Abstract:
A process is disclosed for preparing aromatic polyamine mixtures which contain compounds of general formula (I) H2N-A-CH2-B-NH2, in which A and B stand for 1,4-phenylene radicals which can independently bear 1 to 4 substituents selected among C1-20-alkyl radicals and halogen atoms. A compound of general formula (IV) H-A-NH-CH2-HN-B-H and/or a compound of general formula (V) H-A-NH-CH2-B-NH2, in which A and B are substituted as above, are reacted at a temperature in a range from 20 °C to 200 °C in the presence of a catalyst which is made of one or several oxides of elements of the 3rd to the 10th group of the periodic table of elements and which can be acid activated.
Abstract:
The invention concerns a process for preparing polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butin-1,4-diol, diesters of these polymers with C2-C20 monocarboxylic acids or monoesters of these polymers with C1-C10 monocarboxylic acids by polymerizing tetrahydrofuran in the presence of one of the following telogens, water, 1,-4-butane diol, 2-butin-1,4-diol, polytetrahydrofuran with a molecular weight of between 200 and 700 Dalton, or of a C1-C10 monocarboxylic acid or a carboxylic acid anhydride produced from C2-C20 monocarboxylic acids or mixtures of these telogens on a heterogeneous carrier catalyst which contains a catalytically active amount of an oxygenous molybdenum and/or tungsten compound on an oxidic carrier material, and which has been calcined at temperatures of between 500 °C and 1000 °C after application of the precursor compounds of the oxygenous molybdenum and/or tungsten compounds to the carrier material precursors. Before it is used as a polymerization catalyst, the catalyst is activated by treatment with a reducing agent.
Abstract:
The invention concerns tetrahydrofuran/but-2-ine-1,4-diol copolymers containing C-C triple bonds, the copolymers having a mean molecular weight Mn of 500 to 3,500 Daltons and containing 0.5 to 3 moles of triple bonds per mole of copolymer, as well as blends of these copolymers with polytetrahydrofuran having a mean molecular weight Mn of 500 to 3,500 Daltons. The invention also concerns a method of producing such copolymers or blends and their use.
Abstract:
POLYTETRAHYDROFURAN, TETRAHYDROFURAN COPOLYMERS, DIESTERS OR MONOESTERS OF THESE POLYMERS ARE PREPARED BY THE POLYMERIZATION OF TETRAHYDROFURAN IN THE PRESENCE OF AT LEAST ONE TELOGEN AND/OR COMONOMER OVER A HETEROGENEOUS SUPPORTED CATALYST WHICH CONTAINS AN ACTIVE COMPONENT COMPRISING A CATALYTICALLY ACTIVE AMOUNT OF AT LEAST ONE OXYGEN-CONTAINING TUNGSTEN AND/OR MOLYBDENUM COMPOUND AN OXIDIC SUPPORT MATERIAL AND WHICH, FOLLOWING APPLICATION OF THE PRECURSOR COMPOUNDS OF THE ACTIVE COMPONENT TO THE SUPPORT MATERIAL PRECURSOR, HAS BEEN CALCINED AT TEMPERATURES OF 500°C TO 1000°C,WHERE A CATALYST IS USED WHICH CONTAINS A PROMOTOR WHICH COMPRISES AT LEAST ONE ELEMENT OR A COMPOUND OF AN ELEMENT OF GROUP 2, 3 (INCLUDING THE LANTHANIDES) 5, 6, 7, 8, OR 14 OF THE PERIODIC TABLE.
Abstract:
Process for the preparation of the tautomeric form I of 2,4,6-trianilino-p-(carbo-2'-ethylhexyl-1'-oxy)-1,3,5-triazine by crystallization from a tautomer mixture in the presence of one or more solvents chosen from the group consisting of aliphatic alcohols having 2 to 8 carbon atoms, aliphatic carboxylic alkyl esters having a total of 3 to 10 carbon atoms, aromatic carboxylic alkyl esters having a total of 8 to 12 carbon atoms, aliphatic carbonic esters having a total of 3 to 9 carbon atoms, carbonitriles having a total of 2 to 8 carbon atoms, dialkyl ketones having a total of 3 to 6 carbon atoms and aliphatic sulfones having a total of 3 to 6 carbon atoms, where the solvent or the solvent mixture may additionally comprise up to 30% by weight of a hydrocarbon. I is used as light protection agent in cosmetic preparations.
Abstract:
Polytetrahydrofuran, tetrahydrofuran copolymers, diesters or monoesters of these polymers are prepared by polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer on a heterogeneous carrier catalyst which contains on an oxidic carrier material as active mass a catalytically active amount of at least one oxygenous molybdenum and/or tungsten compound and, when the precursor compounds of the active mass have been applied to the carrier material precursor, has been calcined at temperatures of between 500° C. and 1000° C. The catalyst used contains a promotor which comprises at least one element or a compound of an element of the 2nd, 3rd including the lanthanides, 5th, 6th, 7th, 8th or 14th group of the periodic system of elements.
Abstract:
A process for polymerizing cyclic ethers over a heterogeneous catalyst comprises using a heterogeneous catalyst comprising one or more pillared interlayered clays (PILCs).
Abstract:
A process for decolorizing polymers or copolymers which are obtained by cationic polymerization of tetrahydrofuran or of tetrahydrofuran and alkylene oxide, in the presence or absence of a telogen, comprisesa) first, if desired, removing the low-boiling components by vacuum distillation or extraction andb) heating the remaining polymer or copolymer in the presence of at least one auxiliary selected from the group consisting of solid oxides and/or sheet silicates to from 20 to 150° C.
Abstract:
A process for decolorizing polymers or copolymers which are obtained by cationic polymerization of tetrahydrofuran or of tetrahydrofuran and alkylene oxide, in the presence or absence of a telogen, comprisesa) first, if desired, removing the low-boiling components by vacuum distillation or extraction andb) heating the remaining polymer or copolymer in the presence of at least one auxiliary selected from the group consisting of solid oxides and/or sheet silicates to from 20 to 150° C.