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公开(公告)号：KR100480329B1
公开(公告)日：2005-04-06
申请号：KR1020010086261
申请日：2001-12-27
Applicant: 제일모직주식회사
IPC: C08J3/12
Abstract: 본 발명의 단분산성 고분자 입자는 단량체, 다관능성 가교 단량체, 지용성 개시제, 혼합조성의 연속상 용제, 분산안정제 및 보조 분산안정제를 첨가하여 50-90 ℃의 온도범위에서 5-50 시간 동안 분산중합하여 제조되고, 상기 다관능성 가교 단량체는 단량체 전체 중량에 대하여 최소 10 중량%이상 투입되며, 상기 혼합조성의 연속상 용제는 알코올과 에테르알코올의 혼합물 또는 알코올과 벤젠계 용제와의 혼합물인 것을 특징으로 한다.
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公开(公告)号：KR100459323B1
公开(公告)日：2004-12-03
申请号：KR1020020048795
申请日：2002-08-19
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition using microparticle is provided, to lower the gloss with suppressing the deterioration of the mechanical properties. CONSTITUTION: The thermoplastic resin composition comprises 10-50 parts by weight of the graft copolymer resin prepared by copolymerizing 10-30 parts by weight of a cyano vinyl compound and 70-90 parts by weight of an aromatic vinyl compound to 30-60 parts by weight of a rubbery polymer; 40-80 parts by weight of the copolymer consisting of 20-40 wt% of a cyano vinyl compound and 60-80 wt% of an aromatic vinyl compound; and 1-50 parts by weight of a crosslinkable organic microparticle. Preferably the crosslinkable organic microparticle is prepared by dispersing a polymer organic dispersant aqueous solution and a solution containing a crosslinkable monomer, an initiator and a polymerizable monomer to a drop of 0.1-3.0 micrometers and polymerizing it at a temperature of 50-80 deg.C, and has a particle size of 1-20 micrometers.
Abstract translation: 目的：提供一种使用微粒的热塑性树脂组合物，以抑制机械性能的劣化而降低光泽度。 构成：热塑性树脂组合物含有10〜50重量份的接枝共聚物树脂，该树脂通过将10〜30重量份的氰基乙烯基化合物和70〜90重量份的芳香族乙烯基化合物共聚合30〜60重量份 橡胶状聚合物的重量; 40-80重量份由20-40重量％氰基乙烯基化合物和60-80重量％芳族乙烯基化合物组成的共聚物; 和1-50重量份的可交联有机微粒。 优选地，可交联有机微粒通过将聚合物有机分散剂水溶液和含有可交联单体，引发剂和可聚合单体的溶液分散至0.1-3.0微米的液滴并在50-80℃的温度下聚合而制备 并具有1-20微米的粒度。
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公开(公告)号：KR1020040016624A
公开(公告)日：2004-02-25
申请号：KR1020020048887
申请日：2002-08-19
Applicant: 제일모직주식회사
IPC: C08J3/02
Abstract: PURPOSE: A method for preparing a monodisperse functional particle is provided, to obtain a polymer composite particle having various particle structures by controlling the morphology of monodisperse polymer particles. CONSTITUTION: The method comprises the steps of dissolving a monomer, an oil-soluble and a stabilizer in an alcohol and dispersion polymerizing it to prepare a seed particle; re-dispersing the seed particle in the aqueous phase where an emulsifier is dissolved, introducing a swelling agent into the seed dispersed one to swell it, and introducing the monomer where an initiator is dissolved into the seed dispersed one to swell it; and stabilizing the swollen polymer particle by using a dispersion stabilizer and polymerizing the stabilized one. Preferably a crosslinking agent is added in the first step, and the crosslinking agent is a polydimethylsiloxane-based one represented by the formula 1 or 2 (wherein R' is H or CH3 and n is an integer of 5-600); vinyl-terminated or acrylate-terminated polyoxyethylene glycol-based one, polyoxypropylene glycol-based one, or polytetramethylene glycol-based one having a molecular weight of about 500-10,000; or a reactive crosslinking agent selected from epoxy acrylate and urethane acrylate.
Abstract translation: 目的：提供制备单分散功能性颗粒的方法，通过控制单分散聚合物颗粒的形态来获得具有各种颗粒结构的聚合物复合颗粒。 方法：该方法包括将单体，油溶性和稳定剂溶解在醇中并使其分散聚合以制备种子颗粒的步骤; 将种子颗粒重新分散在溶解有乳化剂的水相中，将溶胀剂引入分散的种子中以使其膨胀，并将引发剂溶解的单体引入分散的种子中以使其膨胀; 并通过使用分散稳定剂稳定溶胀的聚合物颗粒并使其稳定化。 优选在第一步中加入交联剂，交联剂是由式1或2表示的聚二甲基硅氧烷基（其中R'为H或CH 3且n为5-600的整数）; 乙烯基封端或丙烯酸酯封端的聚氧乙烯二醇基，聚氧丙烯二醇基或聚四亚甲基二醇基的分子量约为500-10,000; 或选自环氧丙烯酸酯和氨基甲酸酯丙烯酸酯的活性交联剂。
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公开(公告)号：KR100399817B1
公开(公告)日：2003-09-29
申请号：KR1020000077857
申请日：2000-12-18
Applicant: 제일모직주식회사
Inventor： 정필문
IPC: B01J13/14
Abstract: PURPOSE: An encapsulation method of inorganic particles with organic polymer material is provided, in which anionic emulsifier is used in case that the surface of inorganic particles are charged to positive, and vice versa. CONSTITUTION: The encapsulation method comprises: dissolving completely 0.05-5 wt.% of anionic emulsifier or 2-10 wt.% of cationic emulsifier into the water with controlled hydrogen concentration, keeping the concentration of the emulsifier under critical micelle concentration; absorbing the emulsifier on the surface of 50-1,000 wt.% of the inorganic particles in a reactor by stirring for 0.5-3 hours; and adding 100 wt.% of the vinyl monomers such as styrene or acrylate, raising the temperature up to 70°C and adding 0.3-1.5 wt.% of reaction initiator to emulsion polymerize for encapsulation and to obtain 95% of yield.
Abstract translation: 目的：提供一种无机颗粒与有机聚合物材料的封装方法，其中在无机颗粒表面带正电的情况下使用阴离子乳化剂，反之亦然。 本发明的包封方法包括：将0.05-5重量％的阴离子乳化剂或2-10重量％的阳离子乳化剂完全溶解于控制氢浓度的水中，保持乳化剂浓度在临界胶束浓度以下; 通过搅拌反应0.5-3小时，在反应器中将50-1000重量％无机颗粒表面的乳化剂吸收; 并加入100重量％的乙烯基单体如苯乙烯或丙烯酸酯，将温度升高至70℃并加入0.3-1.5重量％的反应引发剂进行乳液聚合以包封并获得95％的收率。
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Patent Agency Ranking
公开(公告)号：KR100546797B1
公开(公告)日：2006-01-25
申请号：KR1020020081543
申请日：2002-12-20
Applicant: 제일모직주식회사
IPC: C08J3/12
Abstract: 본 발명의 단분산성 고분자 입자의 제조방법은 (1) 소수성 활성화 단량체, 1차 단량체, 유용성 개시제 및 안정제를 알콜상에서 녹인 후 분산중합하여 분말상태의 소수성 시드(seed) 입자를 제조하는 제1단계; (2) 상기 제1단계에서 제조된 소수성 시드 입자를 0.1∼0.5%의 유화제가 용해된 수상에 초음파를 이용하여 재분산시키는 제2단계; (3) 상기 소수성 시드 분산체에 유용성 개시제가 녹아있는 2차 단량체를 도입하여 팽윤시키는 제3단계; 및 (4) 상기 팽윤된 고분자 분산체를 분산 안정제를 이용하여 안정화시키고 중합시키는 제4단계로 이루어진다.
단분산성 고분자 입자, 소수성 활성화 단량체, 시드(seed) 입자, 팽윤 공정, 단량체 팽윤법-
公开(公告)号：KR100527298B1
公开(公告)日：2005-11-09
申请号：KR1020020047684
申请日：2002-08-13
Applicant: 제일모직주식회사
IPC: C08F220/06
Abstract: 본 발명의 응집현상이 감소된 아크릴계 수지의 제조방법은 80-100 중량%의 메틸 메타크릴레이트 및 0-20 중량%의 비닐계 모노머로 이루어진 단량체 혼합물, 개시제 및 분산안정제의 존재 하에 연쇄이동제로서 하기 화학식 1로 표시되는 알킬 3-머켑토프로피오네이트 및 n-도데실머캅탄이 조합된 혼합물을 사용하는 것을 특징으로 한다.
[화학식 1]
(상기 식에서, R은 4 내지 18개의 탄소원자를 갖는 알킬기임).-
公开(公告)号：KR1020050066232A
公开(公告)日：2005-06-30
申请号：KR1020030097491
申请日：2003-12-26
Applicant: 제일모직주식회사
IPC: C08G75/06
Abstract: 본 발명에 따른 전기전도성 폴리티오펜은 카르복시기를 가진 티오펜 단량체를 암모늄 퍼클로레이트 전해질의 존재 하에 전해중합법에 의해 제조한 카르복시기를 가진 폴리티오펜 또는 아민기를 가진 티오펜 단량체를 암모늄 퍼클로레이트 전해질의 존재 하에서 전해중합법에 의해 제조한 아민기를 가진 폴리티오펜을 특징으로 한다. 또한, 본 발명은 전기전도성 폴리티오펜을 이용하여 자기 조립에 의해 형성된 다층 구조체를 특징으로 한다.
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公开(公告)号：KR1020040016623A
公开(公告)日：2004-02-25
申请号：KR1020020048886
申请日：2002-08-19
Applicant: 제일모직주식회사
IPC: C08J3/16
Abstract: PURPOSE: A method for preparing a surface-functionalized monodisperse polymer particle and a surface-functionalized monodisperse polymer particle prepared by the method are provided, to obtain the monodisperse polymer particle which is very stable to the chemical environment and has a uniform shell thickness. CONSTITUTION: The method comprises the steps of dispersing a seed particle(1) having a size of 1-500.0 micrometers in the aqueous phase where an emulsifier is dissolved by an amount of 0.1-0.5 %; dissolving a monomer, an initiator and a crosslinking agent used for functionalizing surface in a hydrocarbon-based solvent, and stirring the solution in the aqueous phase where a dispersion stabilizer is dissolved to prepare a dispersion(2); mixing the obtained dispersion solution(2) with the first dispersion solution with stirring to prepare a mixture dispersion; polymerizing the mixture dispersion to deposit a polymer(3) on the surface of a seed particle(1); and removing a hydrocarbon from the polymerized particle.
Abstract translation: 目的：提供一种通过该方法制备表面官能化单分散聚合物颗粒和表面官能化单分散聚合物颗粒的方法，以获得对化学环境非常稳定并具有均匀壳厚度的单分散聚合物颗粒。 方法：该方法包括将具有1-500.0微米尺寸的种子颗粒（1）分散在乳化剂溶解0.1-0.5％的水相中的步骤; 将用于官能化表面的单体，引发剂和交联剂溶解在烃类溶剂中，并搅拌溶解有分散稳定剂的水相中的溶液以制备分散体（2）; 在搅拌下将得到的分散液（2）与第一分散液混合，制备混合物分散体; 聚合混合物分散体以在种子颗粒（1）的表面上沉积聚合物（3）; 并从聚合的颗粒中除去烃。
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公开(公告)号：KR1020030053087A
公开(公告)日：2003-06-28
申请号：KR1020010083123
申请日：2001-12-22
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08J2300/22 , C08K5/37 , C08L25/12 , C08L2205/03
Abstract: PURPOSE: A styrene-based thermoplastic resin composition is provided, which exhibits excellent vacuum moldability and improved elongation and fluidity by employing a superhigh molecular weight SAN copolymer having a nonlinear structure. CONSTITUTION: The thermoplastic resin composition comprises 20-50 wt% of a graft copolymer which is prepared by graft polymerizing 30-70 wt% of a mixture of an aromatic vinyl-based monomer and a cyanovinyl-based monomer to 30-70 wt% of a butadiene-based rubber, and has an average weight molecular weight of 50,000-100,000; 40-70 wt% of a styrene-acrylonitrile copolymer which is prepared by copolymerizing 50-90 wt% of an aromatic vinyl-based monomer and 10-50 wt% of a cyanovinyl-based monomer, and has an average weight molecular weight of 100,000-300,000; and 0.1-30 wt% of a copolymer which is prepared by adding 0.01-5 parts by weight of a multifunctional mercaptan and 0.005-5 parts by weight of a multifunctional acryl-based monomer to 100 parts by weight of a monomer mixture comprising 50-90 wt% of an aromatic vinyl-based monomer and 10-50 wt% of a cyanovinyl-based monomer, and has a superhigh molecular weight and a nonlinear structure.
Abstract translation: 目的：提供一种苯乙烯类热塑性树脂组合物，其通过使用具有非线性结构的超高分子量SAN共聚物显示出优异的真空成型性和改善的伸长率和流动性。 构成：热塑性树脂组合物包含20-50重量％的接枝共聚物，其通过将30-70重量％的芳族乙烯基类单体和氰基乙烯基类单体的混合物接枝聚合到30-70重量％ 丁二烯类橡胶，平均重量分子量为50,000-100,000; 40-70重量％的苯乙烯 - 丙烯腈共聚物，其通过共聚50-90重量％的芳族乙烯基类单体和10-50重量％的氰基乙烯基类单体制备，平均重量分子量为100,000 300,000; 和0.1-30重量％的共聚物，其通过将0.01-5重量份的多官能硫醇和0.005-5重量份的多官能丙烯酸类单体加入到100重量份的包含50重量份的单体混合物中， 90重量％的芳族乙烯基类单体和10〜50重量％的氰基乙烯基系单体，具有超高分子量和非线性结构。
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