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    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS
    16.
    发明申请
    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS 审中-公开
    制备多孔丙烯聚合物的方法

    公开(公告)号：WO2015059117A1

    公开(公告)日：2015-04-30

    申请号：PCT/EP2014/072501

    申请日：2014-10-21

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GADDI, Benedetta ,  BOCCHINO, Marco ,  COLLINA, Gianni ,  FUSCO, Ofelia ,  GUIDOTTI, Simona ,  MAZZUCCO, Antonio ,  PANTALEONI, Roberto ,  PIEMONTESI, Fabrizio

    IPC: C08F10/06 ,  C08F210/06

    CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

    Abstract: Process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55°C; optionally, ii) pre-polymerizing with one or more olefins of formula CH 2 =CHR, where R is H or a C 1 -C 10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C 4 -C 10 alpha olefins producing said porous propylene (co)polymer.

    Abstract translation: 在催化剂体系存在下进行的多孔丙烯的制备方法，该催化剂体系包含（a）含有至少两种电子给体化合物的齐格勒 - 纳塔催化剂，其中一种催化剂体系以50至90摩尔％的量存在， 相对于供体的总量，选自琥珀酸盐，另一种选自1,3-二醚，（b）烷基铝，包括以下步骤：i）使催化剂组分（a）和（b）接触一段时间 时间为1至60分钟，温度范围为35至55℃; 任选地，ii）使用一种或多种式CH 2 = CHR的烯烃进行预聚合，其中R是H或C1-C10烃基，直至每克固体催化剂组分约0.1至约1000g的聚合物的形成量 （一个）; 和iii）在少量乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯，生产所述多孔丙烯（共）聚合物。

    COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
    18.
    发明申请
    COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开

    公开(公告)号：WO2020035283A1

    公开(公告)日：2020-02-20

    申请号：PCT/EP2019/070086

    申请日：2019-07-25

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GUIDOTTI, Simona ,  LIGUORI, Dario ,  MORINI, Giampiero ,  VITALE, Gianni

    IPC: C08F210/06 ,  C08F210/16 ,  C08F4/657

    Abstract: A solid catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, Bi, halogen and an electron donor obtained from a process comprising: (a) dissolving a Mg(OR) 2 compound where R groups, equal or different to each other, are C 1 -C 15 hydrocarbon groups optionally containing a heteroatom selected from O, N and halogen, in an organic liquid medium in order to have a liquid mixture; (b) contacting the above mixture (a) with Ti Cl 4 obtaining a liquid mixture not containing solid phase, and (c) subjecting the liquid mixture (b) to conditions such that solid catalyst particles are formed, said process being characterized by the fact that (i) a Bi compound and (ii) a bidentate electron donor compound is present in one or more of steps (a) to (c) and/or contacted with the solid catalyst particles obtained from (c).

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