公开(公告)号：DE59704576D1

公开(公告)日：2001-10-18

申请号：DE59704576

申请日：1997-06-10

Applicant: BASF AG

Inventor： ELLER DR ,  KUMMER DR ,  HESSE DR

IPC: B01J21/08 ,  B01J23/24 ,  B01J23/30 ,  B01J35/10 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/33 ,  C07C211/43

Abstract: In the preparation of amines of formula (I) by reacting olefins of formula (II) with ammonia (NH3) or primary or secondary amines of formula (III) at 200-350 degrees C and 100-300 bar in the presence of a heterogeneous catalyst, group IVB and/or VIB oxide(s) on a support is used as catalyst. R R CH-CR R -NR R (I) R R C=CR R (II) H-NR R (III) R = hydrogen (H), 1-20 carbon (C) alkyl, 2-20 C alkenyl, 2-20 C alkynyl, 3-20 C cycloalkyl, 4-20 C alkyl-cycloalkyl, 4-20 C cycloalkyl-alkyl, aryl, 7-20 C alkylaryl or 7-20 C aralkyl; or R R = an (un)saturated 3-9 C alkylene di-chain; and R or R = 21-200 C alk(en)yl or R R = a 12 C alkylene di-chain.

公开(公告)号：DE59702192D1

公开(公告)日：2000-09-21

申请号：DE59702192

申请日：1997-12-01

Applicant: BASF AG

Inventor： ELLER DR ,  KUMMER DR

IPC: B01J29/06 ,  C07B61/00 ,  C07C209/60 ,  C07C211/07

Abstract: The preparation of amines of formula (R )(R )CHC(R )(R )N(R )(R ) (I) by reacting olefins of formula HN(R )(R ) (II) with ammonia (NH3) or primary or secondary amines of formula (R )(R )C=C(R )(R ) (III) at 200-350 degrees C and 100-300 bar is carried out in the presence of a heterogeneous catalyst comprising a type boron-MCM-22 or ERB-1 zeolite. In the formulae, R = H, 1-20 C alkyl, 2-20 C alkenyl, 2-20 C alkynyl, 3-20 C cycloalkyl, 4-20 C alkyl-cycloalkyl, 4-20 C cycloalkyl-alkyl, aryl, 7-20 C alkylaryl or 7-20 C aralkyl; R and R may = an (un)saturated 3-9 C alkylene di-chain; and R or R may = 21-200 C alk(en)yl; or R and R may = a 2-12 C alkylene di-chain.

公开(公告)号：DE59702041D1

公开(公告)日：2000-08-24

申请号：DE59702041

申请日：1997-04-10

Applicant: BASF AG

Inventor： ELLER DR ,  KUMMER DR ,  MUELLER DR

IPC: B01J21/12 ,  B01J23/10 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/25 ,  C07C211/26 ,  C07C211/34 ,  C07C211/45 ,  C07C211/54 ,  C07C211/57

Abstract: The novel feature in preparation of amines of formula (I) by reacting olefins of formula (II) with ammonia or H-N(R )(R ) (III) at 200-350 degrees C/100-300 bar is that the heterogeneous catalyst used is a mesoporous oxide of high surface area. R - R = 1-20C alkyl, 2-20C alkenyl or alkynyl, 3-20C cycloalkyl, 4-20C alkyl-cycloalkyl or cycloalkyl-alkyl, aryl, or 7-20C alkaryl or aralkyl; or R and R together form an optionally unsaturated 3-9C alkylene chain; and R and R = also 21-200C alkyl or alkenyl or together form 2-12C alkylene.