公开(公告)号：KR1020040006120A

公开(公告)日：2004-01-24

申请号：KR1020020039655

申请日：2002-07-09

Applicant: 현대자동차주식회사

Inventor： 이성준 ,  박봉현 ,  김준수 ,  돈윤승

IPC: C08L21/00 ,  C08L51/04 ,  C08L25/12

CPC classification number: C08L51/04 ,  C08J2300/22 ,  C08L21/02 ,  C08L25/12 ,  C08L2205/025

Abstract: PURPOSE: Provided is a thermoplastic resin composition for use in interior and exterior materials of cars, which has excellent dimensional stability at a high temperature, improved impact resistance, and excellent moldability and coating property. CONSTITUTION: The thermoplastic resin composition comprises: 30-70 wt% of a rubber latex; 10-30 wt% of a graft copolymer(I) comprising 70-30 wt% of a mixed monomer consisting of 20-40 wt% of a vinyl cyanide monomer and 60-80 wt% of an aromatic vinyl compound monomer; 20-50 wt% of a non-linear graft copolymer(II) consisting of 20-40 wt% of a vinyl cyanide monomer and 60-80 wt% of an aromatic vinyl compound monomer and having a weight average molecular weight of 200,000-1,000,000; and 20-60 wt% of a linear graft copolymer(III) consisting of 20-40 wt% of a vinyl cyanide monomer and 60-80 wt% of an aromatic vinyl compound monomer and having a weight average molecular weight of 100,000-200,000.

Abstract translation: 目的：提供一种用于汽车的室内外材料的热塑性树脂组合物，其在高温下具有优异的尺寸稳定性，改善的耐冲击性，优异的成型性和涂布性。 构成：热塑性树脂组合物包含：30-70重量％的橡胶胶乳; 10-30重量％的包含70-30重量％的由20-40重量％的乙烯基氰单体和60-80重量％的芳族乙烯基化合物单体组成的混合单体的接枝共聚物（I） 20-50重量％的由20-40重量％的乙烯基氰单体和60-80重量％的芳族乙烯基化合物单体组成的非线性接枝共聚物（II），其重均分子量为200,000-1,000,000 ; 和20-60重量％的由20-40重量％的乙烯基氰单体和60-80重量％的芳族乙烯基化合物单体组成的重均分子量为100,000-200,000的线性接枝共聚物（III）。

公开(公告)号：KR1020020084601A

公开(公告)日：2002-11-09

申请号：KR1020010024002

申请日：2001-05-03

Applicant: 현대자동차주식회사

Inventor： 이성준 ,  박봉현

IPC: C08L23/16

CPC classification number: C08L23/16 ,  C08K3/34 ,  C08K2201/005 ,  C08L2201/02 ,  C08L2205/02

Abstract: PURPOSE: A resin composition is provided, which is improved in the low temperature impact resistance, the hardness and the flowability by optimizing the dispersibility and particle size of rubber, and can be applied to the bumper cover of a car. CONSTITUTION: The resin composition comprises 70-95 wt% of an ethylene-propylene copolymer resin; 5-20 wt% of a thermoplastic elastic rubber; and 0-10 wt% of an inorganic filler. The ethylene-propylene copolymer resin contains ethylene by the amount of 15-25 % and has a melting index of 10-30 g/10 min(230 deg.C, 2.16 kgf). Preferably the thermoplastic elastic rubber is at least one selected from the group consisting of an ethylene-propylene rubber containing 70-80 % of ethylene, an ethylene-propylene-diene rubber containing 70-80 % of ethylene and an ethylene-octene rubber containing 23-27 % of octene. The inorganic filler is preferably talc with a mean particle size of 1-10 micrometers.

Abstract translation: 目的：提供通过优化橡胶的分散性和粒径来提高耐低温冲击性，硬度和流动性的树脂组合物，并且可以应用于汽车的保险杠盖。 构成：树脂组合物包含70-95重量％的乙烯 - 丙烯共聚物树脂; 5-20重量％的热塑性弹性橡胶; 和0-10重量％的无机填料。 乙烯 - 丙烯共聚物树脂含有15-25％的乙烯，熔融指数为10-30g / 10min（230℃，2.16kgf）。 优选地，热塑性弹性橡胶是选自含有70-80％乙烯的乙烯 - 丙烯橡胶，含有70-80％乙烯的乙烯 - 丙烯 - 二烯橡胶和含有23个乙烯 - 辛烯橡胶的至少一种 -27％的辛烯。 无机填料优选平均粒度为1-10微米的滑石。

公开(公告)号：KR100292878B1

公开(公告)日：2001-06-15

申请号：KR1019990015655

申请日：1999-04-30

Applicant: 금호케미칼 주식회사 ,  현대자동차주식회사

Inventor： 임동수 ,  강성우 ,  강원길 ,  이성준 ,  박봉현 ,  김성수

IPC: C08L9/00

Abstract: 본발명은열가소성수지조성물에관한것으로서, 더욱상세하게는내열도금용재료로종래부터사용되던내열 ABS 수지대신에열분해의주요원인물질인α-메틸스티렌및 N-페닐말레이미드를사용하지않은 ABS-수지와내열특성이우수한폴리카보네이트수지를블렌딩함으로써, 밀착강도가우수하고열변형온도가높아도금특성이우수한열가소성수지조성물에관한것이다.

公开(公告)号：KR1020010003015A

公开(公告)日：2001-01-15

申请号：KR1019990023124

申请日：1999-06-19

Applicant: 현대자동차주식회사 ,  한국과학기술원

Inventor： 임양수 ,  박봉현 ,  이성준 ,  김진백 ,  이재준 ,  신범수 ,  조갑성

IPC: C09D183/06

CPC classification number: C09D183/04 ,  C08K5/0025

Abstract: PURPOSE: The coating composition prepared by adding dicyandiamide as a curing catalyst to a silicon-based coating composition comprising a silanol partial condensate and a colloidal silica dispersion is provided, which has excellent abrasion resistance and adhesion property and can store at ordinary temperatures and is excellent in low temperatures cross-linking curing and simplifies coating processes without changing mechanical and mechanical properties. CONSTITUTION: In a silicon-based coating composition comprising a silanol partial condensate and a colloidal silica dispersion, the composition contains a silanol partial condensate having a particle diameter of 2 to 30 micrometer and a colloidal silica dispersion in a weight ratio of 30 to 80 and 20 to 70% by weight and 0.05 to 2.5% by weight of dicyandiamide as a curing catalyst based on the solids content of the mixtures. The composition is suitable for coating an automobile part, optical material, building material and electrical material.

Abstract translation: 目的：提供通过将双氰胺作为固化催化剂添加到包含硅烷醇部分缩合物和胶体二氧化硅分散体的硅系涂料组合物中制备的涂料组合物，其具有优异的耐磨性和粘合性，并且可以在常温下储存并且是优异的 在低温下交联固化，简化了涂层工艺，而不改变机械和机械性能。 构成：在包含硅烷醇部分缩合物和胶体二氧化硅分散体的硅基涂料组合物中，该组合物含有粒径为2至30微米的硅烷醇部分缩合物和重量比为30至80的胶体二氧化硅分散体和 20至70重量％和0.05至2.5重量％的双氰胺作为固化催化剂，基于混合物的固体含量。 该组合物适用于涂覆汽车部件，光学材料，建筑材料和电气材料。

公开(公告)号：KR1020020096342A

公开(公告)日：2002-12-31

申请号：KR1020010034743

申请日：2001-06-19

Applicant: 현대자동차주식회사 ,  한화종합화학 주식회사

Inventor： 박봉현 ,  이성준 ,  정원범 ,  채경석

IPC: C08L23/00

CPC classification number: C08L23/142 ,  C08L23/16 ,  C08L53/02 ,  C08L2666/24 ,  C08L2666/04

Abstract: PURPOSE: A polyolefin resin composition for the wheel cover of a car is provided, which has the strength, the impact strength, the heat resistance and the hardness applicable to the wheel cover of a car and the improved coating property and does not generate the projection in the weld line generation part. CONSTITUTION: The polyolefin resin composition comprises 40-75 wt% of a super high crystalline olefin-based resin; 3-25 wt% of a polyolefin-based elastomer; and 5-30 wt% of an inorganic filler. Preferably the super high crystalline olefin-based resin has a melt index of 10-80 g/10 min and the isotactic peptide fraction of the homopolymer part of 96% or more, and is a copolymer the α-olefin selected from isotactic polypropylene, propylene-ethylene copolymer, propylene-1-butene copolymer, propylene-1-hexene copolymer and propylene-4-methyl-1-pentene copolymer, and propylene; a random copolymer; or their mixture.

Abstract translation: 目的：提供一种用于汽车车轮罩的聚烯烃树脂组合物，其具有强度，冲击强度，耐热性和适用于汽车车轮罩的硬度和改善的涂覆性能，并且不产生突起 在焊线生成部分。 构成：聚烯烃树脂组合物包含40-75wt％的超高结晶烯烃基树脂; 3-25重量％的聚烯烃类弹性体; 和5-30重量％的无机填料。 优选超高结晶性烯烃类树脂的熔融指数为10-80g / 10min，均聚物部分的全同立构肽部分为96％以上，是选自全同立构聚丙烯，丙烯 乙烯共聚物，丙烯-1-丁烯共聚物，丙烯-1-己烯共聚物和丙烯-4-甲基-1-戊烯共聚物和丙烯; 无规共聚物; 或它们的混合物。

公开(公告)号：KR1020010060125A

公开(公告)日：2001-07-06

申请号：KR1019990068247

申请日：1999-12-31

Applicant: 현대자동차주식회사

Inventor： 박봉현 ,  이성준

IPC: C08L23/16

CPC classification number: C08L23/16 ,  C08K3/34 ,  C08K2201/005

Abstract: PURPOSE: A semi-rigid olefine based resin composition is provided to enhance formability and coating property at injection molding of bulk products as well as to significantly increase impact-resistance, heat-resistance and bending elasticity by comprising ethylene-propylene copolymers having different rubber contents as the primary components and adding other modified resin and additives. CONSTITUTION: The semi-rigid olefine based resin composition comprises 18-22 wt.% of ethylene-propylene copolymer containing 7-12 wt.% of ethylene-propylene rubber; and 50-60 wt.% of ethylene-propylene copolymer containing 20-30 wt.% of ethylene- propylene rubber. The composition further includes 10-20 wt.% of ethylene-alpha-olefine copolymer rubber, 0-5 wt.% of talc, 1-2 wt.% of modified resin and 0.1-1.0 wt.% of additives. The ethylene-alpha-olefine copolymer rubber is ethylene-propylene rubber containing 25-45 wt.% of propylene and having 0.5-3g/10min.(230 deg.C.) of the melt index. The modified maleic anhydride is grafted ethylene-propylene rubber or ethylene-2-hydroxy ethylmethacrylate copolymer.

Abstract translation: 目的：提供半刚性烯烃基树脂组合物，以提高散装产品的注塑成型性和涂层性能，并通过包含不同橡胶含量的乙烯 - 丙烯共聚物显着提高抗冲击性，耐热性和弯曲弹性 作为主要成分，并加入其他改性树脂和添加剂。 构成：半刚性烯烃基树脂组合物包含18-22重量％的含有7-12重量％乙丙橡胶的乙烯 - 丙烯共聚物; 和50-60重量％的含有20-30重量％乙丙橡胶的乙烯 - 丙烯共聚物。 组合物还包括10-20重量％的乙烯-α-烯烃共聚物橡胶，0-5重量％的滑石，1-2重量％的改性树脂和0.1-1.0重量％的添加剂。 乙烯-α-烯烃共聚物橡胶是含25-45％（重量）丙烯，熔体指数为0.5-3g / 10min（230℃）的乙丙橡胶。 改性马来酸酐是接枝的乙丙橡胶或乙烯-2-羟乙基甲基丙烯酸酯共聚物。

公开(公告)号：KR1020010060122A

公开(公告)日：2001-07-06

申请号：KR1019990068244

申请日：1999-12-31

Applicant: 현대자동차주식회사

Inventor： 박봉현 ,  이성준

IPC: C08L23/16

CPC classification number: C08L23/16 ,  C08F210/02 ,  C08F2500/12 ,  C08K3/013 ,  C08K3/26 ,  C08L23/08 ,  C08L23/12

Abstract: PURPOSE: An olefin based composite resin composition is provided for formability and painting ability at injection molding of bulk products as well as other physical properties such as impact-resistance, bending and heat-resistance, good tensile strength, surface hardness and scratch-resistance by adding specific ethylene-alpha-olefine copolymer rubber and other inorganic reinforcing agents. CONSTITUTION: The olefin based composition comprises as the main components, 15-70 wt.% of polyethylene-polypropylene copolymer containing 0-70 wt.% of crystalline polypropylene and 5-14 wt.% of ethylene-alpha-olefine; 14-30 wt.% of inorganic reinforcing agent and 0.4-12.5 wt.% of other additives. The ethylene-alpha-olefine includes 2-5 wt.% of the ethylene-propylene rubber having 25-45 wt.% of propylene and a melt index of 0.5-3g/10min.(230 deg.C) or the 2-11 wt.% of ethylene-octene rubber having 20-30 wt.% of octene and a melt index of 0.5-2g/10min.(230 deg.C). The inorganic reinforcing materials contain at least one of 2-4 wt.% of particulate inorganic reinforcing agent having 0.5-10 micrometer made of CaCO3 and BaSO4 and 14-30 wt.% of single plane shaped inorganic reinforcing agent having aspecto ratio of 3-20.

Abstract translation: 目的：提供一种烯烃基复合树脂组合物，用于散装产品的注塑成型性和涂装能力以及其它物理性能如耐冲击性，弯曲性和耐热性，良好的拉伸强度，表面硬度和耐刮擦性 加入特定的乙烯-α-烯烃共聚物橡胶等无机增强剂。 构成：基于烯烃的组合物包含15-70重量％的含有0-70重量％结晶聚丙烯和5-14重量％乙烯-α-烯烃的聚乙烯 - 聚丙烯共聚物作为主要组分; 14-30重量％的无机增强剂和0.4-12.5重量％的其它添加剂。 乙烯-α-烯烃包括2-5重量％的乙丙橡胶，其具有25-45重量％的丙烯，熔体指数为0.5-3克/ 10分钟（230℃）或2-11 重量百分比为20-30重量％的辛烯的乙烯 - 辛烯橡胶，熔体指数为0.5-2克/ 10分钟（230℃）。 无机增强材料含有2-4重量％的具有0.5-10微米的CaCO 3和BaSO 4的颗粒状无机增强剂和14-30重量％的单面无机增强剂中的至少一种，其具有比例为3- 20。

公开(公告)号：KR1020000067654A

公开(公告)日：2000-11-25

申请号：KR1019990015655

申请日：1999-04-30

Applicant: 금호케미칼 주식회사 ,  현대자동차주식회사

Inventor： 임동수 ,  강성우 ,  강원길 ,  이성준 ,  박봉현 ,  김성수

IPC: C08L9/00

CPC classification number: C08L51/04 ,  C08K5/54 ,  C08L9/00 ,  C08L25/12 ,  C08L69/00

Abstract: PURPOSE: A thermoplastic resin composition obtained by blending ABS resin without using α-methylene and N-phenylmaleimide as a major cause material of a thermal decomposition in place of conventional heat resistant ABS resin with a polycarbonate resin having excellent heat resistance is provided which has improved adhesion strength and plating characteristics. CONSTITUTION: The thermoplastic resin composition comprises 30 to 50% by weight of a graft copolymer (A) obtained by graft copolymerization of 30 to 70% by weight of conjugated rubber, 20 to 40% by weight of aromatic vinyl and 10 to 30% by weight of cyanide vinyl; 10 to 20% by weight of a copolymer (B) comprising 60 to 80% by weight of aromatic vinyl and 20 to 40% by weight of cyanide vinyl; and 30 to 55% by weight of polycarbonate resin. The composition has high heat deflection temperature such that it has excellent plating characteristics.

Abstract translation: 目的：提供一种热塑性树脂组合物，其通过将不含α-亚甲基和N-苯基马来酰亚胺作为热分解的主要原料而不是常规耐热ABS树脂与耐热性优异的聚碳酸酯树脂共混而得到的热塑性树脂组合物，其改进 粘合强度和电镀特性。 构成：热塑性树脂组合物含有30〜50重量％的接枝共聚物（A），其通过将30〜70重量％的共轭橡胶，20〜40重量％的芳香族乙烯基和10〜30重量％的共聚橡胶 氰化乙烯基重量; 10至20重量％的共聚物（B），其包含60至80重量％的芳族乙烯基和20至40重量％的氰化乙烯基; 和30〜55重量％的聚碳酸酯树脂。 该组合物具有高的热变形温度，使得其具有优异的电镀特性。