and to improve the water repellency of the stone structure. CONSTITUTION: A polymer impregnation method for a stone structure impregnating monomer to a stone cultural property by pressurizing comprises a pre-processing step of spreading a surface treating agent to the surface of the stone structure. The surface treating agent is obtained by dissolving 0.5~10wt% of fluorine water repellent including a perfluoroalkyl group with the average molecular weight of 1,000~10,000 to a polar solvent or water.

    Abstract translation: 目的:提供一种用于石材结构的聚合物浸渍方法,用于在用于保存过程时容易地从石结构中除去异物或残留物,并提高石材结构的拒水性。 构成:用于通过加压将单体浸渍到石材文化特性的石材结构的聚合物浸渍方法包括将表面处理剂铺展到石材结构的表面的预处理步骤。 将表面处理剂通过将0.5〜10重量%的包含平均分子量为1,000〜10,000的全氟烷基的氟斥水剂溶解在极性溶剂或水中而获得。

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