11.
    发明专利
    未知

    公开(公告)号:DE4302992A1

    公开(公告)日:1994-08-04

    申请号:DE4302992

    申请日:1993-02-03

    Applicant: BASF AG

    Abstract: Process for regenerating spent multimetal oxide oxidation catalysts from catalytic gas-phase oxidations of lower organic compounds, which catalysts, unspent, contain as base constituents the elements Mo, W, V and Cu in oxide form, by the action of oxidising agents and of solubilising aqueous ammonia containing added acetic acid and/or the ammonium salt thereof and subsequent drying and calcination in which, within the process, the content of the metallic constituents is quantitatively determined and supplemented to the respective original value.

    14.
    发明专利
    未知

    公开(公告)号:DE4132684A1

    公开(公告)日:1993-04-08

    申请号:DE4132684

    申请日:1991-10-01

    Applicant: BASF AG

    Abstract: A process for the catalytic gas-phase oxidation of methacrolein to methacrylic acid in a fixed-bed reactor with contacting tubes, at elevated temperature on catalytically active oxides with a conversion of methacrolein for a single pass of from 40 to 95 mol%, wherein the reaction temperature in the flow direction along the contacting tubes in a first reaction zone from entry of the starting reaction gases containing the reactants into the contacting tubes is from 280 to 340 DEG C. until a methacrolein conversion of from 20 to 40% is reached, and the reaction temperature is subsequently reduced by a total of from 5 DEG to 40 DEG C., abruptly or successively in steps or continuously along the contacting tubes until a methacrolein conversion of from 45 to 95% has been reached, with the proviso that the reaction temperature in this second reaction zone is not lower than 260 DEG C.

    18.
    发明专利
    未知

    公开(公告)号:DE19717165A1

    公开(公告)日:1998-10-29

    申请号:DE19717165

    申请日:1997-04-23

    Applicant: BASF AG

    Abstract: Reactor arrangement comprises at least two tubular reactors filled with solid particles, at least one reactor containing a temperature measuring device. The novelty is that the tubular reactors are arranged so that the ratio of the composition of the solid particles to the free cross-sectional surfaces of each reactor as well as the pressure loss, measured by passing an inert gas proportionally transversal to the free cross-sectional, are equal over each tubular reactor. Also claimed is a process for treating fluid compositions with the production and consumption of thermal energy using the above reactor arrangement.

    19.
    发明专利
    未知

    公开(公告)号:DE59600212D1

    公开(公告)日:1998-07-02

    申请号:DE59600212

    申请日:1996-01-13

    Applicant: BASF AG

    Abstract: In the sepn. of (meth)acrylic acid (I) from mixts. contg. (I) as main prod. and lower aldehydes as by-prods. by rectification in a column with a distn. zone and a concn. zone, the mixt. is not supplied to the column directly. Instead, it is passed to a heated dwell vessel connected to the concn. zone, in which the mixt. is kept boiling, and the sump liquid from this vessel is fed to the column.

    20.
    发明专利
    未知

    公开(公告)号:DE59405671D1

    公开(公告)日:1998-05-20

    申请号:DE59405671

    申请日:1994-01-25

    Applicant: BASF AG

    Abstract: Process for regenerating spent multimetal oxide oxidation catalysts from catalytic gas-phase oxidations of lower organic compounds, which catalysts, unspent, contain as base constituents the elements Mo, W, V and Cu in oxide form, by the action of oxidising agents and of solubilising aqueous ammonia containing added acetic acid and/or the ammonium salt thereof and subsequent drying and calcination in which, within the process, the content of the metallic constituents is quantitatively determined and supplemented to the respective original value.

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