公开(公告)号：AT380470T

公开(公告)日：2007-12-15

申请号：AT02800095

申请日：2002-09-19

Applicant: BASF AG

Inventor： DIEING REINHOLD ,  DIETSCHE FRANK ,  GOMEZ MARCOS ,  KESSLER THOMAS ,  SCHILLO SIMONE ,  SCHNEIDER KARL-HEINRICH ,  HEILMANN KARL-OTTO

IPC: A01N25/10 ,  A01N43/90 ,  A01N25/12 ,  A01N37/24 ,  A01N37/50 ,  A01N43/28 ,  A01N43/36 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/78 ,  A01N47/22 ,  A01N47/24 ,  A01N47/32 ,  A01N47/38 ,  A01N47/40 ,  A01N47/42 ,  A01N47/44 ,  A01N51/00 ,  A01N57/14

Abstract: The present invention relates to a method for the preparation of a solid formulation of a slow-release crop protection product, which comprises carrying out a melt extrusion of a composition comprising 0.1 to 80% by weight of at least one fungicidal active ingredient, 0 to 80% by weight of at least one herbicidal, acaricidal, insecticidal or growth-regulatory active ingredient, 3 to 80% by weight of a thermoplastic, water-insoluble polymer from the group of the polylactides, 0 to 80% by weight of at least one thermoplastic water-insoluble polymer, 10 to 80% by weight of at least one mineral filler and 0 to 20% by weight of inorganic or organic additives, and subsequently shaping the extrudate, and to the solid formulations preparable by this method.

公开(公告)号：AU2003296654A1

公开(公告)日：2004-07-14

申请号：AU2003296654

申请日：2003-12-16

Applicant: BASF AG

Inventor： CHOWDHRY MUBARIK MAHMOOD ,  WOOD CLAUDIA ,  MATHAUER KLEMENS ,  ZUAZO IZASKUN MANTECA ,  GOMEZ MARCOS

IPC: A61K8/81 ,  A61Q5/12 ,  C08F290/04

公开(公告)号：DE10108386A1

公开(公告)日：2002-08-29

申请号：DE10108386

申请日：2001-02-21

Applicant: BASF AG

Inventor： GOMEZ MARCOS ,  ROCK TILMAN C ,  MEFFERT HELMUT ,  SANNER AXEL

IPC: C12C7/24 ,  B01D37/02 ,  B01D39/02 ,  B01D39/16 ,  B01J20/26 ,  C08F212/02 ,  C08F220/04 ,  A23L2/72 ,  C12H1/07 ,  C08L35/06 ,  C08J3/14

Abstract: Water-insoluble, poorly swellable polymer comprises: (a) 20-98.9 wt.% alpha , beta -ethylenically unsaturated 3-6C monocarboxylic acid; (b) 1-79.9 wt.% styrene (derivative); (c) 0.1-10 wt.% monomer with at least 2 double bonds; and (d) 0-40 wt.% other monomers.

公开(公告)号：DE50305067D1

公开(公告)日：2006-10-26

申请号：DE50305067

申请日：2003-11-17

Applicant: BASF AG

Inventor： MANTECA ZUAZO IZASKUN ,  GOMEZ MARCOS ,  NGUYEN-KIM SON

IPC: A61K8/00 ,  A61K8/81 ,  A61Q5/02 ,  C08L33/06 ,  C08L33/14 ,  C08L33/26

Abstract: Disclosed is a composition comprising (A) copolymer made up of (A-1) at least one ethylenically unsaturated, radically copolymerizable monomer of general formula Y-NR 1 -C(V)-NHR 2 , wherein the substituents have the following meaning: Y represents a radically polymerizable ethylenically unsaturated radical; V represents O, S, or NH; R 1 , R 2 independently represent H or a C 1 to C 8 alkyl group or jointly represent a bridging C 2 to C 4 alkylene group that can be substituted up to twice with a C 1 to C 4 alkoxy group and/or hydroxyl group; (A-2) at least one unsaturated monomer of general formula X-C(O)CR 7 -CHR 6 , wherein the substituents have the following meaning: X is selected among the group of radicals -OH, -OR 8 , NH 2 , -NHR 8 , N(R 8 ) 2 , radicals R 8 being identically or differently selected among the group comprising -H, C 1 -C 40 linear-chain or branched-chain alkyl radicals, N,N-dimethylaminoethyl, 2-hydroxyethyl, 2-methoxyethyl, 2-ethoxyethyl, hydroxypropyl, methoxypropyl, or ethoxypropyl; R 7 and R 6 are independently selected among the group comprising -H, C 1 -C 8 linear-chain or branched-chain alkyl chains, methoxy, ethoxy, 2-hydroxyethoxy, 2-methoxyethoxy, and 2-ethoxyethyl, (B) at least one additional copolymer that is different from (A) and is made up of (B-1) at least one monomer of general formula (III), wherein R 9 represents H, alkyl with 1 to 8 C atoms, R 10 represents H, methyl, R 11 represents alkylene with 1 to 24 C atoms, which is optionally substituted by C 1 -C 6 alkyl, R 12 , R 13 represent a C 1 -C 40 alkyl radical, Z represents nitrogen if x=1 or oxygen if x=0, and (B-2) at least one ethylenically unsaturated monomer.

公开(公告)号：AU2003283385A1

公开(公告)日：2004-06-15

申请号：AU2003283385

申请日：2003-11-11

Applicant: BASF AG

Inventor： LEHMANN STEPHAN ,  NORENBERG RALF ,  GOMEZ MARCOS ,  SCHEHLMANN VOLKER ,  HEGER ROBERT

IPC: A61K8/04 ,  A61K8/368 ,  A61K8/81 ,  A61K47/48 ,  A61P17/00 ,  A61Q19/00 ,  A61K7/48

公开(公告)号：DE10128531A1

公开(公告)日：2002-12-19

申请号：DE10128531

申请日：2001-06-13

Applicant: BASF AG

Inventor： GOTSCHE MICHAEL ,  GOMEZ MARCOS ,  SCHNEIDER TANJA ,  MEFFERT HELMUT ,  SCHNEIDER KARL-HEINRICH

IPC: B65D65/46 ,  A01N25/10 ,  A01N25/12 ,  A01N35/10 ,  A01N47/20 ,  C08F8/12 ,  C08F283/06 ,  C08L51/00 ,  C08L51/08 ,  C09D151/00 ,  C09D151/08 ,  C09D171/00 ,  B65D65/38

Abstract: The use of a water soluble water dispersible film forming graft polymerisate comprises: (a) vinyl esters of 1-24C carboxylic acids, in the presence of (b) polyethers of mean number average molecular wt. 300 (I), as coating agents, matrix builders,and/or packaging materials for agrochemicals. The use of a water soluble water dispersible film forming graft polymerisate comprises: (a) vinyl esters of 1-24C carboxylic acids, in the presence of (b) polyethers of mean number average molecular wt. 300 of formula (I), as coating agents, matrix builders,and/or packaging materials for agrochemicals. R = OH, amino, 1-24C alkoxy, R -COO, R -NH-COO-, polyalkoxy; R -R = (CH2)2, (CH2)3, (CH2)4, CH2CH(CH3), CH-2-CH(CH2-CH3), CH2-CHOR -CH2 R = H, amino-1-6 alkyl , 1-24 alkyl, R -CO, R -NH-CO; R = 1-24C alkyl; R = H, 1-24C alkyl, R -CO; A = COO, CO-B-COO, CONH-B-NH-COO; B = (CH2)t or optionally substituted arylene; n = 1; s = 0-500; t = 1-12; u = 1-5000; v = 0-5000; w = 0-5000; x = 1-5000; y = 0-5000; z = 0-5000; and provided that when R is polyalcohol, n is 1-8. An Independent claim is also included for agrochemical preparations in tablet form, containing a coating formulation of one or more agrochemical active agents as tab let cores with one or more graft polymerisates.

公开(公告)号：CA2450386A1

公开(公告)日：2002-12-19

申请号：CA2450386

申请日：2002-05-31

Applicant: BASF AG

Inventor： MEFFERT HELMUT ,  GOTSCHE MICHAEL ,  GOMEZ MARCOS ,  SCHNEIDER TANJA ,  SCHNEIDER KARL-HEINRICH

IPC: B65D65/46 ,  A01N25/10 ,  A01N25/12 ,  A01N35/10 ,  A01N47/20 ,  C08F8/12 ,  C08F283/06 ,  C08L51/00 ,  C08L51/08 ,  C09D151/00 ,  C09D151/08

Abstract: The invention relates to water-soluble or water-dispersible, film-forming graft polymers which are obtained by radical polymerization of (a) the vinyl esters of aliphatic C1-C24 carboxylic acids in the presence of (b) the polyethers having an average molecular weight (number average) of at least 3 00 of the general formula (I), wherein the variables independently have the following meanings: R1 represents hydroxy, amino, C1-C24 alkoxy, R9-COO-, R9 - NH-COO-, a polyalcohol group; R2 to R7 represent -(CH2)2-, -(CH2)3-, -(CH-2) 4- , -CH2-CH(CH3)-, -CH2-CH(CH2-CH3)-, -CH2-CHOR10-CH2-; R8 represents hydrogen , amino-C1-C6 alkyl, C1-C24 alkyl, R9-CO-, R9-NH-CO-; R9 represents C1-C24 alkyl; R10 represents hydrogen, C1-C24 alkyl, R9-CO-; A represents -CO-O-, - CO- B-CO-O, -CO-NH-B-NH-CO-O-; B represents -(CH2)t- or optionally a substituted arylene; n is 1 or, if R1 is a polyalcohol group, n is 1 to 8; s is 0 to 500 ; t is 1 to 12; u is 1 to 5000; v is 0 to 5000; w is 0 to 5000; x is 1 to 5000 ; y is 0 to 5000; and z is 0 to 5000. The inventive polymers can be used as coating agents, matrix formers and/or packaging materials for agrochemicals.

公开(公告)号：DE50211370D1

公开(公告)日：2008-01-24

申请号：DE50211370

申请日：2002-09-19

Applicant: BASF AG

Inventor： DIEING REINHOLD ,  DIETSCHE FRANK ,  GOMEZ MARCOS ,  KESSLER THOMAS ,  SCHILLO SIMONE ,  SCHNEIDER KARL-HEINRICH ,  HEILMANN KARL-OTTO

IPC: A01N25/10 ,  A01N43/90 ,  A01N25/12 ,  A01N37/24 ,  A01N37/50 ,  A01N43/28 ,  A01N43/36 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/78 ,  A01N47/22 ,  A01N47/24 ,  A01N47/32 ,  A01N47/38 ,  A01N47/40 ,  A01N47/42 ,  A01N47/44 ,  A01N51/00 ,  A01N57/14

Abstract: The present invention relates to a method for the preparation of a solid formulation of a slow-release crop protection product, which comprises carrying out a melt extrusion of a composition comprising 0.1 to 80% by weight of at least one fungicidal active ingredient, 0 to 80% by weight of at least one herbicidal, acaricidal, insecticidal or growth-regulatory active ingredient, 3 to 80% by weight of a thermoplastic, water-insoluble polymer from the group of the polylactides, 0 to 80% by weight of at least one thermoplastic water-insoluble polymer, 10 to 80% by weight of at least one mineral filler and 0 to 20% by weight of inorganic or organic additives, and subsequently shaping the extrudate, and to the solid formulations preparable by this method.

公开(公告)号：PT1432308E

公开(公告)日：2007-12-27

申请号：PT02800095

申请日：2002-09-19

Applicant: BASF AG

Inventor： SCHNEIDER KARL-HEINRICH ,  KESSLER THOMAS ,  DIEING REINHOLD ,  DIETSCHE FRANK ,  GOMEZ MARCOS ,  SCHILLO SIMONE ,  HEILMANN KARL-OTTO

IPC: A01N25/10 ,  A01N25/12 ,  A01N43/90 ,  A01N37/24 ,  A01N37/50 ,  A01N43/28 ,  A01N43/36 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/78 ,  A01N47/22 ,  A01N47/24 ,  A01N47/32 ,  A01N47/38 ,  A01N47/40 ,  A01N47/42 ,  A01N47/44 ,  A01N51/00 ,  A01N57/14

公开(公告)号：ES2273054T3

公开(公告)日：2007-05-01

申请号：ES03778319

申请日：2003-11-17

Applicant: BASF AG

Inventor： MANTECA ZUAZO IZASKUN ,  GOMEZ MARCOS ,  NGUYEN-KIM SON

IPC: A61K8/00 ,  A61K8/81 ,  A61Q5/02 ,  C08L33/06 ,  C08L33/14 ,  C08L33/26

Abstract: Composición, que contiene (A) copolímeros constituidos por (A-1) al menos un monómero etilénicamente insaturado, copolimerizable por medio de radicales de la fórmula general (I) Y - NR1 - C(V) - NHR2 (I), en la que los substituyentes tienen el significado siguiente: Y = un resto etilénicamente insaturado capaz de polimerización por medio de radicales, V = O, S o NH, R1, R2 = independientemente entre sí, H o un grupo alquilo con 1 hasta 8 átomos de carbono, o ambos, en conjunto, significan un grupo alquileno puenteante, con 2 hasta 4 átomos de carbono, que puede estar substituido hasta dos veces por un grupo alcoxi con 1 hasta 4 átomos de carbono y/o por un grupo hidroxilo, (A-2) al menos un monómero insaturado de la fórmula general (II) X - C(O)CR7 = CHR6 (II), en la que los substituyentes tienen el significado siguiente: X se elige del grupo formado por los restos -OH, -OR8, NH2, -NHR8, N(R8)2; los restos R8 pueden elegirse, de manera idéntica o diferente, del grupo formado por -H, , restos alquilo lineales o ramificados con 1 hasta 40 átomos de carbono, N, N-dimetilaminoetilo, 2-hidroxietilo, 2-metoxietilo, 2-etoxietilo, hidroxipropilo, metoxipropilo o etoxipropilo; R7 y R6 se eligen, independientemente entre sí, entre el grupo formado por -H, cadenas alquilolineales o ramificadas con 1 hasta 8 átomos de carbono, metoxi, etoxi, 2-hidroxietoxi, 2-metoxietoxi y 2-etoxietilo. (B) al menos otro copolímero, diferente de (A), constituido por (B-1) al menos un monómero de la fórmula general (III) (Ver fórmula) con R 9 = H, alquilo con 1 hasta 8 átomos de carbono, R 10 = H, metilo, R 11 = alquileno con 1 hasta 24 átomos de carbono, substituido opcionalmente por alquilo con 1 a 6 átomos de carbono, R 12 , R 13 = resto alquilo con 1 a 40 átomos de carbono, Z = nitrógeno para x = 1 u oxígeno para x = 0, y (B-2) al menos un monómero etilénicamente insaturado.