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公开(公告)号：KR100877296B1
公开(公告)日：2009-01-07
申请号：KR1020070141289
申请日：2007-12-31
Applicant: 제일모직주식회사
Abstract: A thermoplastic resin composition is provided to secure excellent fire retardancy and scratch resistance by using halloysite as an aluminum silicate inorganic filler. A scratch-resistant flame retardant thermoplastic resin composition comprises a base resin 100.0 parts by weight, a flame retardant 1-50 parts by weight, and halloysite 1-20 parts by weight of the chemical formula of Al2Si2O5(OH)4. The base resin is made of (A) polycarbonate-based resin 20-90 weight% and (B) methacrylate-based 10-80 weight%. The methacrylate-based resin (B) is a methylmethacrylate 50-100 weight%, and a monomer 0-50 weight% capable of being copolymerized with the methylmethacrylate. The halloysite has a diameter of 40-200 nanometer.
Abstract translation: 提供一种热塑性树脂组合物，通过使用多水高岭土作为硅酸铝无机填料来确保优异的阻燃性和耐划伤性。 耐刮擦阻燃热塑性树脂组合物包含100.0重量份的基础树脂，1-50重量份的阻燃剂和约100重量份的化学式为Al 2 Si 2 O 5（OH）4的多水高岭土。 基础树脂由（A）20-90重量％的聚碳酸酯基树脂和（B）甲基丙烯酸酯基10-80重量％制成。 甲基丙烯酸酯系树脂（B）为甲基丙烯酸甲酯50-100重量％，能够与甲基丙烯酸甲酯共聚的0-50重量％的单体。 多水高岭土的直径为40-200纳米。
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公开(公告)号：KR100877581B1
公开(公告)日：2009-01-07
申请号：KR1020070140107
申请日：2007-12-28
Applicant: 제일모직주식회사
Abstract: A scratch-resistant flame retardant thermoplastic resin composition is provided to improve the commercial availability of a methacrylate-based resin and a polycarbonate-based resin and to reduce an injection weld line. A scratch-resistant flame retardant thermoplastic resin composition comprises a base resin 100.0 parts by weight, a flame retardant 1-50 parts by weight and an aromatic vinyl resin 1-30 parts by weight containing rubber component 0-15 weight%. The base resin compises (A) a polycarbonate-based resin 40-90 parts by weight and (B) a methacrylate-based resin 10-60 parts by weight. The flame retardant is a phosphate-based flame retardant or halogen-based flame retardant.
Abstract translation: 提供耐刮擦阻燃热塑性树脂组合物，以改善甲基丙烯酸酯类树脂和聚碳酸酯类树脂的商业可用性，并减少注射焊接线。 耐刮擦阻燃热塑性树脂组合物包含100.0重量份的基础树脂，1-50重量份的阻燃剂和1-30重量份的含有0-15重量％的橡胶组分的芳族乙烯基树脂。 基础树脂（A）是40〜90重量份的聚碳酸酯系树脂，（B）10〜60重量份的甲基丙烯酸酯系树脂。 阻燃剂是磷酸酯类阻燃剂或卤素类阻燃剂。
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公开(公告)号：KR100877295B1
公开(公告)日：2009-01-07
申请号：KR1020070137600
申请日：2007-12-26
Applicant: 제일모직주식회사
Abstract: A scratch-resistant thermoplastic resin composition is provided to ensure excellent fire retardancy, transparency and scratch resistance and to increase the fluidity. A scratch-resistant thermoplastic resin composition comprises a base resin 100.0 parts by weight, a phenol resin 1-20 parts by weight and a flame retardant 1-50 parts by weight. The base resin consists of (A) polycarbonate-based resin 20-80 parts by weight and (B) methacrylate-based resin 20-80 parts by weight. The methacrylate-based resin (B) is the copolymers of the monofunctional unsaturated monomer 0-50 weight% and methylmethacrylate 50-100 weight%. The phenol resin (C) is one or their mixture selected from the group consisting of a phenol novolac resin and a phenol epoxy novolac resin.
Abstract translation: 提供耐刮擦热塑性树脂组合物以确保优异的阻燃性，透明性和耐刮擦性，并提高流动性。 耐刮擦热塑性树脂组合物包含100.0重量份的基础树脂，1-20重量份的酚醛树脂和1-50重量份的阻燃剂。 基础树脂由（A）20-80重量份的聚碳酸酯类树脂和（B）20-80重量份的甲基丙烯酸酯系树脂组成。 甲基丙烯酸酯系树脂（B）为0-50重量％的单官能不饱和单体与甲基丙烯酸甲酯50-100重量％的共聚物。 酚醛树脂（C）是选自苯酚酚醛清漆树脂和苯酚环氧酚醛树脂中的一种或它们的混合物。
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公开(公告)号：KR100832518B1
公开(公告)日：2008-05-26
申请号：KR1020060133025
申请日：2006-12-22
Applicant: 제일모직주식회사
IPC: C08F275/00 , C08L57/00
CPC classification number: C08F230/02 , C08F212/10 , C08L43/02 , C08L2201/02
Abstract: A phosphorus-based flame retardant copolymer, a method for preparing the copolymer, and a flame retardant thermoplastic composition containing the copolymer are provided to improve processability and flame retardancy and to prevent environmental pollution in case of processing or burning. A phosphorus-based flame retardant copolymer is prepared by polymerizing 100 parts by weight of a monomer comprising 60-100 wt% of an aromatic vinyl compound and 0-40 wt% of a cyanovinyl compound, and 0.01-30 parts by weight of a phosphorus-containing vinyl compound selected from the compounds represented by the formula 1 and 2 or their mixture. In the formula 1, R1 is H or a C1-C4 alkyl group; R2 and R3 are identical or different each other and are a C1-C4 alkyl group, a C6-C20 aryl group or a C6-C20 aryl group substituted with an alkyl group; n is 1-8; and m is 0 or 1. In the formula 2, R1, R2 and R3 are a phenyl group, a biphenyl group or an allylphenyl group; at least one of R1, R2 and R3 must contain a vinyl group; and n is 0 or 1.
Abstract translation: 提供磷系阻燃剂共聚物，共聚物的制备方法和含有该共聚物的阻燃热塑性组合物，以提高加工性和阻燃性，并防止加工或燃烧时的环境污染。 通过聚合100重量份的包含60-100重量％的芳族乙烯基化合物和0-40重量％的氰基乙烯基化合物的单体和0.01-30重量份的磷来制备磷基阻燃共聚物 的选自式1和2表示的化合物或其混合物的乙烯基化合物。 在式1中，R 1为H或C 1 -C 4烷基; R2和R3相同或不同，为C1-C4烷基，C6-C20芳基或被烷基取代的C6-C20芳基; n为1-8; 在式2中，R 1，R 2和R 3为苯基，联苯基或烯丙基苯基; R1，R2和R3中的至少一个必须含有乙烯基; n为0或1。
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