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1.发明公开새로운 인계 난연제, 그 제조방법 및 이를 함유하는 난연열가소성 수지 조성물 无效新型PHOPHORIC FLAME RETARDANDT，其制备方法和含有其的FLAMEPROOF热塑性树脂组合物
公开(公告)号：KR1020090073474A
公开(公告)日：2009-07-03
申请号：KR1020070141428
申请日：2007-12-31
Applicant: 제일모직주식회사
IPC: C09K21/04
Abstract: A phosphorus-based flame retardant is provided to ensure excellent fire retardancy and stability against fire and to prepare a thermoplastic resin composition with environment-friendliness and excellent fire retardancy. A phosphorus-based flame retardant has a structure represented by chemical formula 1. A method for manufacturing the phosphorus-based flame retardant comprises the steps of: adding a compound represented by chemical formula 3 to a mixture of phloroglucinol and solvent in a temperature range of 0~25°C; after completion of dropping, and increasing the reaction solution to 65~120 °C for 3~5 hours to react the reaction solution; and cooling the reaction solution to 0~20 °C and filtering and evaporating the reaction solution.
Abstract translation: 提供磷系阻燃剂以确保优异的阻燃性和耐火性，并制备具有环境友好性和优异阻燃性的热塑性树脂组合物。 磷系阻燃剂具有由化学式1表示的结构。磷系阻燃剂的制造方法包括以下步骤：将由化学式3表示的化合物加入到间苯三酚和溶剂的混合物中，温度范围为 0〜25℃; 滴加完毕后，将反应溶液加热至65〜120℃反应3〜5小时， 并将反应溶液冷却至0〜20℃，过滤并蒸发反应溶液。
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公开(公告)号：KR100524582B1
公开(公告)日：2005-10-28
申请号：KR1020030066580
申请日：2003-09-25
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 (A) (a
1 ) 고무성분 10∼68 중량부 및 고무성분을 제외한 상태에서 아크릴로니트릴 18∼50 중량%를 포함하는 스티렌-아크릴로니트릴 그라프트 공중합체 수지 5∼40 중량% 및 (a
2 ) 아크릴로니트릴 18∼50중량%를 포함하는 스티렌-아크릴로니트릴 공중합체 수지 95∼60 중량%로 이루어진 고무변성 스티렌계 수지 100 중량부, (B) 에폭시 수지 1∼30 중량부, (C) 페놀 수지 1∼20 중량부, (D) 방향족 인산에스테르 화합물 5∼30 중량부, 및 (E) 가교촉진제 0.005∼5.000 중량부로 이루어지는 것을 특징으로 한다. 본 발명에 따른 난연성 열가소성 수지 조성물은 성형되어 전기제품, 사무기기 등의 성형품에 이용될 수 있다.-
公开(公告)号：KR100508855B1
公开(公告)日：2005-08-17
申请号：KR1020020088243
申请日：2002-12-31
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 (a
1 ) 고무성분이 10 내지 68 중량부를 적용하고 고무성분을 제외하고 아크릴로니트릴 함량이 18-50 중량%인 스티렌-아크릴로니트릴 그라프트 공중합체 수지 5-40 중량% 및 (a
2 ) 아크릴로니트릴 함량이 18-50중량%인 스티렌-아크릴로니트릴 공중합체 수지 95-60 중량%로 이루어진 고무변성 스티렌계 수지 100 중량부; (B) 에폭시 수지 1-30 중량부; (C) 방향족 인산에스테르 화합물 5-30 중량부; 및 (D) 아연 화합물 0.01-20 중량부로 이루어진다.-
公开(公告)号：KR1020040061936A
公开(公告)日：2004-07-07
申请号：KR1020020088243
申请日：2002-12-31
Applicant: 제일모직주식회사
CPC classification number: C08L25/12 , C08J2300/22 , C08K3/10 , C08K5/523 , C08K2201/003 , C08L51/06 , C08L63/00 , C08L2201/02
Abstract: PURPOSE: A flame retardant thermoplastic resin composition and a molded product prepared by using the composition are provided, to improve flame retardancy with minimizing the addition of char generating materials by using a zinc compound. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a rubber modified styrene-based resin which comprises 5-40 wt% of a styrene-acrylonitrile graft copolymer resin having 10-68 parts by weight of rubber component and containing 18-50 wt% of acrylonitrile except the rubber component, and 60-95 wt% of a styrene-acrylonitrile graft copolymer resin containing 18-50 wt% of acrylonitrile; 1-30 parts by weight of an epoxy resin; 5-30 parts by weight of an aromatic phosphoric acid ester compound; and 0.01-20 parts by weight of a zinc compound. Preferably the epoxy resin is represented by the formula 1, 2 or 3, wherein n is 1-10,000. Preferably the zinc compound has a diameter of 0.01-10 micrometers and comprises ZnO, ZnSO4 and ZnCl2.
Abstract translation: 目的：提供一种阻燃热塑性树脂组合物和通过使用该组合物制备的模塑产品，以通过使用锌化合物使焦炭发生材料的添加最小化来改善阻燃性。 构成：热塑性树脂组合物包含100重量份的橡胶改性苯乙烯基树脂，其包含5-40重量％的具有10-68重量份橡胶组分并含有18-50重量％的橡胶组分的苯乙烯 - 丙烯腈接枝共聚物树脂 丙烯腈除橡胶组分外的％，和60-95重量％的含有18-50重量％丙烯腈的苯乙烯 - 丙烯腈接枝共聚物树脂; 1-30重量份环氧树脂; 5-30重量份的芳族磷酸酯化合物; 和0.01-20重量份的锌化合物。 优选地，环氧树脂由式1,2或3表示，其中n为1-10,000。 优选地，锌化合物的直径为0.01-10微米，并且包含ZnO，ZnSO 4和ZnCl 2。
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公开(公告)号：KR1020040061935A
公开(公告)日：2004-07-07
申请号：KR1020020088242
申请日：2002-12-31
Applicant: 제일모직주식회사
IPC: C08L51/04
CPC classification number: C08L51/04 , C08J2300/22 , C08K3/10 , C08K5/523 , C08K2201/003 , C08L25/12 , C08L63/00 , C08L2201/02
Abstract: PURPOSE: A flame retardant thermoplastic resin composition and a molded product prepared by using the composition are provided, to improve flame retardancy with minimizing the addition of char generating materials and using no halogen compound. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a rubber modified styrene-based resin which comprises 5-40 wt% of a styrene-acrylonitrile graft copolymer resin having 10-68 parts by weight of rubber component and containing 18-50 wt% of acrylonitrile except the rubber component, and 60-95 wt% of a styrene-acrylonitrile graft copolymer resin containing 18-50 wt% of acrylonitrile; 1-30 parts by weight of an epoxy resin; 5-30 parts by weight of an aromatic phosphoric acid ester compound; and 0.01-20 parts by weight of a copper compound. Preferably the epoxy resin is represented by the formula 1, 2 or 3, wherein n is 1-10,000. Preferably the copper compound has a diameter of 0.01-10 micrometers and comprises CuO, Cu2O, CuS, Cu2S and CuCl2.
Abstract translation: 目的：提供阻燃热塑性树脂组合物和通过使用该组合物制备的模塑产品，以最大限度地减少焦炭生成材料的添加和不使用卤素化合物来改善阻燃性。 构成：热塑性树脂组合物包含100重量份的橡胶改性苯乙烯基树脂，其包含5-40重量％的具有10-68重量份橡胶组分并含有18-50重量％的橡胶组分的苯乙烯 - 丙烯腈接枝共聚物树脂 丙烯腈除橡胶组分外的％，和60-95重量％的含有18-50重量％丙烯腈的苯乙烯 - 丙烯腈接枝共聚物树脂; 1-30重量份环氧树脂; 5-30重量份的芳族磷酸酯化合物; 和0.01-20重量份的铜化合物。 优选地，环氧树脂由式1,2或3表示，其中n为1-10,000。 优选铜化合物的直径为0.01-10微米，并包含CuO，Cu2O，CuS，Cu2S和CuCl2。
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Patent Agency Ranking
公开(公告)号：KR101411008B1
公开(公告)日：2014-06-23
申请号：KR1020110028418
申请日：2011-03-29
Applicant: 제일모직주식회사
Abstract: 본 발명은 하기 화학식 1로 표시되는 인계 화합물을 제공한다:
[화학식 1]
(상기 식에서, R은 수소, C
1 -C
6 의 알킬기, C
6 -C
12 의 아릴기임).-
公开(公告)号：KR1020050030649A
公开(公告)日：2005-03-31
申请号：KR1020030066580
申请日：2003-09-25
Applicant: 제일모직주식회사
Abstract: Provided are a flame retardant thermoplastic resin composition which is reduced in the addition of char generating materials and is excellent in flame retardancy, heat resistance, and a molded product prepared from the composition. The thermoplastic resin composition comprises 100 parts by weight of a rubber modified styrene-based resin which comprises 10-68 parts by weight of a rubber component, and 5-40 wt% of a styrene-acrylonitrile graft copolymer resin containing 18-50 wt% of acrylonitrile and 60-95 wt% of a styrene-acrylonitrile copolymer resin containing 18-50 wt% of acrylonitrile except a rubber component; 1-30 parts by weight of an epoxy resin; 1-20 parts by weight of a phenol resin; 5-30 parts by weight of an aromatic phosphate compound; and 0.005-5.000 parts by weight of a crosslinking accelerator.
Abstract translation: 提供一种阻燃热塑性树脂组合物，其在添加炭发生材料时减少，并且具有优异的阻燃性，耐热性和由该组合物制备的模塑产品。 热塑性树脂组合物包含100重量份的橡胶改性苯乙烯基树脂，其包含10-68重量份的橡胶组分和5-40重量％的含有18-50重量％的苯乙烯 - 丙烯腈接枝共聚物树脂， 的丙烯腈和60-95重量％的含有18-50重量％丙烯腈的苯乙烯 - 丙烯腈共聚物树脂，除了橡胶组分; 1-30重量份环氧树脂; 1-20份（重量）酚醛树脂; 5-30重量份的芳族磷酸酯化合物; 和交联促进剂0.005-5.000重量份。
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公开(公告)号：KR100437535B1
公开(公告)日：2004-06-30
申请号：KR1020010060437
申请日：2001-09-28
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic flame retardant resin composition and a molded product processed from the composition are provided, to improve the flame retardancy by employing the polyfunctional epoxy resin generating a large amount of char in combustion. CONSTITUTION: The resin composition comprises 100 parts by weight of a styrene-based resin as a base resin; 0.1-100 parts by weight of a polyfunctional epoxy resin represented by the formula 1, wherein n is an integer of 1-100; and 0.1-50 parts by weight of a phosphorus-based flame retardant. Preferably the phosphorus-based flame retardant is at least one selected from the group consisting of a phosphate ester-based compound, an oxaphosphorane-based compound, a carboxy phosphinic acid compound, a phosphate ester morpholide compound, a phosphazene compound and a phosphoramidate compound.
Abstract translation: 目的：提供一种热塑性阻燃树脂组合物和由该组合物加工的模塑产品，以通过使用在燃烧中产生大量焦炭的多官能环氧树脂来提高阻燃性。 构成：树脂组合物包含100重量份作为基础树脂的苯乙烯基树脂; 0.1-100重量份的由式1表示的多官能环氧树脂，其中n是1-100的整数; 和0.1-50重量份的磷基阻燃剂。 磷系阻燃剂优选为选自磷酸酯系化合物，氧杂磷杂环戊烷系化合物，羧基次膦酸化合物，磷酸酯吗啉化合物，磷腈化合物，氨基磷酸酯化合物中的至少一种。
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公开(公告)号：KR100832518B1
公开(公告)日：2008-05-26
申请号：KR1020060133025
申请日：2006-12-22
Applicant: 제일모직주식회사
IPC: C08F275/00 , C08L57/00
CPC classification number: C08F230/02 , C08F212/10 , C08L43/02 , C08L2201/02
Abstract: A phosphorus-based flame retardant copolymer, a method for preparing the copolymer, and a flame retardant thermoplastic composition containing the copolymer are provided to improve processability and flame retardancy and to prevent environmental pollution in case of processing or burning. A phosphorus-based flame retardant copolymer is prepared by polymerizing 100 parts by weight of a monomer comprising 60-100 wt% of an aromatic vinyl compound and 0-40 wt% of a cyanovinyl compound, and 0.01-30 parts by weight of a phosphorus-containing vinyl compound selected from the compounds represented by the formula 1 and 2 or their mixture. In the formula 1, R1 is H or a C1-C4 alkyl group; R2 and R3 are identical or different each other and are a C1-C4 alkyl group, a C6-C20 aryl group or a C6-C20 aryl group substituted with an alkyl group; n is 1-8; and m is 0 or 1. In the formula 2, R1, R2 and R3 are a phenyl group, a biphenyl group or an allylphenyl group; at least one of R1, R2 and R3 must contain a vinyl group; and n is 0 or 1.
Abstract translation: 提供磷系阻燃剂共聚物，共聚物的制备方法和含有该共聚物的阻燃热塑性组合物，以提高加工性和阻燃性，并防止加工或燃烧时的环境污染。 通过聚合100重量份的包含60-100重量％的芳族乙烯基化合物和0-40重量％的氰基乙烯基化合物的单体和0.01-30重量份的磷来制备磷基阻燃共聚物 的选自式1和2表示的化合物或其混合物的乙烯基化合物。 在式1中，R 1为H或C 1 -C 4烷基; R2和R3相同或不同，为C1-C4烷基，C6-C20芳基或被烷基取代的C6-C20芳基; n为1-8; 在式2中，R 1，R 2和R 3为苯基，联苯基或烯丙基苯基; R1，R2和R3中的至少一个必须含有乙烯基; n为0或1。
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公开(公告)号：KR100654525B1
公开(公告)日：2006-12-05
申请号：KR1020050134991
申请日：2005-12-30
Applicant: 제일모직주식회사
IPC: C07F9/32
Abstract: A salt of carboxyethyl phosphinate ester is provided to show excellent flame retardant property, improved heat-stability and moisture absorbing property by esterifying carboxy phosphinic acid and then preparing a salt compound thereof. The salt of carboxyethyl phosphinate ester is represented by the formula(I), where R1 is C1-6 alkyl, C6-12 aryl or alkyl substituted C6-12 aryl, R2 is C1-6 alkyl, C6-12 aryl or alkyl substituted C6-12 aryl, n is an integer from 1 to 3, and M is a metal selected from the group consisting of Al, Zn, Ca, Ba and Mg or an amine-based compound selected from the group consisting of ammonium, melamine and melum. The flame retardant thermoplastic resin composition comprises a thermoplastic resin and 0.1-50 parts by weight of the salt of carboxyethyl phosphinate ester regarding 100 parts by weight of the thermoplastic resin.
Abstract translation: 提供羧乙基次膦酸酯的盐以通过酯化羧基次膦酸然后制备它们的盐化合物显示优异的阻燃性，改善的热稳定性和吸湿性。 羧乙基次膦酸酯的盐由式（I）表示，其中R 1为C 1-6烷基，C 6-12芳基或烷基取代的C 6-12芳基，R 2为C 1-6烷基，C 6-12芳基或烷基取代的C 6 -12芳基，n是1至3的整数，M是选自Al，Zn，Ca，Ba和Mg的金属或选自铵，三聚氰胺和甜菜碱的基于胺的化合物 。 阻燃热塑性树脂组合物包含热塑性树脂和相对于100重量份热塑性树脂0.1重量份〜50重量份的羧乙基次膦酸酯的盐。
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