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    14.
    发明专利
    未知

    公开(公告)号：DE2417003A1

    公开(公告)日：1975-11-06

    申请号：DE2417003

    申请日：1974-04-08

    Applicant: BASF AG

    Inventor： MERTES FRIEDRICH DIPL CHEM DR ,  DOERFEL HELMUT DIPL CHEM DR ,  HEIL EDUARD ,  CORDES CLAUS DIPL CHEM DR

    IPC: C08G69/00 ,  C08G69/04 ,  C08G69/28 ,  C08G69/36 ,  G01N30/91

    Abstract: An improved process for the continuous manufacture of polyamides by continuously conveying the aqueous solution of a salt of essentially equivalent amounts of a diamine, or of a mixture of several diamines, and of a dicarboxylic acid, or of a mixture of several dicarboxylic acids, or of mixtures of such salts with lactams and/or aminocarboxylic acids, through several reaction zones under polyamide-forming conditions, wherein the mixture of starting materials is heated, in a first reaction zone, to from 200 DEG to 300 DEG C, preferably from 220 DEG to 280 DEG C, at pressures which are above the corresponding saturation vapor pressure of water and prevent the formation of a vapor phase, the pressure action on the polycondensation mixture is released in a second reaction zone and condensation of the mixture, to form high molecular weight polyamides, is then completed in further reaction stages. According to the invention, A. THE MIXTURE OF STARTING MATERIALS IS HEATED, IN THE FIRST REACTION ZONE, UNTIL THE POLYCONDENSATION CONVERSION IS AT LEAST 80% AND PREFERABLY 90%, B. IN THE SECOND ZONE THE PRESSURE ACTING ON THE POLYCONDENSATION MIXTURE IS RELEASED, ADIABATICALLY, TO LEVELS OF NOT LESS THAN 3 ATMOSPHERES, PREFERABLY NOT LESS THAN 5 ATMOSPHERES, AND NOT MORE THAN 20 ATMOSPHERES, PREFERABLY NOT MORE THAN 15 ATMOSPHERES, SO AS TO REACH TEMPERATURES BELOW 215 DEG C, preferably 210 DEG C, c. the polycondensation mixture is then heated in a third reaction zone, comprising a heat exchanger consisting of heat exchange elements connected in parallel, to from 220 DEG to 330 DEG C, preferably from 250 DEG to 300 DEG C, in the course of less than 5 minutes and preferably less than 1 minute, the heating being carried out preferably in the presence of the water vapor formed during the adiabatic release of the pressure (in stage b), with application of heat and evaporation of the bulk of the water, at the pressure level to which the pressure has previously been released or at a lower pressure, and D. IN FURTHER REACTION STAGES, THE CONDENSATION IS COMPLETED, UNDER THE CONDITIONS PREVAILING AT THE END OF THE THIRD REACTION ZONE AND, FINALLY, BY CONVENTIONAL METHODS, TO FORM HIGH MOLECULAR WEIGHT POLYAMIDES.

    15.
    发明专利
    未知

    公开(公告)号：DE3578428D1

    公开(公告)日：1990-08-02

    申请号：DE3578428

    申请日：1985-11-07

    Applicant: BASF AG

    Inventor： BRANDT HERMANN DR ,  FISCHER HERMANN DR ,  DREHER HERMANN DR ,  HEIL EDUARD ,  HAMBRECHT JUERGEN DR ,  NAARMANN HERBERT DR ,  ECHTE ADOLF DR ,  GAUSEPOHL HERMANN DR ,  SIEBEL PETER DR ,  SWOBODA JOHANN DR ,  SCHWOEBEL GERD ,  NIKLES ALBERT

    IPC: B01J10/00 ,  B01J19/18 ,  C08G65/44

    Abstract: Polyphenylene ethers are prepared from monohydric phenols, which possess alkyl substituents in the two ortho-positions and, if desired, in the meta-position, but not in the para-position, by an oxidative coupling reaction with oxygen at from 15 DEG to 50 DEG C. and under from 1 to 10 bar in the presence of a catalyst complex, of a solvent and, if required, of an activator, by a method in which the conversion of the phenols is carried out in two more reaction zones, in which some or all of the solvent, the catalyst complex and the phenols and, where relevant, the activator is initially taken and is circulated by means of a conveying unit, and about 60-100% of the stoichiometric amount of oxygen required for the oxidative coupling is introduced into the first reaction zone and from 0 to about 40% of the said stoichiometric amount is introduced into the second reaction zone.

    PROCESS FOR THE CONTINUOUS PRODUCTION OF POLYAMIDES
    16.
    发明专利
    PROCESS FOR THE CONTINUOUS PRODUCTION OF POLYAMIDES 未知

    公开(公告)号：DE3468886D1

    公开(公告)日：1988-02-25

    申请号：DE3468886

    申请日：1984-06-13

    Applicant: BASF AG

    Inventor： PIPPER GUNTER ,  SCHMIDT FRANZ DR ,  THEYSOHN RAINER DR ,  RIEGGER SIEGFRIED DR ,  HEIL EDUARD ,  FISCHER HERMANN DR ,  THOMA RICHARD DR ,  MATTHIES PAUL DR

    IPC: C08G69/00 ,  C08G69/26 ,  C08G69/28 ,  C08L77/00

    Abstract: Nylons are prepared by a continuous process in which, in a precondensation zone, an aqueous solution of a salt of a dicarboxylic acid of 6 to 18 carbon atoms and a diamine of 6 to 18 carbon atoms is heated to 250 DEG -300 DEG C. under superatmospheric pressure, with simultaneous vaporization of water and formation of a prepolymer, the prepolymer and the vapor are separated, and the former is fed into a polycondensation zone and condensed under superatmospheric pressure of from 1 to 10 bar and at from 250 DEG to 300 DEG C., wherein the aqueous salt solution is condensed under superatomspheric pressure of from 1 to 10 bar in the first third of the tubular precondensation zone provided with baffles, until the degree of conversion is not less than 93%, and the prepolymer and the vapor phase are brought into intimate contact with one another in the remaining two thirds of the precondensation zone.

    PROCESS FOR REMOVING CATALYSTS FROM POLYPHENYLENE ETHERS
    17.
    发明专利
    PROCESS FOR REMOVING CATALYSTS FROM POLYPHENYLENE ETHERS 未知

    公开(公告)号：DE3462510D1

    公开(公告)日：1987-04-09

    申请号：DE3462510

    申请日：1984-07-03

    Applicant: BASF AG

    Inventor： BERGER ROSEMARIE ,  DREHER HERMANN DR ,  HAMBRECHT JUERGEN DR ,  HEIL EDUARD ,  REFFERT RUDI WILHELM ,  SWOBODA JOHANN DR ,  ECHTE ADOLF DR ,  SIEBEL PETER DR

    IPC: C08G65/46

    Abstract: The catalyst is removed in the preparation of high molecular weight polyphenylene ethers from monohydric phenols, which are alkyl-substituted at the two ortho-positions but not at the para-position and may or may not be alkyl-substituted at the meta-position, by an oxidative coupling reaction with oxygen at from 15 DEG to 50 DEG C. in the presence of a catalyst complex obtained from a copper salt and an organic amine, in the presence of from 1 to 20 parts by weight of a solvent per part by weight of the monomeric phenol, and in the presence or absence of an activator, and removal of the metal component of the catalyst from the polyphenylene ether solution with a complex-forming or chelate-forming compound in aqueous solution, in the presence or absence of reducing and stabilizing substances and assistants for accelerating the interphase reactions and for phase separation, by a method in which the continuous removal of the copper catalyst is carried out in one or more mixer-settler stages at a phase volume ratio of the organic phase to the aqueous phase of from 1:0.1 to 1:1.0, preferably from 1:0.4 to 1:0.6.

    18.
    发明专利
    未知

    公开(公告)号：DE3321579A1

    公开(公告)日：1984-12-20

    申请号：DE3321579

    申请日：1983-06-15

    Applicant: BASF AG

    Inventor： PIPPER GUNTER ,  SCHMIDT FRANZ DR ,  THEYSOHN RAINER DR ,  RIEGGER SIEGFRIED DR ,  HEIL EDUARD ,  FISCHER HERMANN DR ,  THOMA RICHARD DR ,  MATTHIES PAUL DR

    IPC: C08G69/00 ,  C08G69/26 ,  C08G69/28 ,  C08L77/00

    Abstract: Nylons are prepared by a continuous process in which, in a precondensation zone, an aqueous solution of a salt of a dicarboxylic acid of 6 to 18 carbon atoms and a diamine of 6 to 18 carbon atoms is heated to 250 DEG -300 DEG C. under superatmospheric pressure, with simultaneous vaporization of water and formation of a prepolymer, the prepolymer and the vapor are separated, and the former is fed into a polycondensation zone and condensed under superatmospheric pressure of from 1 to 10 bar and at from 250 DEG to 300 DEG C., wherein the aqueous salt solution is condensed under superatomspheric pressure of from 1 to 10 bar in the first third of the tubular precondensation zone provided with baffles, until the degree of conversion is not less than 93%, and the prepolymer and the vapor phase are brought into intimate contact with one another in the remaining two thirds of the precondensation zone.

    20.
    发明专利
    未知

    公开(公告)号：CH596250A5

    公开(公告)日：1978-03-15

    申请号：CH429975

    申请日：1975-04-04

    Applicant: BASF AG

    Inventor： MERTES FRIEDRICH DR ,  DOERFEL HELMUT DR ,  HEIL EDUARD ,  CORDES CLAUS DR

    IPC: C08G69/00 ,  C08G69/04 ,  C08G69/28 ,  C08G69/36 ,  G01N30/91

    Abstract: An improved process for the continuous manufacture of polyamides by continuously conveying the aqueous solution of a salt of essentially equivalent amounts of a diamine, or of a mixture of several diamines, and of a dicarboxylic acid, or of a mixture of several dicarboxylic acids, or of mixtures of such salts with lactams and/or aminocarboxylic acids, through several reaction zones under polyamide-forming conditions, wherein the mixture of starting materials is heated, in a first reaction zone, to from 200 DEG to 300 DEG C, preferably from 220 DEG to 280 DEG C, at pressures which are above the corresponding saturation vapor pressure of water and prevent the formation of a vapor phase, the pressure action on the polycondensation mixture is released in a second reaction zone and condensation of the mixture, to form high molecular weight polyamides, is then completed in further reaction stages. According to the invention, A. THE MIXTURE OF STARTING MATERIALS IS HEATED, IN THE FIRST REACTION ZONE, UNTIL THE POLYCONDENSATION CONVERSION IS AT LEAST 80% AND PREFERABLY 90%, B. IN THE SECOND ZONE THE PRESSURE ACTING ON THE POLYCONDENSATION MIXTURE IS RELEASED, ADIABATICALLY, TO LEVELS OF NOT LESS THAN 3 ATMOSPHERES, PREFERABLY NOT LESS THAN 5 ATMOSPHERES, AND NOT MORE THAN 20 ATMOSPHERES, PREFERABLY NOT MORE THAN 15 ATMOSPHERES, SO AS TO REACH TEMPERATURES BELOW 215 DEG C, preferably 210 DEG C, c. the polycondensation mixture is then heated in a third reaction zone, comprising a heat exchanger consisting of heat exchange elements connected in parallel, to from 220 DEG to 330 DEG C, preferably from 250 DEG to 300 DEG C, in the course of less than 5 minutes and preferably less than 1 minute, the heating being carried out preferably in the presence of the water vapor formed during the adiabatic release of the pressure (in stage b), with application of heat and evaporation of the bulk of the water, at the pressure level to which the pressure has previously been released or at a lower pressure, and D. IN FURTHER REACTION STAGES, THE CONDENSATION IS COMPLETED, UNDER THE CONDITIONS PREVAILING AT THE END OF THE THIRD REACTION ZONE AND, FINALLY, BY CONVENTIONAL METHODS, TO FORM HIGH MOLECULAR WEIGHT POLYAMIDES.

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