Abstract:
PURPOSE: Aqueous ceramic slurry and a method for preparing an aqueous ceramic tape using the slurry are provided, wherein the slurry contains no nonaqueous binder for preventing the danger of explosion, the environmental pollution and the problem of toxicity. CONSTITUTION: The aqueous ceramic slurry comprises metal oxide; 0.05-2.0 wt% of a dispersant, 10-50 wt% of water, 3-17 wt% of a plasticizer and 5-30 wt% of a PVP (poly(vinyl pyrrolidone)) binder based on the weight of the metal oxide; 0.5-30 wt% of a PVA (poly(vinyl alcohol)) binder based on the weight of the PVP binder; and optionally 0.1-2.0 wt% of gelatin as a binder based on the weight of the metal oxide. Preferably the metal oxide is alumina, spinel aluminate, zirconia or their mixtures; the dispersant is poly(methacrylic acid), poly(carboxylic acid), ammonium polyacrylate salt or ether; and the plasticizer is triethylene glycol, polyethylene glycol or their mixture.
Abstract:
본 발명은 더욱 향상된 품질계수(Q), 유전율(K)과 공진주파수의 온도계수(τ f )를 얻기 위하여, 90에서 99몰%의 (Zr x Sn y )Ti z O 4 (x+y+z=2, 0.6dxd1.0, 0dyd0.4, 0.6dzd1.4)를 주성분으로 하는 유전체 자기 조성물에 0.5에서 5.0몰%의 산화마그네슘 및 0.5에서 5.0몰%의 산화탄탈륨 또는 0.5에서 5.0몰%의 산화니오비늄의 복합물이 첨가되고 이에 부가하여 0.75에서 1.5 중량%의 산화아연이 가해져 소결된 고주파용 유전체 자기 조성물을 제공한다.
Abstract:
Method for manufacturing tetragonal zirconia polycrystal complex is provided which has high toughness without exhibiting low temperature degradation due to phase transition into monoclinic zirconia polycrystal even under exposure for log time at a low temperature range of 100 to 400 deg. C. Transitional tetragonal zirconia polycrystal produced from mixing 82 to 86 mol% of ZrO2 and 7 to 9 mol% of Y2O3, Nb2O5 and Ta2O5 respectively is mixed with not more than 60wt% of non-transitional tetragonal zirconia polycrystal having a composition of 93 to 97 mol% of ZrO2, 2 to 4 mol% of Y2O3 and 1 to 3 mol% of Nb2O5 or Ta2O5, and sintered at 1,500 deg. C or more for 2 to 10 hours, to produce the tetragonal zirconia polycrystal complex.
Abstract translation:提供四方晶氧化锆多晶配合物的制造方法,即使在100〜400度的低温范围内,即使在曝光时间对数时,由于相转变成单斜晶氧化锆多晶而具有高韧性而不显示低温降解。 C.将82〜86mol%的ZrO 2和7〜9mol%的Y 2 O 3,Nb 2 O 5和Ta 2 O 5分别混合的过渡四方晶氧化锆多晶与不大于60wt%的非过渡四方晶氧化锆多晶相混合,组成为93〜 ZrO2为97摩尔%,Y2O3为2〜4摩尔%,Nb2O5或Ta2O5为1〜3摩尔%,烧结温度为1500度。 ℃以上2〜10小时,生成四方晶氧化锆多晶复合体。
Abstract:
본 발명은 물을 용매로 포함하고 수계 결합제를 포함하는 세라믹 슬러리의 제조, 이를 이용한 세라믹 테이프 제조방법 및 이들을 이용하여 제조된 세라믹 테이프에 관한 것이다. 즉, 본 발명은 용매로서 물을 사용하고 결합제로서 아크릴 에멀젼과 HPMC를 혼합 사용하는 것을 특징으로 하며, 이들을 유리-알루미나 복합 분말, 분산제, 가소제 등과 혼합하는 수계 세라믹 슬러리 및 이를 혼합, 탈포, 성형 건조하는 것을 포함하는 세라믹 테이프 제조에 관한 것이다.
Abstract:
PURPOSE: Provided are an aqueous ceramic slurry containing an acryl emulsion as a binder and a method for producing a ceramic tape for LTCC(low temperature co-fired ceramic) by using the aqueous ceramic slurry. The ceramic tape dose not generate environmental pollution and is not harmful to human bodies. CONSTITUTION: The aqueous ceramic slurry comprises 100pts.wt. of a metal oxide powder, 0.1-3.0pts.wt. of a dispersant, 15-50pts.wt. of water, 5-20pts.wt. of an aqueous binder, and 3-15pts.wt. of a plasticizer, wherein the aqueous binder is a mixture of the acryl emulsion and HPMC(hydroxypropyl methyl cellulose). And the method for producing the ceramic tape contains the steps of: preparing the ceramic slurry; ball-milling the ceramic slurry and then stirring under a vacuum at a fixed speed to remove residual foams from the slurry and to reach a proper viscosity; forming the defoamed ceramic slurry into a sheet. The ceramic tape for LTCC produced by the method has a thickness of 20-200 micrometer.
Abstract:
PURPOSE: Aqueous ceramic slurry and a method for preparing an aqueous ceramic tape using the slurry are provided, wherein the slurry contains no nonaqueous binder for preventing the danger of explosion, the environmental pollution and the problem of toxicity. CONSTITUTION: The aqueous ceramic slurry comprises metal oxide; 0.05-2.0 wt% of a dispersant, 10-50 wt% of water, 3-17 wt% of a plasticizer and 5-30 wt% of a PVP (poly(vinyl pyrrolidone)) binder based on the weight of the metal oxide; 0.5-30 wt% of a PVA (poly(vinyl alcohol)) binder based on the weight of the PVP binder; and optionally 0.1-2.0 wt% of gelatin as a binder based on the weight of the metal oxide. Preferably the metal oxide is alumina, spinel aluminate, zirconia or their mixtures; the dispersant is poly(methacrylic acid), poly(carboxylic acid), ammonium polyacrylate salt or ether; and the plasticizer is triethylene glycol, polyethylene glycol or their mixture.
Abstract:
PURPOSE: A synthesizing method of fine powder of copper using organic solvent is provided to directly prepare copper powder without reduction treatment by inducing reaction of organic solvent at proper temperature and pressure. CONSTITUTION: The synthesizing method of fine powder of copper using organic solvent comprises the processes of preparing copper hydroxide sediment by reacting a copper precursor aqueous solution with a neutralizer selected from calcium hydroxide (KOH), sodium hydroxide (NaOH) and ammonium hydroxide (NH4OH); and reacting the mixed solution at a temperature of 200 to 300 deg.C for 0.5 to 20 hours after dissolving the sediment into an organic solvent, wherein the copper precursor is at least one or more precursors selected from copper nitrate hydride (Cu(NO3)2·xH2O), copper chloride dehydride (CuCl2·2H2O), copper sulfide pentahydride (CuSO4·5H2O) and copper sulfide hydride (CuSO4·xH2O), wherein the organic solvent is at least one or more solvents selected from ethylene glycol, di(ethylene glycol), polyethylene glycol and butanediol, and wherein centrifuge method is used to recover the obtained copper fine powder.
Abstract:
PURPOSE: Provided is a water-based ceramic slurry using water, and polyvinyl pyrrolidone(PVP) and gelatin as solvent and a binder based on water, unlike conventional nonwater-based solvent and binder, for producing ceramic tapes. CONSTITUTION: The water-based ceramic slurry comprises the components of: metal oxide powder such as Al2O3, magnesium aluminate spinel, ZrO2, Al2O3/ZrO2 composite or spinel/ZrO2 composite; 0.01-2.0wt.% of dispersant such as polymethacrylic acid, polycarboxylic acid, ammonium polyacrylate or ether; 20-90wt.% of water; 5-20wt.% of PVP and 0.1-2.0wt.% of gelatin as a binder; 3-17wt.% of plasticizer such as triethylene glycol or polyethylene glycol. The each amount is based on the metal oxide powder and 0.3-2.0wt.%(based on the total components) surfactant is optionally added. The preparation method of ceramic tapes is as follows: mixing all components except gelatin, for a ceramic slurry with a viscosity of 1000-3000cps; defoaming by heating the slurry in boiling water(50-80deg.C); adding a gelatin solution, obtained by dissolving gelatin into water(50-80deg.C), and defoaming again; and forming the slurry into a sheet.