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公开(公告)号：KR1020110022431A
公开(公告)日：2011-03-07
申请号：KR1020090080025
申请日：2009-08-27
Applicant: 현대자동차주식회사
CPC classification number: H01M4/8668 , H01M4/8828 , H01M4/8882 , H01M4/92 , H01M2008/1095
Abstract: PURPOSE: A porous electrode catalyst layer for a fuel cell is provided to obtain an electrode with improved bindability with a hydrocarbon-based film by lowering a glass transition temperature of a hydrocarbon-based binder. CONSTITUTION: A porous electrode catalyst layer for a fuel cell comprises sulfonated hydrocarbon, porogen, and platinum catalyst. The sulfonated hydrocarbon is such that single or two or more hydrocarbons are sulfonated, wherein the hydrocarbon is selected from polysulfone, polyarylene ethersulfone, polyetherethersulfone, polyethersulfone, polyimide, polyimidazole, polybenzimidazole, polyether benzimidazole, polyarylene ethylene ketone, polyether ether ketone, and polystyrene.
Abstract translation: 目的：提供一种用于燃料电池的多孔电极催化剂层，以通过降低烃基粘合剂的玻璃化转变温度来获得具有改进的与烃类膜的粘合性的电极。 构成：用于燃料电池的多孔电极催化剂层包括磺化烃，致孔剂和铂催化剂。 所述磺化烃使得一个或两个以上的烃被磺化，其中烃选自聚砜，聚亚芳基醚砜，聚醚醚砜，聚醚砜，聚酰亚胺，聚咪唑，聚苯并咪唑，聚醚苯并咪唑，聚亚芳基乙烯酮，聚醚醚酮和聚苯乙烯。
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公开(公告)号：KR100969011B1
公开(公告)日：2010-07-09
申请号：KR1020080015339
申请日：2008-02-20
Applicant: 현대자동차주식회사 , 서강대학교산학협력단
IPC: H01M8/10
CPC classification number: C08J5/2275 , C08J2371/00 , C08J2381/06 , H01M8/1016 , H01M2300/0068 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
Abstract: 3-아미노프로필트리에틸실란과 테트라에틸오소실리케이트의 기공 구조를 양말단에 포함하고 인산이 화학적으로 결합된, 주쇄가 폴리디메틸실록산(poly dimethyl siloxane)인 무기고분자로 이루어진 고분자 및 측쇄에 양이온 교환기를 갖는 양성자 전도성 고분자로 이루어진 고분자 블렌드 전해질 막 및 그 제조방법에 관한 것이다.
일반적으로, 양이온 전도성 전해질 막은 고온에서는 그 양이온 전도성이 급격히 떨어진다. 그러나, 효율성과 비용적인 이점이 있어, 고온에서도 양이온 전도성이 우수한 전해질 막이 요구되는 바, 본 발명에서는 고온용 고분자 블렌드 전해질 막과 이의 제조 방법을 제공하고자 한다.
연료전지, 전해질 막, 고분자 블렌드, 무기고분자, 인산-
公开(公告)号：KR1020100079695A
公开(公告)日：2010-07-08
申请号：KR1020080138240
申请日：2008-12-31
CPC classification number: B01J21/18 , B01J23/42 , B01J37/0225 , B01J37/04 , B01J37/08 , B82B3/00 , H01M4/92
Abstract: PURPOSE: A manufacturing method of platinum/fullerene hybrid nanoparticles or platinum ruthenium/fullerent hybrid nanoparticles, a catalyst manufactured thereby, and a manufacturing method of the catalyst are provided to offer high activity with uniform and small size. CONSTITUTION: A manufacturing method of platinum/fullerene hybrid nanoparticles includes a step for drying liquid at 200 ~ 300°C after making the liquid by mixing fullerene, platinum acetylacetonate, a reducing agent and a surfactant. A manufacturing method of platinum ruthenium/fullerent hybrid nanoparticles includes a step for drying the liquid in 200 ~ 300°C after mixing fullerene, platinum acetylacetonate, ruthenium acetyl acetonate, a reducing agent and a surface active agent. The reducing agent is 1,2- hexadecandiols, ethylene glycol and diethylene glycol.
Abstract translation: 目的：提供铂/富勒烯杂化纳米颗粒或铂钌/富勒杂交纳米颗粒的制造方法，由此制造的催化剂和催化剂的制造方法，以提供均匀和小尺寸的高活性。 构成：铂/富勒烯杂化纳米颗粒的制造方法包括在通过混合富勒烯，乙酰丙酮铂，还原剂和表面活性剂制备液体之后，在200〜300℃下干燥液体的步骤。 铂钌/富勒杂交纳米颗粒的制造方法包括在富勒烯，乙酰丙酮酸铂，乙酰丙酮钌，还原剂和表面活性剂混合后，在200〜300℃下干燥液体的步骤。 还原剂是1,2-十六烷二醇，乙二醇和二甘醇。
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公开(公告)号：KR100844752B1
公开(公告)日：2008-07-07
申请号：KR1020070063045
申请日：2007-06-26
Applicant: 현대자동차주식회사
CPC classification number: H01M4/921 , H01M4/926 , H01M2008/1095
Abstract: A method for preparing a mixed electrode catalyst material for a solid electrolyte fuel cell is provided to reduce the amount of platinum required for producing a high-quality electrode catalyst, thereby reducing the manufacturing cost of an electrode catalyst and fuel cell. A method for preparing a mixed electrode catalyst material for a solid electrolyte fuel cell comprises the steps of: (a) dispersing a RuOs alloy material dispersed in the state of highly dispersed crystalline nanoparticles into water, injecting nitrogen thereto to remove undesired gases, and preliminarily injecting hydrogen thereto as a reducing agent; introducing a platinum precursor solution to the dispersion of RuOs alloy material and further injecting hydrogen thereto for 1 hour after the completion of the platinum precursor; and (c) washing and drying the resultant product after the completion of the hydrogen injection to obtain a powdery material.
Abstract translation: 提供一种制备用于固体电解质燃料电池的混合电极催化剂材料的方法，以减少生产高质量电极催化剂所需的铂的量，从而降低电极催化剂和燃料电池的制造成本。 制备用于固体电解质燃料电池的混合电极催化剂材料的方法包括以下步骤：（a）将分散在高度分散的结晶纳米颗粒状态的RuO x合金材料分散在水中，向其中注入氮气以除去不期望的气体， 将氢气注入其中作为还原剂; 向RuO合金材料的分散体中引入铂前体溶液，并在铂前体完成后进一步注入氢气1小时; 和（c）在完成氢气注入之后洗涤和干燥所得产物以获得粉状材料。
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公开(公告)号：KR1020130035076A
公开(公告)日：2013-04-08
申请号：KR1020110099337
申请日：2011-09-29
Applicant: 현대자동차주식회사 , 주식회사 동진쎄미켐
CPC classification number: B01D71/82 , H01M8/1027 , H01M8/1032 , H01M8/1044 , H01M8/1048 , H01M8/1051
Abstract: PURPOSE: A proton-conducting polymer is provided to have a plurality of proton-conducting polymers, to have excellent dimensional stability, and to have high ion exchange capacity and hydrogen ion conductivity. CONSTITUTION: A proton-conducting polymer is represented by chemical formula 1. In the chemical formula 1: m is an integer from 0.01-0.99; n is an integer from 10-1,000; Y is a chemical bond, oxygen, or sulfur, independently; each of D and E is a divalent coupling group which comprises one or more selected from a substituted or unsubstituted C1-10 alkylene group, a substituted or unsubstituted C2-10 alkenylene group, a substituted or unsubstituted C6-20 arylene group, a sulfone group, or a carbonyl group; and Z is represented by chemical formula 2a.
Abstract translation: 目的：提供质子传导聚合物以具有多个质子传导聚合物，具有优异的尺寸稳定性，并具有高离子交换能力和氢离子传导性。 构成：质子导电聚合物由化学式1表示。在化学式1中：m是0.01-0.99的整数; n为10-1000的整数; Y是独立的化学键，氧或硫; D和E中的每一个是包含一个或多个选自取代或未取代的C 1-10亚烷基，取代或未取代的C 2-10亚烯基，取代或未取代的C 6-20亚芳基，砜基 ，或羰基; Z由化学式2a表示。
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Patent Agency Ranking
公开(公告)号：KR101134478B1
公开(公告)日：2012-04-13
申请号：KR1020100013909
申请日：2010-02-16
Applicant: 현대자동차주식회사 , 서울대학교산학협력단
IPC: C08F293/00 , C08F297/00 , H01M8/02 , H01M8/10
CPC classification number: H01M8/1023 , C08F8/36 , C08F293/00 , C08G65/48 , C08G75/23 , C08G2261/722 , C08G2650/40 , C08L71/00 , C08L2205/05 , H01M8/1025 , H01M8/1027 , H01M8/1044 , H01M8/1072 , H01M2300/0082 , Y02P70/56 , C08L25/06 , C08L25/04 , C08F293/005
Abstract: 본 발명은 양친성 블록 공중합체 , 이의 제조방법 및 이를 이용한 연료전지용 막에 관한 것이다. 보다 상세하게는 소수부로서 PSEK[poly(arylene sulfone ether ketone)]과 친수부의 PSSAN[poly(sulfonated styrene-co-acrylonitrile)]을 포함하는 블록 공중합체에 관한 것이다.
상기 양친성 블록 공중합체를 이용하여 제조된 고분자 전해질 막은 100℃ 이상의 고온에서도 수소이온전도도가 감소하는 경향을 보이지 않고, 오히려 증가하는 경향을 보였으며, 높은 열적/화학적 치수안정성을 보인다.-
公开(公告)号：KR101113632B1
公开(公告)日：2012-03-13
申请号：KR1020090103747
申请日：2009-10-29
Applicant: 현대자동차주식회사 , 서울대학교산학협력단
CPC classification number: H01M4/92 , H01M4/8663 , H01M4/885 , H01M4/926 , Y02E60/50
Abstract: 본 발명은 탄소에 담지된 전이금속 나노입자 촉매의 제조방법에 관한 것으로서, 더욱 상세하게 설명하면 에탄올에 안정화제를 녹인 혼합액에 담지체를 넣어 분산액을 제조하고, 여기에 전이금속 전구체를 에탄올에 용해시킨 전구체 용액을 혼합 및 교반한 후 환원공정을 거쳐 전이금속 나노입자 촉매를 제조하는 것을 특징으로 한다. 본 발명의 탄소에 담지된 전이금속 나노입자 촉매의 제조방법은 간단한 공정으로 좁은 입자 크기 분포와 넓은 분산도를 가지는 탄소분말에 담지된 전이금속 나노입자의 제조가 가능하여 연료전지의 전극물질 등에 유용하게 적용될 수 있다.
연료전지, 전이금속, 수소화붕소나트륨, 안정화제, 나노입자-
公开(公告)号：KR1020110094498A
公开(公告)日：2011-08-24
申请号：KR1020100013909
申请日：2010-02-16
Applicant: 현대자동차주식회사 , 서울대학교산학협력단
IPC: C08F293/00 , C08F297/00 , H01M8/02 , H01M8/10
CPC classification number: H01M8/1023 , C08F8/36 , C08F293/00 , C08G65/48 , C08G75/23 , C08G2261/722 , C08G2650/40 , C08L71/00 , C08L2205/05 , H01M8/1025 , H01M8/1027 , H01M8/1044 , H01M8/1072 , H01M2300/0082 , Y02P70/56 , C08L25/06 , C08L25/04 , C08F293/005
Abstract: PURPOSE: A hydrophilic-hydrophobic block copolymer is provided to ensure excellent thermomechanical stability, and to obtain an electrolyte film for a polymer electrolyte fuel cell with excellent thermal, chemical, and mechanical stability while having high hydrogen ion conductivity at high temperature. CONSTITUTION: A hydrophilic-hydrophobic block copolymer comprises one or more of homopolymers having hydrophobicity and polymers having hydrophilicity. The hydrophobic part includes the structure represented by chemical formula 1 and the hydrophilic part includes the structure represented by chemical formula 2. In chemical formula 2, p, m and are mutually independent integer, and m > r.
Abstract translation: 目的：提供亲水疏水性嵌段共聚物，以确保优异的机械稳定性，并获得具有优异的热稳定性，化学稳定性和机械稳定性的聚合物电解质燃料电池的电解质膜，同时在高温下具有高的氢离子传导性。 构成：亲水疏水性嵌段共聚物包含一种或多种具有疏水性的均聚物和具有亲水性的聚合物。 疏水部分包括由化学式1表示的结构，亲水部分包括由化学式2表示的结构。在化学式2中，p，m和相互独立的整数，并且m> r。
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19.发明公开술폰산기를 갖는 폴리(아릴렌에테르) 공중합체, 이의 제조방법 및 이를 이용한 연료전지용 고분자 전해질 막 有权磺化聚（亚乙基醚）共聚物，其制备方法和聚合物电解质膜用于使用共聚物的燃料电池
公开(公告)号：KR1020110063178A
公开(公告)日：2011-06-10
申请号：KR1020090120133
申请日：2009-12-04
Applicant: 현대자동차주식회사 , 주식회사 동진쎄미켐
IPC: C08G65/334 , C08G65/32 , C08J5/22 , H01M8/10
CPC classification number: H01M8/1025 , C08G65/4012 , C08G65/48 , C08G75/23 , C08G2261/722 , C08J5/2256 , C08J2371/12 , C08J2481/06 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1044 , H01M8/1048 , H01M8/1051 , H01M8/1072 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
Abstract: PURPOSE: A poly(arylene ether) copolymer having a sulfonic acid group is provided to ensure high hydrogen ion conductivity and excellent mechanical properties due to high sulfonation degree and high average molecular weight. CONSTITUTION: A poly(arylene ether) copolymer having a sulfonic acid group is represented by chemical formula 3. A polymer electrolyte membrane comprises the poly(arylene ether) copolymer. The polymer electrolyte membrane further includes one or more polymers selected from the group consisting of polyimide, polyetherketone, polysulfone, polyethersulfone, polyetherethersulfone, polybenzimidazole, polyphenylene oxide, polyphenylene sulfide, polystyrene, polytrifluorostyrene sulfonic acid, polystyrenesulfonic acid, polyurethane, and branched sulfonated polysulfone ketone copolymers.
Abstract translation: 目的：提供具有磺酸基的聚（亚芳基醚）共聚物，以确保高磺化程度和高平均分子量的高氢离子传导性和优异的机械性能。 构成：具有磺酸基的聚（亚芳基醚）共聚物由化学式3表示。聚合物电解质膜包含聚（亚芳基醚）共聚物。 聚合物电解质膜还包括一种或多种选自聚酰亚胺，聚醚酮，聚砜，聚醚砜，聚醚醚砜，聚苯并咪唑，聚苯醚，聚苯硫醚，聚苯乙烯，聚三氟苯乙烯磺酸，聚苯乙烯磺酸，聚氨酯和支链磺化聚砜酮 共聚物。
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公开(公告)号：KR1020110060094A
公开(公告)日：2011-06-08
申请号：KR1020090116575
申请日：2009-11-30
Applicant: 현대자동차주식회사
CPC classification number: H01M4/8605 , H01M4/8896 , H01M4/921 , H01M4/926
Abstract: PURPOSE: An electrode for a polymer electrolyte membrane fuel cell is provided to reinforce mechanical strength and to maintain the thickness of a catalyst layer after long time driving by adding carbon nano fibers to an electrode catalyst layer of a fuel cell. CONSTITUTION: An electrode for a polymer electrolyte membrane fuel cell comprises, 100.0 parts by weight of a catalyst, 20~80 parts by weight of hydrogen ion conductive polymer electrolyte binder, 1~60 parts by weight of carbon nanofiber, 1~20 parts by weight of radical inhibitor. The carbon nano fiber is one selected from the group consisting of carbon nanotubes with 5~100 nm size, carbon nanofiber, carbon nanowires, carbon nanohorns, and carbon nanorings, and their mixture.
Abstract translation: 目的：提供一种聚合物电解质膜燃料电池用电极，通过向燃料电池的电极催化剂层添加碳纳米纤维，来增强机械强度并长时间驱动后维持催化剂层的厚度。 构成：用于聚合物电解质膜燃料电池的电极包括：100.0重量份催化剂，20〜80重量份氢离子导电聚合物电解质粘合剂，1〜60重量份碳纳米纤维，1〜20重量份 自由基抑制剂的重量。 碳纳米纤维是选自具有5〜100nm尺寸的碳纳米管，碳纳米纤维，碳纳米线，碳纳米角和碳纳米线的组合，以及它们的混合物。
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