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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    3.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：WO2018060116A1

    公开(公告)日：2018-04-05

    申请号：PCT/EP2017/074180

    申请日：2017-09-25

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GUIDOTTI, Simona ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F210/16 ,  C08F4/651 ,  C08F4/656 ,  C08F4/658

    CPC classification number: C08F10/02 ,  C08F210/16 ,  C08F2410/01 ,  C08F210/08 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6494 ,  C08F4/6567

    Abstract: A process for the preparation of a solid catalyst component for the homo or copolymerization of olefins which comprises Mg, Ti, halogen and an electron donor selected from cycloalkyl ethers, said process comprising (a) dissolving a Mg based compound and a TiCI 3 based compound in a liquid medium further comprising a cycloalkyl ether and a compound of formula R 2 OH where R 2 is a C 1 -C 20 hydrocarbon group, in which the Ti/Mg molar ratio ranges from 0.1 to 0.5, the cycloalkyl ether/Mg ratio ranges from 1 to 4 and the R 2 OH/Mg molar ratio ranges from 1 to 4; and (b) adding, to the solution coming from step (a), SiCI4 in an amount such that the R 2 OH/SiCI4 molar ratio ranges from 0.5 to 1.5 and maintaining the temperature in the range 50-150°C thereby allowing precipitation of the solid catalyst component particles.

    Abstract translation: 一种制备用于烯烃均聚或共聚的固体催化剂组分的方法，该组分包含Mg，Ti，卤素和选自环烷基醚的电子供体，所述方法包括：（a）将Mg 在液体介质中进一步包含环烷基醚和式R 2 OH的化合物，其中R 2是（CH 3）2基团的化合物和基于TiCl 3的化合物 C 1 -C 20烃基，其中Ti / Mg摩尔比范围为0.1至0.5，环烷基醚/ Mg比率范围为1至4，且 R 2 OH / Mg摩尔比范围为1至4; 和（b）向来自步骤（a）的溶液中加入一定量的SiCl 4，使R 2 / OH / SiCl 4摩尔比为0.5-1.5，并保持温度在50℃ -150℃，从而使固体催化剂组分颗粒沉淀。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    4.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：WO2017186623A1

    公开(公告)日：2017-11-02

    申请号：PCT/EP2017/059619

    申请日：2017-04-24

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GUIDOTTI, Simona ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F10/02 ,  C08F4/654 ,  C08F4/651

    Abstract: A solid catalyst component obtainable by a process comprising: (a) a first step in which a titanium compound of formula Ti(OEt) 4 , is reacted with a Mg based compound at a Ti/Mg molar ratio between 0.2 and 0.4, at a reaction temperature between 110 and 130°C during 2 to 5 hours; and (b) a subsequent step in which the product obtained in (a) is reacted with a Ti compound formula Ti(OR I ) 4-y Cl y , where y is a number between 3 and 4.

    Abstract translation: （a）第一步，其中使式Ti（OEt）4的钛化合物与基于Mg Ti / Mg摩尔比为0.2-0.4的化合物，反应温度为110-130℃，时间为2-5小时; 和（b）随后的步骤，其中使（a）中获得的产物与Ti化合物式Ti（OR 1）4-yCl y ，其中y是3到4之间的数字。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    5.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：WO2013131912A2

    公开(公告)日：2013-09-12

    申请号：PCT/EP2013/054399

    申请日：2013-03-05

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M.

    CPC classification number: C08F4/6494 ,  C07C69/96 ,  C07C2603/18 ,  C08F4/6543 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which R1 groups are selected from C 1 -C 15 hydrocarbon groups, R 8 groups, equal or different to each other, are selected from hydrogen, halogen and C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N and Si and L is a divalent hydrocarbon group optionally containing heteroatoms selected from halogen, O, P, S, N and Si.

    Abstract translation: 用于烯烃聚合的催化剂组分包含Mg，Ti和下式（I）的电子给体化合物，其中R 1基团选自C 1 -C 4烷基， 15个烃基，R 8基团彼此相同或不同，选自氢，卤素和C 1 -C 15 烃基，任选地含有选自卤素，O，P，S，N和Si的杂原子，并且L是任选地含有选自卤素，O，P，S，N和Si的杂原子的二价烃基。 p>

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    9.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2013174759A1

    公开(公告)日：2013-11-28

    申请号：PCT/EP2013/060289

    申请日：2013-05-17

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M.

    IPC: C08F10/00 ,  C08F4/651

    CPC classification number: C08F10/06 ,  C08F10/00 ,  C08F4/6543 ,  C08F4/651 ,  C08F110/06 ,  C08F2500/12

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I), in which R2-R8 groups, equal or different to each other, are selected from hydrogen, halogen and C1 -C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N, and Si and R9 groups are selected from C1 -C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, O, P, S, N, and Si.

    Abstract translation: 包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合用催化剂组分，其中相互相同或不同的R 2 -R 8基团选自氢，卤素和C 1 -C 15烃基 任选地含有选自卤素，O，P，S，N和Si的杂原子，R 9基团选自任选含有选自卤素，O，P，S，N和Si的杂原子的C 1 -C 15烃基。

    CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS
    10.
    发明申请
    CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂体系

    公开(公告)号：WO2013092205A1

    公开(公告)日：2013-06-27

    申请号：PCT/EP2012/074394

    申请日：2012-12-05

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M. ,  MORINI, Giampiero

    IPC: C08F4/649 ,  C08F110/06 ,  C08F4/651

    CPC classification number: C08F4/16 ,  C08F110/06 ,  C08F4/6494 ,  C08F2500/04 ,  C08F2500/12 ,  C08F4/651

    Abstract: A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from phenylene aromatic diesters of a specific formula (b) an alkylaluminum cocatalystand (c) an ester of formula R'OOC-(CR" 2 ) m -COOR' in which m is an integer from 2 to 7, the R' groups, equal to or different from each other, are C 1 -C 10 alkyl groups and the R" groups, independently, are hydrogen or C 1 -C 15 hydrocarbon groups.

    Abstract translation: 一种催化剂体系，其包括通过使（a）含有Mg，Ti，卤素和至少一种选自特定式（b）的亚苯基芳族二酯和至少一种电子给体化合物的固体催化剂组分（b）烷基铝助催化剂和（c） 式R'OOC-（CR“2）m-COOR'，其中m为2至7的整数，R'基彼此相同或不同，为C 1 -C 10烷基，R”基， 独立地是氢或C 1 -C 15烃基。

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